Semipermeable membrane devices link site-specific contaminants to effects: Part 1 - Induction of CYP1A in rainbow trout from contaminants in Prince William Sound, Alaska

Extracts from semi-permeable membrane devices (SPMDs) deployed on beaches in Prince William Sound (PWS), Alaska, were used to evaluate if complex contaminant mixtures from different sources can be distinguished by the resulting cytochrome P450 1A (CYP1A) activity in exposed test animals. Deployment sites included canneries, salmon hatcheries, and beaches where lingering oil remains from discharges during the 1964 earthquake or the 1989 Exxon Valdez oil spill. Other sites were selected at random to evaluate region-wide contaminant inputs or were located in salmon streams to evaluate contaminants carried and released by migrating salmon carcasses following reproduction. Following standard deployments of approximately 28 d, an aliquot of the accumulated contaminants was intraperitoneally injected without cleanup into juvenile rainbow trout (Oncorhynchus mykiss). After 2 d and 7 d, the activity of CYP1A was measured by the ethoxyresorufin-o-deethylase (EROD) assay. Exposure to extracts from the oiled sites and one hatchery site with numerous creosote pilings elicited strong EROD responses, whereas fish exposed to salmon stream extracts elicited weak but significant responses during late summer compared to late spring. Responses from the other sites were not significant, indicating contaminants from these sources are unlikely to cause CYP1A induction in resident biota. Rather than simply assessing extant contaminants, this method evaluates the potency of the different sites for bringing about aryl hydrocarbon receptor responses in resident biota.     

Comparative biomass structure and estimated carbon flow in food webs in the deep Gulf of Mexico

A budget of the standing stocks and cycling of organic carbon associated with the sea floor has been generated for seven sites across a 3-km depth gradient in the NE Gulf of Mexico, based on a series of reports by co-authors on specific biotic groups or processes. The standing stocks measured at each site were bacteria, Foraminifera, metazoan meiofauna, macrofauna, invertebrate megafauna, and demersal fishes. Sediment community oxygen consumption (SCOC) by the sediment-dwelling organisms was measured at each site using a remotely deployed benthic lander, profiles of oxygen concentration in the sediment pore water of recovered cores and ship-board core incubations. The long-term incorporation and burial of organic carbon into the sediments has been estimated using profiles of a combination of stable and radiocarbon isotopes. The total stock estimates, carbon burial, and the SCOC allowed estimates of living and detrital carbon residence time within the sediments, illustrating that the total biota turns over on time scales of months on the upper continental slope but this is extended to years on the abyssal plain at 3.6 km depth. The detrital carbon turnover is many times longer, however, over the same depths. A composite carbon budget illustrates that total carbon biomass and associated fluxes declined precipitously with increasing depth. Imbalances in the carbon budgets suggest that organic detritus is exported from the upper continental slope to greater depths offshore.The respiration of each individual “size” or functional group within the community has been estimated from allometric models, supplemented by direct measurements in the laboratory. The respiration and standing stocks were incorporated into budgets of carbon flow through and between the different size groups in hypothetical food webs. The decline in stocks and respiration with depth were more abrupt in the larger forms (fishes and megafauna), resulting in an increase in the relative predominance of smaller sizes (bacteria and meiofauna) at depth. Rates and stocks in the deep northern GoM appeared to be comparable to other continental margins where similar comparisons have been made.     

Variation in the composition and partitioning of adsorbed cations at a brine-contaminated crude oil production facility in southeastern Louisiana,USA

The first geological materials impacted by oil field wastes released into near-surface environments in southern Louisiana, USA, are typically clays and silts. Clay minerals within these siliciclastic sediments have the potential for altering the composition of produced water wastes through cation exchange. The general relations between the composition of adsorbed cations and interstitial water salinity in brine-contaminated samples from a site in southeastern Louisiana are consistent with previous studies of multicomponent exchange in groundwater systems of varying salinity. The divalent cations Ca and Mg dominate as adsorbed cations at low salinities (<1200 mg/L), but Na is dominant at moderate to high salinities (up to 53,000 mg/L). The change in the proportions of adsorbed cations is a non-linear function of salinity, and the transition from Ca-dominated adsorption to Na-dominated adsorption occurs over a narrow range of salinities.     

Bivariate conditional sampling of buoyancy flux during an intense cold-air outbreak

Buoyancy fluxes in the marine atmospheric boundary layer (MABL) for the cloud street regime, observed during the Genesis of Atlantic Lows Experiment (GALE), have been analyzed using the technique of joint frequency distribution. For the lower half of the MABL, the results suggest that the buoyancy flux is mainly generated by the rising thermals and the sinking compensating ambient air, and is mainly consumed by the entrainment and detrainment of thermals, penetrative convection, and the entrainment from the MABL top.The results are compared to those from previous studies of mesoscale cellular convection (Air-Mass Transformation Experiment, AMTEX), the dry convective boundary layer, and the trade-wind MABL. For the lower MABL, the quadrant buoyancy fluxes, fractional coverages, and flux intensities are in good agreement with those of mesoscale cellular convection (AMTEX) and the dry convective boundary layer. The results suggest that, if the buoyancy flux is primarily driven by the temperature flux, the physical processes for generating buoyancy flux mentioned above are about the same for the lower boundary layers over land and ocean, even with different convective regimes. For the trade-wind MABL, the buoyancy flux is mainly driven by the moisture flux; the quadrant flux intensities are stronger than those of the other three studies except for the buoyant updrafts (thermals). These results suggest that the entrainment and detrainment of thermals are more effective in the trade-wind MABL than in the boundary layers driven by the temperature flux.Scale analysis of the buoyancy flux is in good agreement with that of AMTEX. For the lower half of the MABL, the buoyancy flux is mainly generated by the intermediate scale (200 m to 2 km), which includes the dominant convective thermals in the surface layer and the mixed layer. The scale smaller than 200 m is important only in the surface layer. The scale larger than 2 km, which includes the roll vortices, increases its significance upward. While most of the positive and negative fluxes are associated with the updrafts for the intermediate scale, the downdrafts are as important as updrafts for the larger scale.ST Systems Corporation, Lanham, MD, 20706, U.S.A.     

Bridging arsenate surface complexes on the hematite (0 1 2) surface

The fate of the oxoanion arsenate in diverse systems is strongly affected by its adsorption on the surfaces of iron (oxyhydr)oxide minerals. Predicting this behavior in the environment requires an understanding of the mechanisms of arsenate adsorption. In this study, the binding site and adsorption geometry of arsenate on the hematite (0 1 2) surface is investigated. The structure and termination of the hematite (0 1 2)-water interface were determined by high resolution X-ray reflectivity, revealing that two distinct terminations exist in a roughly 3:1 proportion. The occurrence of multiple terminations appears to be a result of sample preparation, and is not intrinsic to the hematite (0 1 2) surface. X-ray standing wave (XSW) measurements were used to determine the registry of adsorbed arsenate to the hematite structure, and thus the binding site and geometry of the resulting surface complex. Arsenate forms a bridging bidentate complex on two adjacent singly coordinated oxygen groups on each of the two distinct terminations present at the hematite surface. Although this geometry is consistent with that seen in past studies, the derived As-Fe distances are longer, the result of the topology of the FeO₆ octahedra on the (0 1 2) surface. As EXAFS-derived As-Fe distances are often used to determine the adsorption mechanism in environmental samples (e.g., mine tailings, contaminated sediments), this demonstrates the importance of considering the possible sorbent surface structures and arrangements of adsorbates when interpreting such data.As multiple functional groups are present and multiple binding geometries are possible on the hematite (0 1 2) surface, the XSW data suggest that formation of bridging bidentate surface complexes on singly coordinated oxygen sites is the preferred adsorption mechanism on this and most other hematite surfaces (provided those surfaces contain adjacent singly coordinated oxygen groups). These measurements also constrain the likely reaction stoichiometry, with only the protonation state of the surface complex undetermined. Although bridging bidentate inner-sphere surface complexes comprised the majority of the adsorbed arsenate present on the hematite (0 1 2) surface, there is an additional population of sorbed arsenate species that could not be characterized by the XSW measurements. These species are likely more disordered, and thus more weakly bound, than the bridging bidentate complexes, and may play a role in determining the fate, transport, and bioavailability of arsenate in the environment. Finally, the possibility of obtaining species-specific XSW measurements by tuning the incident beam energy to specific features in a XANES spectrum is described.     

西安地区地热水和渭北岩溶水同位素特征及相互关系

依据采自西安地区300到3000米深地热井中地热水的水化学成分和同位素成分,确定出地热水的主要补给源和循环路径。地热水δ~(18)O 值变化于-11.8‰～-3.1‰VSMOW 之间,而δD 值变化幅度很小,在-87～-80‰VSMOW 之间,与西安市区现代大气降水的δD 值(～-60‰VSMOW)明显不同。在δ~(18)O～δD 关系图上,浅层地热水(〈1500米〉落在大气降水线上,而深层地热水(>1500米)向右侧偏离了大气降水线,呈现显著的氧同位素正向漂移现象。氧同位素由秦岭山前向盆地内部逐渐富集,在盆地内部随井深成正相关。据此判断,西安地热水的补给区位于秦岭山区。~(14)C 值表现为与氧同位素相反的变化趋势,~(14)C 年龄值在6,000～30,000年之间,表明地热水的地下循环时间很长。由井间~(14)C 年龄差异估算出从南到北地热水平均流速为1.7米/年,从西到东为2.5米/年。这些特征与渭北岩溶水截然不同,表明西安地区地热水与渭北岩溶水之间,虽然在空间上有密切联系,但分属于不同的水文地质单元,有各自独立的补径排系统。     

Comparison of Measured and Numerically Simulated Turbulence Statistics in a Convective Boundary Layer Over Complex Terrain

The Weather Research and Forecasting (WRF) model can be used to simulate atmospheric processes ranging from quasi-global to tens of m in scale. Here we employ large-eddy simulation (LES) using the WRF model, with the LES-domain nested within a mesoscale WRF model domain with grid spacing decreasing from 12.15 km (mesoscale) to 0.03 km (LES). We simulate real-world conditions in the convective planetary boundary layer over an area of complex terrain. The WRF-LES model results are evaluated against observations collected during the US Department of Energy-supported Columbia Basin Wind Energy Study. Comparison of the first- and second-order moments, turbulence spectrum, and probability density function of wind speed shows good agreement between the simulations and observations. One key result is to demonstrate that a systematic methodology needs to be applied to select the grid spacing and refinement ratio used between domains, to avoid having a grid resolution that falls in the grey zone and to minimize artefacts in the WRF-LES model solutions. Furthermore, the WRF-LES model variables show large variability in space and time caused by the complex topography in the LES domain. Analyses of WRF-LES model results show that the flow structures, such as roll vortices and convective cells, vary depending on both the location and time of day as well as the distance from the inflow boundaries.     

An oxygen isotopic profile through the upper kilometer of the oceanic crust, DSDP Hole 504B

DSDP Hole 504B is the deepest basement hole in the oceanic crust, penetrating through a 571.5 m pillow section, a 209 m lithologic transition zone, and 295 m into a sheeted dike complex. An oxygen isotopic profile through the upper crust at Site 504 is similar to that in many ophiolite complexes, where the extrusive section is enriched in¹⁸O relative to unaltered basalts, and the dike section is variably depleted and enriched. Basalts in the pillow section at Site 504 haveδ¹⁸O values generally ranging from +6.1 to +8.5‰ SMOW(mean= +7.0‰), although minor zeolite-rich samples range up to 12.7‰. Rocks depleted in¹⁸O appear abruptly at 624 m sub-basement in the lithologic transition from 100% pillows to 100% dikes, coinciding with the appearance of greenschist facies minerals in the rocks. Whole-rock values range to as low as +3.6‰, but the mean values for the lithologic transition zone and dike section are +5.8 and +5.4‰, respectively.

Oxygen and carbon isotopic data for secondary vein minerals combined with the whole rock data provide evidence for the former presence of two distinct circulation systems separated by a relatively sharp boundary at the top of the lithologic transition zone. The pillow section reacted with seawater at low temperatures (near 0°C up to a maximum of around 150°C) and relatively high water/rock mass ratios (10–100); water/rock ratios were greater and conditions were more oxidizing during submarine weathering of the uppermost 320 m than deeper in the pillow section. The transition zone and dikes were altered at much higher temperatures (up to about 350°C) and generally low water/rock mass ratios ( 1), and hydrothermal fluids probably contained mantle-derived CO₂. Mixing of axial hydrothermal fluids upwelling through the dike section with cooler seawater circulating in the overlying pillow section resulted in a steep temperature gradient ( 2.5°C/m) across a 70 m interval at the top of the lithologic transition zone. Progressive reaction during axial hydrothermal metamorphism and later off-axis alteration led to the formation of albite- and Ca-zeolite-rich alteration halos around fractures. This enhanced the effects of cooling and¹⁸O enrichment of fluids, resulting in local increases inδ¹⁸O of rocks which had been previously depleted in¹⁸O during prior axial metamorphism.     

Numerical Simulation of the 2011 Tohoku Tsunami Based on a New Transient FEM Co-seismic Source: Comparison to Far- and Near-Field Observations

In this work, we simulate the 2011 M9 Tohoku-Oki tsunami using new coseismic tsunami sources based on inverting onshore and offshore geodetic data, using 3D Finite Element Models (FEM). Such FEMs simulate elastic dislocations along the plate boundary interface separating the stiff subducting Pacific Plate from the relatively weak forearc and volcanic arc of the overriding Eurasian plate. Due in part to the simulated weak forearc materials, such sources produce significant shallow slip (several tens of meters) along the updip portion of the rupture near the trench. To assess the accuracy of the new approach, we compare observations and numerical simulations of the tsunami's far- and near-field coastal impact for: (i) one of the standard seismic inversion sources (UCSB; Shao et al. 2011); and (ii) the new FEM sources. Specifically, results of numerical simulations for both sources, performed using the fully nonlinear and dispersive Boussinesq wave model FUNWAVE-TVD, are compared to DART buoy, GPS tide gauge, and inundation/runup measurements. We use a series of nested model grids with varying resolution (down to 250 m nearshore) and size, and assess effects on model results of the latter and of model physics (such as when including dispersion or not). We also assess the effects of triggering the tsunami sources in the propagation model: (i) either at once as a hot start, or with the spatiotemporal sequence derived from seismic inversion; and (ii) as a specified surface elevation or as a more realistic time and space-varying bottom boundary condition (in the latter case, we compute the initial tsunami generation up to 300 s using the non-hydrostatic model NHWAVE). Although additional refinements are expected in the near future, results based on the current FEM sources better explain long wave near-field observations at DART and GPS buoys near Japan, and measured tsunami inundation, while they simulate observations at distant DART buoys as well or better than the UCSB source. None of the sources, however, are able to explain the largest runup and inundation measured between 39.5° and 40.25°N, which could be due to insufficient model resolution in this region (Sanriku/Ria) of complex bathymetry/topography, and/or to additional tsunami generation mechanisms not represented in the coseismic sources (e.g., splay faults, submarine mass failure). This will be the object of future work.     

Analytic signal approach and its applicability in environmental magnetic investigations

We investigate the analytic signal method and its applicability in obtaining source locations of compact environmental magnetic objects. Previous investigations have shown that, for two-dimensional magnetic sources, the shape and location of the maxima of the amplitude of the analytic signal (AAS) are independent of the magnetization direction. In this study, we show that the shape of the AAS over magnetic dipole or sphere source is dependent on the direction of magnetization and, consequently, the maxima of the AAS are not always located directly over the dipolar sources. Maximum shift in the horizontal location is obtained for magnetic inclination of 30°. The shifts of the maxima are a function of the source-to-observation distance and they can be up to 30% of the distance. We also present a method of estimating the depths of compact magnetic objects based on the ratio of the AAS of the magnetic anomaly to the AAS of the vertical gradient of the magnetic anomaly. The estimated depths are independent of the magnetization direction. With the help of magnetic anomalies over environmental targets of buried steel drums, we show that the depths can be reliably estimated in most cases. Therefore, the analytic signal approach can be useful in estimating source locations of compact magnetic objects. However, horizontal locations of the targets derived from the maximum values of the AAS must be verified using other techniques.