Effect of monochloramine on isolated fulvic acid

Monochloramine is interesting both as a selective oxidant of fulvic acid and as a drinking water disinfectant. In this study, the controlled reaction of aquatic fulvic acid with monochloramine did not result in products detectable by ether extraction-gas chromatography-flame ionization detection techniques. Evidence of a reaction was shown by bleaching of the fulvic acid solution (decreased absorbance at 465 nm) and chlorine substitution. Chlorine-containing products were quantified by the total carbon adsorbable organic halide (TOX) parameter. Bleaching and organic chlorine formation were much less extensive than in the reaction of free chlorine with fulvic acid. Monochloramine was shown to produce an organic chlorine fraction more hydrophilic and with higher molecular size than that produced by chlorine and fulvic acid. Results suggest that monochloramine may be useful tool for the investigation of certain humic functionalities because it reacts rather selectively and to a small extent with aquatic fulvic acid.     

Last glacial maximum ecology and climate from terrestrial gastropod assemblages in Peoria loess,western Kentucky

The Rocks loess section, in unglaciated western Kentucky, provides a high-resolution environmental record during the last glacial maximum onset. The Peoria Silt (9 m thick) contains 26 terrestrial gastropod species, with up to 15 species within a single 5 cm interval. Thirteen radiocarbon ages, using shells or charcoal, range between 30 and 24.5 cal ka; younger loess has been leached or eroded. Stratigraphic shifts in gastropod assemblages imply significant cooling, particularly ~27 cal ka, as solar insolation was decreasing and the southern Laurentide Ice Sheet rapidly advancing. Midwestern to southern species (e.g. Anguispira kochi, Gastrocopta pentodon, Hawaii miniscula, Helicodiscus parallelus, Vallonia perspectiva) occur only in the lowermost Peoria Silt (~30–27 cal ka). In contrast, cold-tolerant species (Columella alticola, Vertigo modesta, Vallonia gracilicosta) occur only in full glacial Peoria Silt (27–24.5 cal ka). Inferred mean July temperatures, from mutual climatic range methods, range from ~23 °C at 30 cal ka, cooling to ~18 °C by 26 cal ka; about 3–8 °C cooler than today (~26 °C). Superimposed on this cooling trend are multi-centennial variations in detrital carbonate, fossil shell concentrations, palaeotemperature estimates, and oxygen isotope values (Vertigo, Discus, Helicodiscus). The finer-scale variations imply relatively synchronous fluctuations in glacial sediment supply, loess sedimentation, and climate.     

Spatial Data Infrastructure Requirements for Mobile Location Based Journey Planning

A growing number of services are now being offered over mobile devices. They typically combine positioning technology, wireless technology and spatial analysis methods applied to detailed geographical, time based data to offer services in support of time critical, spatial, mobile decision making. A collection of research issues need to be addressed in the successful delivery of such services that extend beyond issues of sophisticated network algorithms. Specifically, careful attention needs to be given to: (1) people and user environments; (2) access to networks; (3) policy, privacy and liability; (4) standards and interoperability; and (5) data quality. Spatial Data Infrastructure (SDI) is the collective term for these interconnected issues and has been a traditional area of research associated with geographic information science. In this paper the particular SDI requirements for the successful delivery of Location Based Services (LBS) are explored through the development of a prototype LBS for journey planning. The initial implementation and testing of this prototype has revealed that the SDI context is well suited as a framework within which to examine the related LBS issues. From a more technical perspective, the testing has revealed that data structure and the means by which large data sets are mined (in order to gather information to present to users) is critical to the success of timely information delivery over limited bandwidth media.     

Probable tsunami origin for a Shell and Sand Sheet from marine ponds on Anegada, British Virgin Islands

A distinctive Shell and Sand Sheet found beneath the marine ponds of Anegada, British Virgin Islands, was formed by a post-1650 AD overwash event, but its origin (tsunami or hurricane) was unclear. This study assesses the taphonomic characters of the shell and large clast material (>2?mm) to determine its provenance and origin. Pond-wide stratigraphic units (Shelly Mud, Shell and Sand Sheet, Mud Cap) were analyzed (12 samples) at four sites in Bumber Well and Red Pond along with eight samples from the Shell and Sand Sheet in a 2-km transect of Bumber Well. Mollusks in the pond muds include Anomalocardia spp. and cerithids with no allochthonous shells from the offshore reef-flat. Results show that the shells and clasts (>2?mm) are derived from the erosion and winnowing of the underlying Shelly Mud of the former marine pond, forming a distinctive sheet-like deposit with Homotrema sand. The Shell and Sand Sheet contains articulated Anomalocardia bivalves and moderate numbers of angular fragments (approximately 35%) that are likely from crab predation. Radiocarbon dates of articulated Anomalocardia specimens from the Shell and Sand Sheet range widely (approximately 4000?years), with shell condition (pristine to variably preserved) showing no correlation with age. The articulated condition of the bivalves with the wide-ranging dates suggests erosion and winnowing of the underlying Shelly Mud but minimal transport of the bivalves. The Shell and Sand Sheet has taphonomic characteristics indicative of a widespread tsunami overwash (sheet-like extent and articulated specimens) but lacks allochthonous reef-flat shells. Reef-flat shell material may not have penetrated the pond, as a tsunami would have to cross the reef-flat and overtop high dunes (2.2?m) hindering transport of larger shell material but allowing the Homotrema sand to penetrate. Processes including hurricane overwash, pond wave action, or tidal channel opening and closure are not favoured interpretations as they would not produce extensive sheet-like deposits. Taphonomic analysis is hampered by the limited (400?C500?years BP) depositional history from Anegada??s ponds and the lack of comparative data from other Caribbean locations.     

Spatial coincidence and similar geochemistry of Late Triassic and Eocene–Oligocene magmatism in the Andes of northern Chile: evidence from the MMH porphyry type Cu–Mo deposit,Chuquicamata District

International Journal of Earth Sciences - The MMH porphyry type copper–molybdenum deposit in northern Chile is the newest mine in the Chuquicamata District, one of largest copper...     

Distributions of branched GDGTs in a tropical lake system: Implications for lacustrine application of the MBT/CBT paleoproxy

Branched glycerol dialkyl glycerol tetraether (GDGT) lipids are abundant and ubiquitous in lake sediments, potentially allowing for a paleolimnological application of the so-called MBT/CBT proxy (methylation index of branched tetraethers/cyclization ratio of branched tetraethers). To investigate the origin and characteristics of these compounds in lacustrine environments, we examined the distributions of GDGTs in soils, river sediments and lake sediments from Lake Towuti on the island of Sulawesi, Indonesia. We found significant differences in the degree of methylation and cyclization (expressed by way of the MBT and CBT indices) between the soil samples and the aquatic samples, suggesting that there may be in situ production of GDGTs in the aquatic environment. Based on these findings, we urge caution in the application of the MBT/CBT paleoproxy to lake sediments and encourage more rigorous study of these compounds in freshwater environments.     

Distribution of high field strength and rare earth elements in mantle and lower crustal xenoliths from the Southwestern United States: The role of grain-boundary phases

Spinel lherzolite and harzburgite xenoliths from the Basin and Range and Colorado Plateau Provinces in the southwestern United States (SWUS) show a broad range in incompatible element distributions from depleted to enriched, both within and between sites. The most fertile xenoliths occur in the Basin and Range Province and the most refractory in the Colorado Plateau or Transition Zone. Mass balance calculations indicate that up to 80% of the high field strength (Nb, Ta, Zr, Hf, Th, Ti) and rare earth elements (50% for Yb) in these xenoliths occur in phases along grain boundaries (or in microfractures). In lower crustal and eclogite xenoliths, up to 90% of these elements occur in grain-boundary phases. Nb/Ta, Zr/Hf, La/Sm and Nb/Th ratios and Nb-Ta anomalies in both types of xenoliths are also controlled by grain-boundary phases. To interpret these ratios in whole-rock analyses, it is critical to understand the timing and origin of the grain-boundary components in the xenoliths. Most of the enriched mantle xenoliths appear to have been enriched by metasomatic fluids related to silicate magmas and not to carbonatite magmas.Because of a complex multi-event history that affected the composition of the xenoliths, there is no simple geochemical relationship between magmatic or metamorphic history of the lower crust and upper mantle in the SWUS as reflected by the xenolith populations.     

Surficial Hydrocarbon Seep Infauna from the Blake Ridge (Atlantic Ocean, 2150 m) and the Gulf of Mexico (690–2240 m)

Abstract.  Infauna, including foraminifera and metazoans, were enumerated and identified from five types of seep habitats and two adjacent non-seep habitats. Collections were made with the deep submergence research vessel 'Alvin' from three areas of active seepage in the Gulf of Mexico (Alaminos Canyon [2220 m], Atwater Canyon [1930 m], and Green Canyon lease block 272 [700 m]) and on the Blake Ridge Diapir [2250 m], which is located off the southeastern coast of the United States. The seep habitats sampled included four types of microbial mats ( Beggiatoa , Thioploca , thin and thick Arcobacter ) and the periphery of a large mussel bed. Sediments under large rhizopod protists, xenophyophores, were sampled adjacent to the mussel bed periphery. A non-seep site, which was >1 km away from active seeps, was also sampled for comparison. Densities of most taxa were higher in the Gulf of Mexico seeps than in Blake Ridge samples, largely because densities in the thick microbial mats of Blake Ridge were significantly lower. Diversity was higher in the Thioploca mats compared to other microbial-mat types. Within an ocean basin ( i.e. , Atlantic, Gulf of Mexico) we did not observe significant differences in meiofaunal or macrofaunal composition in Beggiatoa versus Thioploca mats or thin versus thick Arcobacter mats. Foraminifera represented up to 16% of the seep community, a proportion that is comparable to their contribution at adjacent non-seep communities. In general, the observed densities and taxonomic composition of seep sites at the genus level was consistent with previous observations from seeps ( e.g. , the foraminifers Bolivina and Fursenkoina , the dorvilleid polychaete Ophryotrocha ).     

Climate change beliefs in an agricultural context: what is the role of values held by farming and non-farming groups?

Climate change in many agricultural contexts will increase tensions between farming and non-farming populations over adaptations in land use and water conservation strategies. How adequately these future tensions may be mitigated will be partially determined by each groups' beliefs about climate change. A voluminous literature shows that climate change beliefs are crucial for understanding engagement with climate change mitigation and adaptation strategies, and that values motivate climate change beliefs, but the role of values remains unclear, and comparisons of farming and non-farming populations are scant. We develop a model of climate change beliefs that integrates four main motivating factors - values, political ideology, knowledge, and worldview - and we explicitly compare members of farming and non-farming populations in an agricultural watershed in the Central Great Plains, USA. Our findings highlight the role of held values in motivating climate change beliefs and point to areas of potential consensus and tension within and among members of these two groups. The results provide an empirical basis for developing future climate change engagement strategies in contexts of growing divides and conflicts among farming and non-farming groups.