Jet Deflection by a Quasi-Steady-State Side Wind in the Laboratory

We present experimental data on the steady state deflection of a highly supersonic jet by a side-wind in the laboratory. The use of a long interaction region enables internal shocks to fully cross the jet, leading to the development of significantly more structure in the jet than in previous work with a similar setup (Lebedev et al., 2004). The ability to control the length of the interaction region in the laboratory allows the switch between a regime representing a clumpy jet or wind and a regime similar to a slowly varying mass loss rate. The results indicate that multiple internal oblique shocks develop in the jet and the possible formation of a second working surface as the jet attempts to tunnel through the ambient medium.     

Assessment of δ13C and C/N ratios in bulk organic matter as palaeosalinity indicators in Holocene and Lateglacial isolation basin sediments,northwest Scotland

Carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter have recently been used as alternative proxies for relative sea‐level (RSL) reconstruction where there are problems associated with conventional biological indictors. A previous study on a single isolation basin (Upper Loch nan Eala) in northwest Scotland has shown a clear relationship between δ¹³C, C/N ratios and palaeosalinity from Younger Dryas and Holocene aged sediments. In this paper we present results of δ¹³C and C/N ratio analyses from other isolation basins in northwest Scotland over the Holocene and the Lateglacial period in order to validate this technique. The results from the Holocene sequences support the earlier findings that this technique can be used to identify RSL change from isolation basins over the Holocene in this region. The relationship between δ¹³C, C/N ratios and RSL change is not apparent in sediments of Lateglacial age. Other environmental variables such as atmospheric CO₂ concentration, poor vegetation development and temperature influence δ¹³C values during this period. Copyright © 2007 John Wiley & Sons, Ltd.     

First cosmogenic 10Be age constraint on the timing of Younger Dryas glaciation and ice cap thickness,western Scottish Highlands

We use cosmogenic ¹⁰Be surface exposure age techniques at a locality close to Rannoch Moor, western Scottish Highlands, in order to establish the age and chronology of its most recent glaciation. Glacial erratics and an in situ bedrock quartz vein sampled from this site—the summit of Beinn Inverveigh—have yielded zero‐erosion exposure ages of 12.9 ± 1.5 ka to 11.6 ± 1.0 ka, implying complete ice cover of the mountain during the Younger Dryas, or Loch Lomond Stadial. These results fit closely with published ¹⁴C dates that bracket the maximum (lateral) extent of ice cap outlet glaciers, and are the first internally consistent ages to specifically address this period of glaciation in Scotland. Furthermore, the dates imply that previous palaeoglaciological reconstructions for this area may have underestimated both the thickness of the former ice cap and, by implication, its volume. © British Geological Survey/Natural Environment Research Council copyright 2007. Reproduced with the permission of BGS/NERC. Published by John Wiley & Sons, Ltd.     

Spatial variability of snowmelt timing from AMSR‐E and SSM/I passive microwave sensors,Pelly River,Yukon Territory,Canada

Spring snow melt run‐off in high latitude and snow‐dominated drainage basins is generally the most significant annual hydrological event. Melt timing, duration, and flow magnitude are highly variable and influence regional climate, geomorphology, and hydrology. Arctic and sub‐arctic regions have sparse long‐term ground observations and these snow‐dominated hydrologic regimes are sensitive to the rapidly warming climate trends that characterize much of the northern latitudes. Passive microwave brightness temperatures are sensitive to changes in the liquid water content of the snow pack and make it possible to detect incipient melt, diurnal melt‐refreeze cycles, and the approximate end of snow cover on the ground over large regions. Special Sensor Microwave Imager (SSM/I) and Advanced Microwave Scanning Radiometer for EOS (AMSR‐E) passive microwave brightness temperatures (T_b) and diurnal amplitude variations (DAV) are used to investigate the spatial variability of snowmelt onset timing (in two stages, ‘DAV onset’ and ‘melt onset’) and duration for a complex sub‐arctic landscape during 2005. The satellites are sensitive to small percentages of liquid water, and therefore represent ‘incipient melt’, a condition somewhat earlier than a traditional definition of a melting snowpack. Incipient melt dates and duration are compared to topography, land cover, and hydrology to investigate the strength and significance of melt timing in heterogeneous landscapes in the Pelly River, a major tributary to the Yukon River. Microwave‐derived melt onset in this region in 2005 occurred from late February to late April. Upland areas melt 1–2 weeks later than lowland areas and have shorter transition periods. Melt timing and duration appear to be influenced by pixel elevation, aspect, and uniformity as well as other factors such as weather and snow mass distribution. The end of the transition season is uniform across sensors and across the basin in spite of a wide variety of pixel characteristics. Copyright © 2007 John Wiley & Sons, Ltd.     

XMM-Newton observations of the isolated neutron star 1RXS J214303.7+065419/RBS1774

We report XMM-Newton observations of the isolated neutron star RBS1774 and confirm its membership as an XDINS. The X-ray spectrum is best fit with an absorbed blackbody with temperature kT=101 eV and absorption edge at 0.7 keV. No power law component is required. An absorption feature in the RGS data at 0.4 keV is not evident in the EPIC data, but it is not possible to resolve this inconsistency. The star is not seen in the UV OM data to m _AB ∼21. There is a sinusoidal variation in the X-ray flux at a period of 9.437 s with an amplitude of 4%. The age as determined from cooling and magnetic field decay arguments is 10⁵–10⁶ yr for a neutron star mass of 1.35–1.5 M_⊙.      

High- and low-affinity binding sites for Cd on the bacterial cell walls of Bacillus subtilis and Shewanella oneidensis

Bulk Cd adsorption isotherm experiments, thermodynamic equilibrium modeling, and Cd K edge EXAFS were used to constrain the mechanisms of proton and Cd adsorption to bacterial cells of the commonly occurring Gram-positive and Gram-negative bacteria, Bacillus subtilis and Shewanella oneidensis, respectively. Potentiometric titrations were used to characterize the functional group reactivity of the S. oneidensis cells, and we model the titration data using the same type of non-electrostatic surface complexation approach as was applied to titrations of B. subtilis suspensions by Fein et al. (2005). Similar to the results for B. subtilis, the S. oneidensis cells exhibit buffering behavior from approximately pH 3-9 that requires the presence of four distinct sites, with pK_a values of 3.3 ± 0.2, 4.8 ± 0.2, 6.7 ± 0.4, and 9.4 ± 0.5, and site concentrations of 8.9(±2.6) × 10⁻⁵, 1.3(±0.2) × 10⁻⁴, 5.9(±3.3) × 10⁻⁵, and 1.1(±0.6) × 10⁻⁴ moles/g bacteria (wet mass), respectively. The bulk Cd isotherm adsorption data for both species, conducted at pH 5.9 as a function of Cd concentration at a fixed biomass concentration, were best modeled by reactions with a Cd:site stoichiometry of 1:1. EXAFS data were collected for both bacterial species as a function of Cd concentration at pH 5.9 and 10 g/L bacteria. The EXAFS results show that the same types of binding sites are responsible for Cd sorption to both bacterial species at all Cd loadings tested (1-200 ppm). Carboxyl sites are responsible for the binding at intermediate Cd loadings. Phosphoryl ligands are more important than carboxyl ligands for Cd binding at high Cd loadings. For the lowest Cd loadings studied here, a sulfhydryl site was found to dominate the bound Cd budgets for both species, in addition to the carboxyl and phosphoryl sites that dominate the higher loadings. The EXAFS results suggest that both Gram-positive and Gram-negative bacterial cell walls have a low concentration of very high-affinity sulfhydryl sites which become masked by the more abundant carboxyl and phosphoryl sites at higher metal:bacteria ratios. This study demonstrates that metal loading plays a vital role in determining the important metal-binding reactions that occur on bacterial cell walls, and that high affinity, low-density sites can be revealed by spectroscopy of biomass samples. Such sites may control the fate and transport of metals in realistic geologic settings, where metal concentrations are low.     

Tertiary coal geology and stratigraphy of the Port Phillip Basin,Victoria

Results from coal‐exploration drilling in the onshore part of the Port Phillip Basin, Victoria, have established stratigraphic and age correlations of the Lower Miocene Werribee Formation brown coal deposits at Bacchus Marsh to similar brown coals at Altona. The coal deposits occur in a northwest‐southeast structural depression (the Parwan Trough) that appears to be a southeast continuation of the Ballan Graben. Recent drilling for potential coal‐bed methane in the trough has provided new data on the deeper stratigraphy not penetrated by earlier drilling, including recognition of an Upper Cretaceous to Eocene Yaloak Formation coal‐bearing interval, similar to the Anglesea area, Ballan Graben and Lal Lal Basin. Up to 200 m of coal‐bearing sediment and minor volcanics underlie the Miocene coal measures. A marine facies transition takes place between the Miocene coal swamps of the Parwan Trough, through barrier sands west of Werribee, to carbonate facies near Geelong. To the south beneath Port Phillip Bay, a similar transition probably occurs between coal swamps of the Parwan Trough and fully marine carbonate environments of the contiguous Sorrento Graben. The palaeogeographical reconstructions suggest a similar coal‐to‐carbonate facies transition as in the adjacent onshore Gippsland Basin.     

Classification of Streaky Bay,Mangalo, Ethiudna and Crockers Well: Stony meteorites from South Australia

Abstract— Four meteorites from South Australia are described and classified. Streaky Bay (L4b) and Mangalo (L6e) were received by the South Australian Museum in December, 1989. Ethiudna (L4a) and Crockers Well (LL7) were previously thought to be paired and were previously described only as chondrites.