Processing of atmospheric organic matter by California radiation fogs

Considerable effort has been put into characterizing the ionic composition of fogs and clouds over the past twenty-five years. Recently it has become evident that clouds and fogs often contain large concentrations of organic material as well. Here we report findings from a series of studies examining the organic composition of radiation fogs in central California. Organic compounds in these fogs comprise a major fraction of total solute mass, with total organic carbon sometimes reaching levels of several tens of mg/L. This organic matter is comprised of a wide variety of compounds, ranging from low molecular weight organic acids to high molecular weight compounds with molecular masses approaching several hundred to a thousand g/mole. The most abundant individual compounds are typically formic acid, acetic acid, and formaldehyde. High concentrations are also observed of some dicarboxylic acids (e.g., oxalate) and dicarbonyls (e.g., glyoxal and methylglyoxal) and of levoglucosan, an anhydrosugar characteristically emitted by biomass combustion. Many other compounds have been identified in fog water by GC/MS, including long chain n-alkanoic acids, n-alkanes, PAH, and others, although these compounds typically comprise a total of only a few percent of fog TOC. Measurements of fog scavenging of organic and elemental carbon reveal preferential scavenging of organic carbon. Tracking of individual organic compounds utilized as source type markers suggests the fogs differentially scavenge carbonaceous particles from different source types, with more active processing of wood smoke than vehicle exhaust. Observations of high deposition velocities of fog-borne organic carbon, in excess of 1 cm/s, indicate that fogs in the region represent an important mechanism for cleansing the atmosphere of pollution.     

European glacial relict snails and plants: environmental context of their modern refugial occurrence in southern Siberia

Knowledge of present‐day communities and ecosystems resembling those reconstructed from the fossil record can help improve our understanding of historical distribution patterns and species composition of past communities. Here, we use a unique data set of 570 plots explored for vascular plant and 315 for land‐snail assemblages located along a 650‐km‐long transect running across a steep climatic gradient in the Russian Altai Mountains and their foothills in southern Siberia. We analysed climatic and habitat requirements of modern populations for eight land‐snail and 16 vascular plant species that are considered characteristic of the full‐glacial environment of central Europe based on (i) fossil evidence from loess deposits (snails) or (ii) refugial patterns of their modern distributions (plants). The analysis yielded consistent predictions of the full‐glacial central European climate derived from both snail and plant populations. We found that the distribution of these 24 species was limited to the areas with mean annual temperature varying from ?6.7 to 3.4 °C (median ?2.5 °C) and with total annual precipitation varying from 137 to 593 mm (median 283 mm). In both groups there were species limited to areas with colder and drier macroclimates (e.g. snails Columella columella and Pupilla loessica, and plants Kobresia myosuroides and Krascheninnikovia ceratoides), whereas other species preferred areas with relatively warmer and/or moister macroclimates (e.g. snails Pupilla turcmenica and P. alpicola, and plants Artemisia laciniata and Carex capillaris). Analysis of climatic conditions also indicated that distributional shifts of the studied species during the Pleistocene/Holocene transition were closely related to their climatic tolerances. Our results suggest that the habitat requirements of southern Siberian populations can provide realistic insights into the reconstruction of Eurasian, especially central European, glacial environments. Data obtained from modern populations also highlight the importance of wet habitats as refugia in the generally dry full‐glacial landscape.     

Plant source water apportionment using stable isotopes: A comparison of simple linear,two‐compartment mixing model approaches

Plant source water identification using stable isotopes is now a common practice in ecohydrological process investigations. Notwithstanding, little critical evaluation of the approaches for source apportionment have been conducted. Here, we present a critical evaluation of the main methods used for source apportionment between vadose and saturated zone water: simple mass balance and Bayesian mixing models. We leverage new isotope stem water samples from a diverse set of tree species in a strikingly uniform terrain and soil conditions at the Christchurch Botanic Garden, New Zealand. Our results show that using δ²H alone in a simple, two‐source mass balance approach leads to erroneous results, particularly an apparent overestimation of groundwater contribution to xylem. Alternatively, using both δ²H and δ¹⁸O in a Bayesian inference framework improves the source water estimates and is more useful than the simple mass balance approach, particularly when soil and groundwater contributions are relatively disproportionate. We suggest that plant source water quantification methods should take into consideration the possible effects of ²H/¹H fractionation. The Bayesian inference approach used here may be less sensitive to ²H/¹H fractionation effects than simple mass balance methods.     

Active layer hydrology in an arctic tundra ecosystem: quantifying water sources and cycling using water stable isotopes

Climate change and thawing permafrost in the Arctic will significantly alter landscape hydro‐geomorphology and the distribution of soil moisture, which will have cascading effects on climate feedbacks (CO₂ and CH₄) and plant and microbial communities. Fundamental processes critical to predicting active layer hydrology are not well understood. This study applied water stable isotope techniques (δ²H and δ¹⁸O) to infer sources and mixing of active layer waters in a polygonal tundra landscape in Barrow, Alaska (USA), in August and September of 2012. Results suggested that winter precipitation did not contribute substantially to surface waters or subsurface active layer pore waters measured in August and September. Summer rain was the main source of water to the active layer, with seasonal ice melt contributing to deeper pore waters later in the season. Surface water evaporation was evident in August from a characteristic isotopic fractionation slope (δ²H vs δ¹⁸O). Freeze‐out isotopic fractionation effects in frozen active layer samples and textural permafrost were indistinguishable from evaporation fractionation, emphasizing the importance of considering the most likely processes in water isotope studies, in systems where both evaporation and freeze‐out occur in close proximity. The fractionation observed in frozen active layer ice was not observed in liquid active layer pore waters. Such a discrepancy between frozen and liquid active layer samples suggests mixing of meltwater, likely due to slow melting of seasonal ice. This research provides insight into fundamental processes relating to sources and mixing of active layer waters, which should be considered in process‐based fine‐scale and intermediate‐scale hydrologic models. Copyright © 2016 John Wiley & Sons, Ltd.     

Speleothem and glacier records of latest Pleistocene–early Holocene climate change in the western North American interior

Rapid and high-magnitude North Atlantic climate oscillations following the Last Glacial Maximum have been correlated to climate change events in western North America. However, the strength of teleconnections between the North Atlantic and the interior of western North America remains poorly understood. We present a U-series calibrated speleothem record from Timpanogos Cave National Monument, located at 2040 m asl in the Wasatch Mountains of Utah, spanning 13.5–10.6 ka. Additionally, we carried out a climate reconstruction for a coeval glacier advance in the Wind River Range of Wyoming. Our results indicate that between 13.5 and 12.8 ka, the Wasatch was probably first cool and dry and then warmed. After 12.8 ka, our record suggests cool and/or wetter conditions followed by reduced moisture until 11.8 ka, followed by an early Holocene wet period. The Timpanogos record exhibits few similarities with those from the North Atlantic. Climate reconstructions of the Titcomb Basin glacier suggest modest temperature depressions relative to modern (<−3 °C) were necessary to sustain the glacier with a moderate increase in precipitation (>150%). The high-altitude speleothem record presented here provides a valuable basis for understanding latest Pleistocene–early Holocene glacial episodes in western North America.     

Winter precipitation isotope slopes of the contiguous USA and their relationship to the Pacific/North American (PNA) pattern

This study compares the synoptic-dynamic relationship between two phases of the Pacific/North American (PNA) pattern and winter precipitation isotopes at 73 sites across the contiguous USA. We use the spatial pattern of isotope slope—the rate of changes in precipitation isotope ratios with distance—to identify features in the seasonal precipitation isotope fields related to climatic patterns, PNA positive and PNA negative. Our results show relationships between zones of high isotope slopes and the spatial position of the polar jet stream and juxtaposition of air masses associated with the PNA pattern. During a positive PNA winter, zones of high isotope slope in the eastern USA shift southward. This change is coincident with a southward displacement of the polar jet stream in this region, which leads to a greater frequency of polar air masses and ¹⁸O-depleted isotope values of precipitation in the region. In the western USA, zones of high slope shift eastward during the positive PNA winter, associated with more frequent penetration of tropical air masses that bring ¹⁸O-enriched precipitation to the region. Differences in δ¹⁸O/temperature relationships between the PNA-positive and -negative winters and contrasting δ¹⁸O/temperature behaviors in the eastern and western USA provide support for the role of variation in moisture source and transport as a control on the isotopic patterns. These findings highlight the importance of synoptic climate driven by PNA pattern in determining the spatial patterns of precipitation isotopes and provide constraints on paleo-water isotope interpretation and modern isotope hydrological processes.     

Place attachment among retirees in Greensburg, Kansas

On 4 May 2007 an ef-5 tornado leveled 95 percent of Greensburg, Kansas. Because city leaders encouraged everyone to use “green” building techniques as they rebuilt their homes and businesses, not only has the return to normalcy been exceedingly slow, but some of the town's older residents feel that officials have overlooked their needs. These minor episodes of discord enabled us to learn what features are most important to people in retirement. The features include identifiable landmarks, a space in which to socialize, and age-specific businesses. We assert that the lessons learned in Greensburg are applicable to other communities with a sizable older population. As baby boomers rapidly enter retirement they will seek places to live that are elder friendly and enable them to effectively bond with place. As previous research attests, people who have a strong attachment to place commonly have a good quality of life.