Apatite as a monitor of late-stage magmatic processes at Volcán Irazú, Costa Rica

Apatite phenocrysts from the 1963 and 1723 eruptions of Irazú volcano (Costa Rica) record a volatile evolution history that confirms previous melt inclusion studies, and provides additional information concerning the relative and absolute timing of subvolcanic magmatic events. Measurements of H, Cl, and F by secondary ion mass spectrometry reveal multiple populations of apatite in both 1723 and 1963 magmas. Assuming nominal apatite/melt partition coefficients allows us to compare the pattern of melt inclusions and apatites in ternary space, demonstrating the fidelity of the record preserved in apatite, and revealing a complex history of magma mixing with at least two components. The preservation of heterogeneous populations of apatite and of internally heterogeneous crystals requires short timescales (days to years) for these magmatic processes to occur.     

Sedimentary and faunal events revealed by a revised correlation of post‐glacial Hirnantian (Late Ordovician) strata in the Welsh Basin,UK

The discovery of a previously unrecognized unconformity and of new faunas in the type Llandovery area underpins a revised correlation of Hirnantian strata in mid Wales. This has revealed the sedimentary and faunal events which affected the Lower Palaeozoic Welsh Basin during the global rise in sea level that followed the end‐Ordovician glacial maximum and has allowed their interpretation in the context of local and global influences. In peri‐basinal shelfal settings the onset of post‐glacial deepening is recorded by an unfossiliferous, transgressive shoreface sequence (Cwm Clyd Sandstone and Garth House formations) which rests unconformably on Rawtheyan rocks, deformed during an episode of pre‐Hirnantian tectonism. In the deep water facies of the basin centre, this same sequence boundary is now recognized as the contact between fine‐grained, re‐sedimented mudstones and an underlying regressive sequence of turbidite sandstones and conglomerates; it is at a level lower than previously cited and calls into question the established lithostratigraphy. In younger Hirnantian strata, graptolites associated with the newly recognized Ystradwalter Member (Chwefri Formation) demonstrate that this distal shelf unit correlates with the persculptus graptolite‐bearing Mottled Mudstone Member of the basinal succession. Together these members record an important macrofaunal recolonization of the Welsh Basin and mark a key event in the post‐glacial transgression. Further deepening saw the establishment of a stratified water column and the imposition of anoxic bottom water conditions across the basin floor. These post‐glacial Hirnantian events are consistent with the re‐establishment of connections between a silled Welsh Basin and the open Iapetus Ocean. However, a comparison with other areas suggests that each event records a separate deepening episode within a pulsed glacio‐eustatic transgression, while also reflecting changes in post‐glacial climate and patterns of oceanic circulation and associated biotic flux. British Geological Survey © NERC 2009. All rights reserved.     

The distribution of carbon monoxide in the lower atmosphere of Venus

We have obtained spatially resolved near-infrared spectroscopy of the Venus nightside on 15 nights over three observing seasons. We use the depth of the CO absorption band at 2.3 μm to map the two-dimensional distribution of CO across both hemispheres. Radiative transfer models are used to relate the measured CO band depth to the volume mixing ratio of CO. The results confirm previous investigations in showing a general trend of increased CO abundances at around 60° latitude north and south as compared with the equatorial regions. Observations taken over a few nights generally show very similar CO distributions, but significant changes are apparent over longer periods. In past studies it has been assumed that the CO latitudinal variation occurs near 35 km altitude, at which K-band sensitivity to CO is greatest. By modeling the detailed spectrum of the excess CO at high latitudes we show that it occurs at altitudes around 45 km, much higher than has previously been assumed, and that there cannot be significant contribution from levels of 36 km or lower. We suggest that this is most likely due to downwelling of CO-rich gas from the upper atmosphere at these latitudes, with the CO being removed by around 40 km through chemical processes such as the reaction with SO₃.     

Extending the Capture Map Concept to Estimate Discrete and Risk-Based Streamflow Depletion Potential

A popular and contemporary use of numerical groundwater models is to estimate the discrete relation between groundwater extraction and surface-water/groundwater exchange. Previously, the concept of a “capture map” has been put forward as a means to effectively summarize this relation for decision-making consumption. While capture maps have enjoyed success in the environmental simulation industry, they are deterministic, ignoring uncertainty in the underlying model. Furthermore, capture maps are not typically calculated in a manner that facilitates analysis of varying combinations of extraction locations and/or reaches. That is, they are typically constructed with focus on a single reach or group of reaches. The former of these limitations is important for conveying risk to decision makers and stakeholders, while the latter is important for decision-making support related to surface-water management, where future foci may include reaches that were not the focus of the original capture analysis. Herein, we use the concept of a response matrix to generalize the theory of the capture-map approach to estimate spatially discrete streamflow depletion potential. We also use first-order, second-moment uncertainty estimation techniques with the concept of “risk shifting” to place capture maps and streamflow depletion potential in a stochastic, risk-based framework. Our approach is demonstrated for an integrated groundwater/surface-water model of the lower San Antonio River, Texas, USA.     

Southern high latitude climate variability in the Late Cretaceous greenhouse world

A palynological study of oil exploration wells in the Gippsland Basin southeastern Australia has provided a record of southern high latitude climate variability for the last 12 million years of the Cretaceous greenhouse world. During this time, the vegetation was dominated by a cool to temperate flora of Podocarpaceae, Proteaceae and Nothofagidites spp. at a latitude of 60°S. Milankovitch forced cyclic alternations from drier to wetter climatic periods caused vegetation variability from 72 to 77 Ma. This climate change was probably related to the waxing and waning of ephemeral (100 ky) small ice sheets in Antarctica during times of insolation minima and maxima. Drying and cooling after 72 Ma culminated from 68 to 66 Ma, mirroring trends in global δ¹⁸O data. Quantitative palynofloral analyses have the potential to provide realistic proxies for small-scale climate variability in the predominantly ice-free Late Cretaceous.     

Spectral analysis of continuous redox data reveals geochemical dynamics near the stream–aquifer interface

Changes in streamflow and water table elevation influence oxidation–reduction (redox) conditions near river–aquifer interfaces, with potentially important consequences for solute fluxes and biogeochemical reaction rates. Although continuous measurements of groundwater chemistry can be arduous, in situ sensors reveal chemistry dynamics across a wide range of timescales. We monitored redox potential in an aquifer adjacent to a tidal river and used spectral and wavelet analyses to link redox responses to hydrologic perturbations within the bed and banks. Storms perturb redox potential within both the bed and banks over timescales of days to weeks. Tides drive semidiurnal oscillations in redox potential within the streambed that are absent in the banks. Wavelet analysis shows that tidal redox oscillations in the bed are greatest during late summer (wavelet magnitude of 5.62 mV) when river stage fluctuations are on the order of 70 cm and microbial activity is relatively high. Tidal redox oscillations diminish during the winter (wavelet magnitude of 2.73 mV) when river stage fluctuations are smaller (on the order of 50 cm) and microbial activity is presumably low. Although traditional geochemical observations are often limited to summer baseflow conditions, in situ redox sensing provides continuous, high‐resolution chemical characterization of the subsurface, revealing transport and reaction processes across spatial and temporal scales in aquifers.     

Constraining basin thermal history and petroleum generation using palaeoclimate data in the Piceance Basin,Colorado

Careful assessment of basin thermal history is critical to modelling petroleum generation in sedimentary basins. In this paper, we propose a novel approach to constraining basin thermal history using palaeoclimate temperature reconstructions and study its impact on estimating source rock maturation and hydrocarbon generation in a terrestrial sedimentary basin. We compile mean annual temperature (MAT) estimates from macroflora assemblage data to capture past surface temperature variation for the Piceance Basin, a high‐elevation, intermontane, sedimentary basin in Colorado, USA. We use macroflora assemblage data to constrain the temporal evolution of the upper thermal boundary condition and to capture the temperature change with basin uplift. We compare these results with the case where the upper thermal boundary condition is based solely upon a simplified latitudinal temperature estimate with no elevation effect. For illustrative purposes, 2 one‐dimensional (1‐D) basin models are constructed using these two different upper thermal boundary condition scenarios and additional geological and geochemical input data in order to investigate the impact of the upper thermal boundary condition on petroleum source rock maturation and kerogen transformation processes. The basin model predictions indicate that the source rock maturation is very sensitive to the upper thermal boundary condition for terrestrial basins with variable elevation histories. The models show substantial differences in source rock maturation histories and kerogen transformation ratio over geologic time. Vitrinite reflectance decreases by 0.21%Ro, source rock transformation ratio decreases 10.5% and hydrocarbon mass generation decreases by 16% using the macroflora assemblage data. In addition, we find that by using the macroflora assemblage data, the modelled depth profiles of vitrinite reflectance better matches present‐day measurements. These differences demonstrate the importance of constraining thermal boundary conditions, which can be addressed by palaeotemperature reconstructions from palaeoclimate and palaeo‐elevation data for many terrestrial basins. Although the palaeotemperature reconstruction compiled for this study is region specific, the approach presented here is generally applicable for other terrestrial basin settings, particularly basins which have undergone substantial subaerial elevation change over time.     

Dispersion of naturally occurring ions in groundwater from various rock types in a portion of the San Pedro river basin, Arizona

The groundwater in an alluvial basin in southern Arizona was analyzed for concentrations of Ca⁺⁺, Mg⁺⁺, Na⁺, and Cl⁻, ions.

The variety of rock types in the area, plus the undisturbed state of the groundwater basin, make comparative rock mineralization-groundwater ionization interpretations possible. Ionic dispersion in groundwater eminating from source areas composed of differing rock types is plotted as isogram maps. These isolated areas of differing mineral composition each exhibit a unique ionic contribution to groundwater. The ion concentrations in groundwater were then used as naturally occurring tracers to determine source areas of recharge and to delineate subsurface barriers to the normal basin flow net. Ion dispersion plots reveal the carbonates of the Dragoon Mountains to be a major contributor of Ca⁺⁺ and Mg⁺⁺ to the deep alluvial portion of the basin. Cl⁻ dispersion patterns show the granitic intrusives of the Tombstone Hills produce a barrier effect in the normal flow pattern of the basin as well as being a contributor of Cl⁻ to groundwater.     

A GPS-Supported Gravity Survey in the Amazon of Ecuador

The growing importance and effectiveness of the Global Positioning System (GPS) in positioning geophysical surveys is now well established. In Ecuador's Amazon basin the use of GPS was the determining factor in the successful completion of a gravity survey carried out in 1994. Over 500 gravity stations, spaced from 1 to 5 km apart and positioned by GPS, were collected in the jungle environment in the country's southeast, where the preexisting data, of variable and unknown quality, were mostly confined to areas along the major rivers. This station densification, which includes the reoccupation of selected points, contributed to increase the gravity coverage; it also allowed us to evaluate and correct 1100 preexisting data points in the area, so that the different surveys can be merged. The composite data set is used for a geologic analysis of the study area, where previously unknown structures are discovered. ? 1999 John Wiley & Sons, Inc.     

Growth and mortality of juvenile winter flounder in two New England estuaries

A length-based model for calculating growth and mortality of juvenile winter flounder (Pseudopleuronectes americanus) populations has been developed. This model is based on work by Sullivan et al. (1990) and incorporates the von Bertalanffy growth equation, including stochasticity in growth, and a mortality rate that decreases exponentially with size. The length-based model was fit to observed size-frequency distributions, and model likelihood profiles were generated to produce 95% confidence intervals about parameter estimates. We analyzed size-frequency distributions of 3 to 15 cm juvenile winter flounder, collected with a 1-m beam trawl, at monthly intervals from June to October during 1993 and 1994. Growth rates were higher at a contaminated site, New Haven Harbor, than at a clean site, the Connecticut River estuary, however, the parameter estimates had overlapping 95% confidence intervals. Mortality rates were similar at the two sites.