Eckfeld Maar: Window into an Eocene Terrestrial Habitat in Central Europe

<正>To mark the occasion of the 175th anniversary of the Rheinische Naturforschende Gesellschaft in 2009 and of the centennial of the Mainz Natural History Museum in 2010,we present a short account of our present knowledge of the Eckfeld Maar after 20 years of continuous research.This paper does not attempt to include all of the detailed results on the geology of the Eckfeld site or its biota.To date,nearly 250 papers and books have been published since the start of our project.An up-to-date list of these publications can be found at www.eckfeldermaar. de.     

Predicting riverine dissolved silica fluxes to coastal zones from a hyperactive region and analysis of their first-order controls

Silicate weathering and resulting transport of dissolved matter influence the global carbon cycle in two ways. First by the uptake of atmospheric/soil CO₂ and second by providing the oceanic ecosystems via the fluvial systems with the nutrient dissolved silica (DSi). Previous work suggests that regions dominated by volcanics are hyperactive or even “hot spots” concerning DSi-mobilization. Here, we present a new approach for predicting DSi-fluxes to coastal zones, emphasizing “first-order” controlling factors (lithology, runoff, relief, land cover and temperature). This approach is applied to the Japanese Archipelago, a region characterized by a high percentage of volcanics (29.1% of surface area). The presented DSi-flux model is based on data of 516 catchments, covering approximately 56.7% of the area of the Japanese Archipelago. The spatial distribution of lithology—one of the most important first order controls—is taken from a new high resolution map of Japan. Results show that the Japanese Archipelago is a hyperactive region with a DSi-yield 6.6 times higher than the world average of 3.3 t SiO₂ km⁻² a⁻¹, but with large regional variations. Approximately 10% of its area exceeds 10 times the world average DSi-yield. Slope constitutes another important controlling factor on DSi-fluxes besides lithology and runoff, and can exceed the influence of runoff on DSi-yields. Even though the monitored area on the Japanese Archipelago stretches from about 31° to 46°N, temperature is not identified as a significant first-order model variable. This may be due to the fact that slope, runoff and lithology are correlated with temperature due to regional settings of the Archipelago, and temperature information is substituted to a certain extent by these factors. Land cover data also do not improve the prediction model. This may partly be attributed to misinterpreted land cover information from satellite images. Implications of results for Earth System and global carbon cycle modeling are discussed.     

A guideline for the evaluation of the soil radon potential based on geogenic and anthropogenic parameters

Following a brief review about radon (²²²Rn) in soils, this study gives a compilation and evaluation of important parameters of the soil ²²²Rn potential. Because investigations of the potential are usually limited to rural areas, anthropogenic or urban effects have not attracted much attention so far. Measurements within the densely populated Ruhr district (Germany) present some new insights into geogenic and anthropogenic parameters on the soil ²²²Rn potential. According to their importance, seven parameters were strung in aranking system, which can be applied in both rural and urban areas: made grounds, geology, relief, vegetation cover, tectonics, soil sealing, traffic vibrations. While the first four parameters control the soil ²²²Rn potential on a more regional scale, the last three can modify it locally. Furthermore, an evaluation of the potential within a ten-point-system is proposed. The advantage of the system lies in the possibility to estimate the soil ²²²Rn potential of any site on a local scale. Common classifications and rankings, based on insufficiently scaled maps, can be included in the proposed system.     

Assessing parameter identifiability for multiple performance criteria to constrain model parameters

ABSTRACT

Reliable simulations of hydrological models require that model parameters are precisely identified. In constraining model parameters to small ranges, high parameter identifiability is achieved. In this study, it is investigated how precisely model parameters can be constrained in relation to a set of contrasting performance criteria. For this, model simulations with identical parameter samplings are carried out with a hydrological model (SWAT) applied to three contrasting catchments in Germany (lowland, mid-range mountains, alpine regions). Ten performance criteria including statistical metrics and signature measures are calculated for each model simulation. Based on the parameter identifiability that is computed separately for each performance criterion, model parameters are constrained to smaller ranges individually for each catchment. An iterative repetition of model simulations with successively constrained parameter ranges leads to more precise parameter identifiability and improves model performance. Based on these results, a more consistent handling of model parameters is achieved for model calibration.     

U-Pb zircon and monazite dating of a mafic-ultramafic complex and its country rocks

U-Pb data on zircons from the largest mafic-ultramafic body (6×2 km) of the French Central Massif (Sauviat-sur-Vige) yield the following age results: Primary magmatic crystallization of the gabbroic and peridotitic protoliths took place in the Cambro-Ordovician (496±25/17 m.y.). Variable transformation under eclogite facies conditions was Hercynian (320±29/36 m.y.). The same age pattern, derived by U-Pb monazite analyses, was found also for the immediate country rocks, i.e. kyanite bearing, coarse-grained metagranites occurring to the W and N of the Sauviat massif. Due to the fact that there is no regional Hercynian high-grade metamorphism in this part of the French Central Massif (e.g. Duthou 1977; Bernard-Griffiths 1975), both mafic-ultramafic complex as well as immediate felsic country rocks must have been emplaced tectonically into pre-Hercynian (Acadian±Caledonian) crustal rocks. The cause for such a Hercynian tectonism is thought to be due to continent-continent collision of the Spanish with the Armorican plate. Preliminary U-Pb zircon results on one eclogite sample taken about 50 km S of the Sauviat complex indicate also an Early Palaeozoic age for the magmatic protolith and a Hercynian transformation into eclogite, combined with and/or followed by tectonic emplacement. However, opposite to the continental Sauviat massif, we are probably dealing here with oceanic material, possibly deposited in an Early Palaeozoic marginal sea basin. Thus, subduction and tectonic emplacement of oceanic crust into continental crust terminated in this area also in the Hercynian. Concerning U-Pb systematics of zircon and monazite the following conclusions can be drawn:

1. U-Pb systems of primary magmatic zircons of mafic and ultramafic rocks are only weakly disturbed during static eclogite facies metamorphism (T>820° C; P> 15 kbar);
2. New- and overgrowth of zircon during eclogite facies metamorphism seems to be the major cause for the degree of discordance;
3. Amphibolitization of metagabbros and eclogites had no effect on the degree of discordance of zircon;
4. U-Pb systems of monazites remained undisturbed during intense weathering of the mother rock.

     

U-Pb systematics of detrital zircons from some unmetamorphosed to slightly metamorphosed sediments of Central Europe

In an attempt to find the premetamorphic discordance pattern of detrital zircons extracted from Central European metasediments, unmetamorphosed or only slightly metamorphosed sediments were collected from two areas: (1) from the Montagne Noire, the southernmost part of the French Central Massif and (2) from the innerbohemian Algonkian (= Proterozoic) in the CSSR.The generally accepted hypothesis that zircons from Central European metasediments must have plotted close to or at the corresponding upper intercept between discordia trajectory and concordia curve prior to the metamorphism of the host rocks could not be supported. The zircon populations from sediments of both areas are similar in discordance to those of the numerous populations extracted from metasediments of the Central European basement complexes. However, in contrast to the latter, the data points of size fractions scatter considerably and reliable intercept ages cannot be calculated.In the case of the Cambro-Ordovician sand- and siltstones of the Montagne Noire, the ages of detrital muscovites strongly argue for a Cadomian (550–700 m.y.) provenance of the detritus. Thus, the strong discordance of the analyzed fractions most probably is caused by zircons newly formed and/or partly or completely reset during a Cadomian event in the provenance of the detritus. In addition, lattice unit parameters indicate that the detrital zircons must have been recrystallized after their primary formation more than 1.7 b.y. ago.The Algonkian sediments of Bohemia (CSSR) can be taken as the very low-grade metamorphic equivalents of the Moldanubian paragneisses from which discordia trajectories between about 2 b.y. and 460–320 m.y. are known (Gebauer and Grünenfelder, 1974; Grauert et al., 1974). Nevertheless, all analyzed zircon fractions are strongly discordant indicating that they probably recrystallized during the Assyntian (=Cadomian) very low-grade metamorphism of the host rock loosing most of their accumulated radiogenic lead. If such an interpretation is correct, the low-temperature recrystallization model of Gebauer and Grünenfelder (1976) can be applied to metamict zircons in host rocks formed at temperatures as low as 300 ° C. In our 1976-paper we gave temperatures of 350–400 ° C for the maximum temperature necessary to recrystallize metamict zircons in chlorite-grade quartzphyllites in agreement with the experimental results of Pidgeon et al. (1973).In contrast to the zircons of the Montagne Noire it can be shown that the U-Pb systems of the Algonkian zircons must have been re-opened in post-Assyntian time, probably recently or in the Tertiary. However, no plausible explanation can be given to account for this.     

Effect of an oil spill in Spitzbergen in 1978

The oil content in the sediment and the marine life along the arctic shores of Van Mijenfjord, Spitzbergen, were investigated about two years after a spill from diesel storage tanks. High values of oil were recorded in the sediment along the shore near the tanks. The shore fauna is generally poor in these areas and the only biological effect detected was the disappearance of the amphipod Gammarus setosus from the surface layers.     

Aquifer vulnerability to pesticide migration through till aquitards

This study investigates the influence of key factors-mainly recharge rate and degradation half-life--on downward migration of the widely used pesticide mecoprop (MCPP) through a typical clayey till aquitard. The study uses the numerical model FRAC3Dvs, which is a three-dimensional discrete fracture/matrix diffusion (DFMD) numerical transport model. The model was calibrated with laboratory and field data from a site near Havdrup, Denmark, but the overall findings are expected to be relevant to many other sites in similar settings. Fracture flow and MCPP transport parameters for the model were obtained through calibration using well-characterized laboratory experiments with large (0.5 m diameter by 0.5 m high) undisturbed columns of the fractured till and a field experiment. A second level of upscaling and sensitivity analysis was then carried out using data on hydraulic head, fracture spacing, and water budget from the field site. The simulations of downward migration of MCPP show that MCPP concentration and mass flux into the underlying aquifer, and hence the aquifer vulnerability to this pesticide compound, is mainly dependent on the degradation rate of the pesticide, the overall aquitard water budget, and the ground water recharge rate into the aquifer. The influence of flow rate, matrix diffusion, and degradation rate are intertwined. This results in one to four orders of magnitude higher MCPP flux into the aquifer from aquifer recharge rates of 20 and 120 mm/yr, respectively, for no degradation and MCPP half-life of 0.5 yr. From a sensitivity analysis it was found that the range of MCPP flux into the aquifer varied less than one order of magnitude due to (1) changing fracture spacing from 1 to 10 m, or (2) preferential flow along inclined thin sand layers, which represent common conditions for the current and other settings of clayey till in Denmark and other glaciated areas in Europe and North America. The results indicate that for aquifers overlain by fractured clayey tills, the vulnerability to contamination with pesticides (pesticide flux into the aquifer) and other widespread agricultural contaminants is going to vary strongly in the watershed as a function of the distribution of aquitard water budget (flow rate) and aquitard redox environment (controlling contaminant degradation rates), even if the thickness of the till is relatively constant. DFMD modeling of cause-effect relationships within such systems has great potential to support decisions in planning, regulation, and contaminant remediation.     

Geochemical evidence for mixing of magmatic fluids with seawater,Nisyros hydrothermal system,Greece

The chemical and isotopic compositions (δD_H2O, δ¹⁸O_H2O, δ¹⁸O_CO2, δ¹³C_CO2, δ³⁴S, and He/N₂ and He/Ar ratios) of fumarolic gases from Nisyros, Greece, indicate that both arc-type magmatic water and local seawater feed the hydrothermal system. Isotopic composition of the deep fluid is estimated to be +4.9±0.5‰ for δ¹⁸O and ?11±5‰ for δD corresponding to a magmatic water fraction of 0.7. Interpretation of the stable water isotopes was based on liquid–vapor separation conditions obtained through gas geothermometry. The H₂–Ar, H₂–N₂, and H₂–H₂O geothermometers suggest reservoir temperatures of 345±15 °C, in agreement with temperatures measured in deep geothermal wells, whereas a vapor/liquid separation temperature of 260±30 °C is indicated by gas equilibria in the H₂O–H₂–CO₂–CO–CH₄ system. The largest magmatic inputs seem to occur below the Stephanos–Polybotes Micros crater, whereas the marginal fumarolic areas of Phlegeton–Polybotes Megalos craters receive a smaller contribution of magmatic gases.