Extent and magnitude of copper contamination in marinas of the San Diego region, California, USA

Marinas are areas of special water quality concern because of the potential for pollutant accumulation within their protected waters. Perhaps the largest contaminant source to marinas is antifouling paints that leach copper to prevent the growth of encrusting organisms on vessel bottoms. Very little monitoring of marinas is typically conducted despite the potential environmental risk, particularly in the San Diego region of California, USA where as many as 17,000 recreational vessels are berthed. The objective of this study was twofold: (1) determine the extent and magnitude of dissolved copper concentrations in marinas throughout the San Diego region, and (2) determine if elevated copper concentrations in marinas of the San Diego region are resulting in adverse biological impacts. A probabilistic study design was used to sample water column copper concentrations and toxicity (using Mytilus galloprovincialis) at 30 stations. Results indicated that exceedence of state water quality objectives was widespread (86% of marina area), but that toxicity was much less prevalent (21% of marina area). Toxicity identification evaluations (TIEs) conducted at the most toxic sites indicated that toxicity was largely due to trace metals, most likely copper. Toxicity was reduced using TIE treatments that chelated trace metals such as cation exchange column, ethylenediaminetetraacetic acid (EDTA), and sodium thiosulfate (STS). Moreover, increasing dissolved copper concentrations correlated with increasing toxicity and these copper concentrations were high enough to account for virtually all of the observed toxicity.     

Rapid inactivation of seven Bacillus spp. under simulated Mars UV irradiation

Seven Bacillus spp. were exposed to simulations of Mars-normal UV fluence rates in order to study the effects of UV irradiation on microbial survival. A UV illumination system was calibrated to deliver 9.78 W m⁻² (35.2 kJ m⁻² h⁻¹) of UVC + UVB irradiation (200-320 nm) to microbial samples, thus creating a clear-sky simulation (0.5 optical depth) of equatorial Mars. The Bacillus spp. studied were: B. licheniformis KL-196, B. megaterium KL-197, B. nealsonii FO-092, B. pumilus FO-36B, B. pumilus SAFR-032, B. subtilis 42HS1, and B. subtilis HA101. The bacteria were prepared as thin monolayers of endospores on aluminum coupons in order to simulate contaminated spacecraft surfaces. Bacterial monolayers were exposed to Mars UV irradiation for time-steps of 0, 0.25, 0.5, 1, 5, 15, 30, 60, 120, or 180 min. The surviving endospores were then assayed with a Most Probable Numbers (MPN) procedure and with a culture-based assay that utilized a bacillus spore germination medium. Results indicated that B. pumilus SAFR-032 was the most resistant, and B. subtilis 42HS-1 and B. megaterium were the most sensitive of the seven strains exposed to martian UV fluence rates. Bacillus subtilis 42HS1 and B. megaterium were inactivated after 30 min exposure to Mars UV, while B. pumilus SAFR-032 required 180 min for full inactivation in both assays. Spores of B. pumilus SAFR-032 exhibited significantly different inactivation kinetics suggesting that this wild type isolate also was more resistant than the standard dosimetric strain, B. subtilis HA101. Although the various Bacillus spp. exhibited diverse levels of UV resistance, none were immune to UV irradiation, and, thus, all species would be expected to be inactivated on Sun-exposed spacecraft surfaces within a few tens-of-minutes to a few hours on sol 1 under clear-sky conditions on equatorial Mars. The inactivation kinetics of all seven Bacillus spp. support the conclusion that significant levels of bioload reductions are possible on Sun-exposed spacecraft surfaces in very short time periods under clear-sky conditions on Mars. However, the presence of UV resistant microbes on spacecraft surfaces rapidly covered in dust during landing operations, and non-Sun-exposed surfaces of spacecraft remain concerns that must continue to be addressed through adequate spacecraft sanitizing procedures prior to launch.     

Carbon,nitrogen, and water stable isotopes in plant tissue and soils across a moisture gradient in Puerto Rico

Stable isotopes in the water molecule (²H or D and ¹⁸O), carbon, and nitrogen are useful tracers and integrators of processes in plant ecohydrological systems across scales. Over the last few years, there has been growing interest in regional to continental scale synthesis of stable isotope data with a view to elucidating biogeochemical and ecohydrological patterns. Published datasets from the humid tropics, however, are limited. To be able to contribute to bridging the “data gap” in the humid tropics, here, we publish a relatively novel and unique suite of δ¹³C, δ¹⁵N, δ²H, and δ¹⁸O isotope data from three sites across a moisture gradient and contrasting land use in Puerto Rico. Plant tissue (xylem and leaf) samples from two species of mahogany (Swietenia macrophylla and Swietenia mahagoni) and soil samples down to 60 cm in the soil profile were collected in relatively “wet” (July 2012) and “dry” (February 2013) periods at two sites in northeastern (Luquillo) and southwestern (Susua) Puerto Rico. The same sampling suite is also being made available from a highly urbanized site in the capital San Juan. Leaf samples taken in July 2012 and February 2013 were analyzed for δ¹³C and δ¹⁵N; all xylem and bulk soil samples were analyzed for δ²H and δ¹⁸O. Soil samples taken in July 2012 were analyzed for δ¹³C and δ¹⁵N. Leaf δ¹⁵N and δ¹³C dataset showed patterns that are possibly associated with site differences. While spatial patterns were also apparent in soil δ¹⁵N and δ¹³C dataset, the positively linear δ¹⁵N –δ¹³C relationship tends to weaken with site moisture. Soil depth and site moisture patterns were also observed in the δ²H and δ¹⁸O datasets of bulk soil and xylem samples. The purpose of these datasets is to provide baseline information on soil–plant water (δ²H and δ¹⁸O, N = 319), δ¹³C (N = 272), and δ¹⁵N (N = 269) that may be useful in a wide range of research questions from ecohydrological relations to biogeochemical patterns in soils and vegetation.     

An assessment of large-scale flood modelling based on LiDAR data

Large-scale flood modelling approaches designed for regional to continental scales usually rely on relatively simple assumptions to represent the potentially highly complex river bathymetry at the watershed scale based on digital elevation models (DEMs) with a resolution in the range of 25–30 m. Here, high-resolution (1 m) LiDAR DEMs are employed to present a novel large-scale methodology using a more realistic estimation of bathymetry based on hydrogeomorphological GIS tools to extract water surface slope. The large-scale 1D/2D flood model LISFLOOD-FP is applied to validate the simulated flood levels using detailed water level data in four different watersheds in Quebec (Canada), including continuous profiles over extensive distances measured with the HydroBall technology. A GIS-automated procedure allows to obtain the average width required to run LISFLOOD-FP. The GIS-automated procedure to estimate bathymetry from LiDAR water surface data uses a hydraulic inverse problem based on discharge at the time of acquisition of LiDAR data. A tiling approach, allowing several small independent hydraulic simulations to cover an entire watershed, greatly improves processing time to simulate large watersheds with a 10-m resampled LiDAR DEM. Results show significant improvements to large-scale flood modelling at the watershed scale with standard deviation in the range of 0.30 m and an average fit of around 90%. The main advantage of the proposed approach is to avoid the need to collect expensive bathymetry data to efficiently and accurately simulate flood levels over extensive areas.     

Timing and distribution of calciturbidites around a deeply submerged carbonate platform in a seismically active setting (Pedro Bank, Northern Nicaragua Rise, Caribbean Sea)

The sedimentological study of thirteen sediment cores from the periplatform setting surrounding Pedro Bank (Northern Nicaragua Rise, Caribbean Sea) shows that during the last 300 ka turbidite deposition is controlled by at least four factors: (1) late Quaternary sea level fluctuations, (2) prolific fine-grained sediment production and export resulting in oversteepening of the upper slope environment, (3) the proximity to the bank margin, and (4) local slope and seafloor morphology. The most intriguing finding of this study is the paucity of turbidites, with only 101 turbidites in 13 cores in this tectonically active setting near the Caribbean plate boundary. Throughout the last 300 ka, the frequency of turbidite input during interglacial stages is three times higher than during glacial stages. Also it is obvious that changes in sea level influence the timing of turbidite deposition. This is especially evident during the transgressions resulting in rapid renewed bank-top flooding, subsequent neritic sediment overproduction, and offbank export. The flooding event during each transgression is usually recorded by the onset of turbidite deposition at various sites along several platform-to-basin transects in down- and upcurrent slope settings. Overall, however, more turbidites are deposited during the regressive rather than the transgressive phases in sea level, probably as a result of sediment reorganisation on the slope resulting in slope failure. Five cores show "highstand bundling" of calciturbidites, i.e. higher number of turbidites during highstands than during lowstands in sea level.     

Religion and governmentality: Understanding governance in urban Brazil

In this paper I argue that geographies of religion are fundamental to understanding governance and social order in contemporary urban space. More specifically, I show how Foucault’s notion of governmentality characterizes regimes of power beyond the state apparatus, positing that religion and churches also produce and maintain the knowledges, truths, and social order associated with governmentality and self-regulated governance. By considering the geography of religion literature within the context of Foucualt’s work, I illustrate the importance of religious and spiritual practices to contemporary urban space, and the roles they play in producing and maintaining governance and socio-political order. My purpose is not to suggest that governmentality has been misapplied as a theoretical tool for understanding the state and political power, but to show how the term actually describes power more generally, including spiritual moments in addition to political ones. Drawing from my case study in Fortaleza, Brazil, I substantiate my theoretical argument using empirical examples, showing how governmentality is produced through religion and churches and the relationship between spiritual practices and governance in everyday space.     

Understanding and managing the stressed Mexico-USA transboundary Hueco bolson aquifer in the El Paso del Norte region as a complex system

As the latest drought has swept over the southwestern United States, most local and regional water providers have had to rely on ground water to meet their water demands as surface water supplies have diminished. In areas near major population centers this situation has continued to put strain and stress on already over-drafted regional aquifers. Metropolitan centers throughout the southwestern United States, as exemplified by Las Vegas, Nevada; Phoenix and Tucson, Arizona; and El Paso, Texas, have a history of over drafting their available ground water resources. How these stressed aquifers should be managed is an urgent issue. In El Paso, Texas long-term groundwater mining in the transboundary Hueco bolson aquifer has resulted in large water level drawdowns within the basin, particularly in several well fields. This situation has promoted the intrusion of brackish water into fresh water zones, and consequently reduced the volume of fresh water stored in the aquifer. Management of this aquifer is made more complex as the water resources of the region are shared across the United States/Mexico boundary and the transboundary region continues to grow rapidly. This paper describes the current situation within the Hueco bolson due to over drafting and continued reliance on the fresh water in storage and describes how understanding the dynamics of the aquifer as a complex system can offer managerial perspectives that can be used to establish operational procedures and programs for bringing drawdowns into equilibrium, increasing the longevity of the aquifer, gradually restoring water quality, and offering the hope of utilization of the resource in a sustainable manner.

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Resumen A medida que la última sequía ha pasado ligeramente sobre el suroeste de Estados Unidos la mayoría de abastecedores locales y regionales de agua han tenido que depender del agua subterránea para satisfacer sus demandas de agua debido a que las fuentes de agua superficial han disminuido. En áreas cerca de centros poblados principales esta situación ha continuado ejerciendo presión en los ya sobre explotados acuíferos regionales. Los centros metropolitanos en todo el suroeste de Estados Unidos, por ejemplo Las Vegas, Nevada; Fénix y Tucson, Arizona; y El Paso, Texas tienen una historia de sobre explotar los recursos de agua subterránea disponibles.La gestión de estos acuíferos estresados constituye un problema urgente. En El Paso, Texas el minado de agua subterránea a largo plazo en el acuífero transnacional Hueco bolsón ha resultado en varios campos de pozos. Esta situación ha promovido la intrusión de agua salobre hacia zonas con agua fresca y reducido consecuentemente el volumen de agua fresca almacenado en el acuífero. El manejo de este acuífero se hace más complejo debido a que los recursos hídricos de la región son compartidos a través del límite Estados Unidos/México y la región transnacional continúa creciendo rápidamente. Este artículo describe la situación actual dentro del Hueco bolsón debido a la sobre explotación y continua dependencia en el agua fresca almacenada y describe como el entendimiento de la dinámica del acuífero como un sistema complejo puede ofrecer perspectivas de gestión que pueden utilizarse para establecer procedimientos operacionales y programas que conduzcan al equilibrio de los descensos, aumentando la longevidad del acuífero, gradualmente restaurando la calidad del agua, y ofreciendo la esperanza de utilizar el recurso de manera sostenible.

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Résumé Alors que la dernière sécheresse a atteint toute la partie Sud-Ouest des Etats-Unis, la plus part des distributeurs deau, locaux et régionaux, doivent sapprovisionner en eau souterraine dés lors que les niveaux des eaux de surface ont diminués. Dans les zones proches des grands centres densément peuplés, cette situation a continuée a altérée des aquifères déjà surexploités. Les centres métropolitains du Sud-Ouest des Etats-Unis (Las Vegas dans le Nevada, Phoenix et Tucson dans lArizona, El Paso au Texas) sont connus historiquement pour surexploités leurs ressources en eaux souterraines. Il devient urgent de définir un mode de gestion de ses aquifères surexploités. A El Paso dans le Texas, le minage de laquifère transfrontalier engendre un rabattement important dans le bassin, et plus particulièrement autour des zones de captage. Cette situation a induit lintrusion deaux saumâtres dans des zones deaux douces, et a par conséquent réduit le volume deau douce stockée et exploitable dans laquifère. La gestion de cet aquifère est par ailleurs complexifiée par la situation transfrontalière, dautant que la zone frontalière connaît une croissance rapide. Cet article décrit la situation actuelle dans la vallée fermée du Hueco, due au sur-rabattement et à lexploitation continue des eaux douces, et décrit comment la compréhension de laquifère, vu comme un système complexe, peut offrir des perspectives de gestion amenant à des procédures opérationnelles et à des programmes à long terme permettant de ramener à léquilibre la baisse des niveaux deau. Ainsi la longévité de laquifère sera mieux garantie, la qualité de leau sera graduellement restaurée et lutilisation de leau respectera le souci de développement durable.