Evaluating Subsurface Parameterization to Simulate Hyporheic Exchange: The Steinlach River Test Site

Hyporheic exchange is the interaction of river water and groundwater, and is difficult to predict. One of the largest contributions to predictive uncertainty for hyporheic exchange has been attributed to the representation of heterogeneous subsurface properties. Our study evaluates the trade-offs between intrinsic (irreducible) and epistemic (reducible) model errors when choosing between homogeneous and highly complex subsurface parameter structures. We modeled the Steinlach River Test Site in Southwest Germany using a fully coupled surface water-groundwater model to simulate hyporheic exchange and to assess the predictive errors and uncertainties of transit time distributions. A highly parameterized model was built, treated as a “virtual reality” and used as a reference. We found that if the parameter structure is too simple, it will be limited by intrinsic model errors. By increasing subsurface complexity through the addition of zones or heterogeneity, we can begin to exchange intrinsic for epistemic errors. Thus, the appropriate level of detail to represent the subsurface depends on the acceptable range of intrinsic structural errors for the given modeling objectives and the available site data. We found that a zonated model is capable of reproducing the transit time distributions of a more detailed model, but only if the geological structures are known. An interpolated heterogeneous parameter field (cf. pilot points) showed the best trade-offs between the two errors, indicating fitness for practical applications. Parameter fields generated by multiple-point geostatistics (MPS) produce transit time distributions with the largest uncertainties, however, these are reducible by additional hydrogeological data, particularly flux measurements.     

Transition from frontal accretion to underplating in a part of the Nankai Trough Accretionary Complex off Shikoku (SW Japan) and extensional features on the lower trench slope

Migrated multichannel seismic reflection profiles and bathymetry from a 200 × 120 km area of the Nankai Trough inner slope reveal three physiographic-tectonic domains on the lowermost slope. Linear ridges demarking laterally-continuous hangingwall anticlines above ramps in a relatively simple imbricate stack of trench turbidites characterize the western domain. An imbricate fan underlies a relatively flat structural terrace in the east. Between these two domains lies a compound knoll (Minami Muroto Knoll) some 40 km long, opposite which the thrust front pushes some 10 km further seaward than is the case in the domains to east and west. In the western ‘linear-ridge’ domain previous DSDP drilling penetrated turbiditic trench fill uplifted in the lowermost thrust-fold terrace above a decollement within the underthrusting Shikoku Basin (oceanic plate) sequence. The Shikoku Basin sequence in the western domain is divided into an upper, poorly reflective, hemipelagic claystone unit and a lower, strongly reflective, unit comprising Pliocene turbidites. The lower unit is traceable intact up to c.20 km landward below the lower trench slope and in the better resolved profiles the decollement lies along the base of the claystone unit. A similar decollement within the Shikoku Basin sequence in the eastern domain is traceable up to c.22 km landward. A critical seismic record crossing the western part of Minami-Muroto Knoll shows that the decollement is traceable only 8 km landward to a point, under the steep slope at the front of the knoll, landward of which the subducting Shikoku basin sequence is apparently thickened by as much as twice. This thickening, occuring as it does immediately along-strike from a simple imbricate fan to the east of the knoll and a relatively simple imbricate stack to the west (both evidently involving no strata from the lower Shikoku Basin unit) we ascribe to underplating by formation of duplexes of Shikoku Basin strata. Strike-parallel extension, akin to that postulated for high structural levels in certain thrust belts, is caused by uplift of the knoll as a result either of the underplating, or segmentation of the subducting oceanic crust, or both: a normal fault throws to the west off the west flank of the knoll. It bounds a transverse, trough-like, slope-basin with at least 900 m of fill. Upslope from the knoll broadly slope-parallel normal faults cut, and pond, recent slope sediments. The most impressive is a listric growth fault which dips trenchward. Alternative explanations for these involve extensional collapse of this part of the prism resulting from the subduction of a topographic high, or a zone of selective underplating below the trenchward portion of Minami Murato Knoll.     

Triangulation hand‐held laser‐scanning (TriHaLaS) for micro‐ and meso‐habitat surveys in streams

A novel hand‐held laser‐based stream bed survey system is presented. The system facilitates the capture of detailed 3D mapping of shallow (< 0.7 m) riverbed topography in sections approximately 4 m by 2 m. The system includes a stationary reference system, which projects three laser sheets (two at offset angles), within which a hand‐held monitoring pole is moved. The unique configuration of the light sheets intercepts with the pole as it moves within the survey area providing an exact horizontal location. Pole tilt is compensated for by an inertial measurement unit on the pole, and the height above the bed of the pole and submerged scanning laser are monitored relative to the horizontal laser sheet. Verification and application measurements demonstrate high resolution and accuracy in the horizontal (~5 mm) and vertical (~1 mm) direction. The system can be applied at sites where a free view is blocked and other optical through‐water methods fail. It is appropriate for studies on riverbed statistics and dynamics, which necessitate non‐invasive in‐situ surveys. Copyright © 2017 John Wiley & Sons, Ltd.     

Geomagnetic field analysis—III. Magnetic fields on the core—mantle boundary

Summary. The method of stochastic inversion, previously applied to secular variation data, is applied to main field data. Adaptations to the method are required: non-linear, as well as linear, data are used; allowance is made for crustal components in the observatory data; and the prior information is specified differently. The requirement that the models should satisfy a finite lower bound on the Ohmic heating in the core provides strong prior information and gives finite error estimates at the core—mantle boundary.
The new method is applied to data from the epochs 1969.5 and 1980.0. The resulting field models are very much more complex than other models, such as the IGRF models extrapolated to the core, and show considerable small-scale detail which, on the basis of the error analysis, can be believed.
The flux integral over the northern hemisphere is computed at each epoch; the difference between the two epochs is approximately one standard deviation, suggesting that the question as to whether the decay of the dipole is consistent with the frozen-flux hypothesis has been resolved in favour of the hypothesis.     

Influence of dissolved organic carbon on photochemically mediated cycling of hydrogen peroxide in rainwater

The influence of sunlight and dissolved organic carbon (DOC) on the photochemically mediated cycling of hydrogen peroxide (H₂O₂) was investigated in rainwater samples collected in Wilmington, North Carolina USA. Upon exposure to simulated sunlight 14 of 19 authentic rainwater samples exhibited significant decreases in H₂O₂. The concentration of hydrogen peroxide did not change significantly in organic-free synthetic rainwater spiked with H₂O₂ in the light or in dark controls suggesting that the loss was not due to direct photolysis or dark mediated reactions. There was a significant correlation between pseudo-first order rate constants of H₂O₂ decay and initial H₂O₂ concentrations. There was also a significant correlation between the rate constant and the abundance of DOC suggesting that rainwater organic carbon plays an important role during photolytic decay either via direct reaction or indirectly through production of peroxide reactive species or scavenging of peroxide generating radicals. Several rain samples exhibited an initial increase in H₂O₂ during the first 2 h of irradiation. These increases were generally small and most likely do not represent a significant input of peroxide in precipitation. The photo-induced destruction of H₂O₂ is important because it may partly explain the late afternoon decrease of peroxide concentrations observed in earlier field studies and the substantial under saturation (<10%) of this oxidant in rainwater compared with gas phase concentrations.     

Air Quality,Climate, and Policy: A Case Study of Ozone Pollution in Tucson,Arizona

This article addresses the need to better understand the complex interactions between climate, human activities, vegetation responses, and surface ozone so that more informed air‐quality policy recommendations can be made. The impacts of intraseasonal climate variations on ozone levels in Tucson, Arizona from April through September of 1995 to 1998 are determined by relating variations in ozone levels to variations in atmospheric conditions and emissions of ozone's precursor chemicals, volatile organic compounds (VOCs) and nitrogen oxides (NO_x), and by determining month‐specific atmospheric conditions that are conducive to elevated ozone levels. Results show that the transport of ozone and its precursor chemicals within the Tucson area causes the highest ozone levels to be measured at a downwind monitor. The highest ozone levels occur in August, due in part to the presence of the North American monsoon. Atmospheric conditions conducive to elevated ozone concentrations differ substantially between the arid foresummer (May and June) and the core monsoon months ( July and August). Transport of pollution from Phoenix may have a substantial impact on elevated ozone concentrations during April, May, and June, while El Paso/Ciudad Juarez –derived pollution may contribute significantly to elevated ozone concentrations in August and September. Two broad policy implications derive from this work. Regional pollutant transport, both within the U.S. and between the U.S. and Mexico, is a potential issue that needs to be examined more intensively in future studies. In addition, spatiotemporal variations in sensitivities of ozone production require the adoption of both NO_x and VOC control measures to reduce ozone levels in the Tucson area.