A Method for the Exploratory Analysis of Airline Networks

The airline industry in the United States has experienced significant changes in the spatial configuration of networks since the Airline Deregulation Act of 1978. Attempts have been made to study the structure of the hub-and-spoke network in the airline industry, but no efficient methodology has been available. This paper describes an exploratory approach to analyzing the spatial configuration of airline networks. Flight frequencies and numbers of passengers from published schedules of six U.S. domestic airlines (American, Continental, Delta, Northwest, United, and USAir) are used in this study. The analytic components in the exploratory system include the examination of network connectivity and network autocorrelation in a dynamic mapping environment. The results of the analyses show both the overall spatial patterns of airline networks and the hierarchical hubbing structures.     

A high sensitivity, low volume HPLC method to determine soluble reactive phosphate in freshwater and saltwater

A reverse phase High Performance Liquid Chromatography (HPLC) method was developed to detect soluble reactive phosphate (SRP) in marine and freshwater samples. This technique is scalable over a range of sample volumes from 10 μl to 10 ml, requires minimal sample preparation, and responds linearly from 1 nM to 100 μM (R²>0.964). Standard Murphy–Riley molybdenum blue reagents were used to react with phosphate in samples for analysis. Solid phase extraction tubes were used to clean the mixed complexing reagent prior to combining the reagent with samples. The method was applied to freshwater samples collected in July 2001 along an Andean mountain stream located in the Eastern Cordillera (2400 m) of Peru and marine samples collected in January 2002 within the low marsh of the estuarine Nueces Delta System, Texas Coastal Bend. For method comparison, field samples were analyzed using a standard manual spectrophotometric method. Field sample phosphate concentrations produced from each method were nearly identical. This method offers the advantages of low sample volume (1 ml or less) with high sensitivity, precision, and potential automation.     

The design and testing of small,low-cost GPS-tracked surface drifters

We have designed and constructed drifters appropriate for use in regions characterized by limited horizontal extent. The drifters follow the upper 30 cm of surface currents, but can be modified to follow water at any depth. The drifters store their latitude and longitude internally, and transmit their current latitude and longitude to a handheld Global Positioning System (GPS)-radio receiver, making their location and subsequent retrieval straight forward A field test of six drifters in Hog Island Bay, Virginia, United States, in August 2003 was successful and led to several design improvements. With simple construction and a total materials cost of under U.S.$200 this design will make drifters an accessible part of interdisciplinary experiments, provide a potentially valuable educational tool, and make experiments that require large numbers of drifters more cost-effective.     

Photochemistry of methane-water ices

We report a study on the broadband ultraviolet photolysis of methane-water ice mixtures, at low methane concentrations and temperatures relevant to the icy satellites of the outer Solar System. The photochemistry of these mixtures is dominated by the action of hydroxyl radicals on methane and the resulting products. This implies that, given sufficient exposure time, the methane will eventually be completely oxidized to carbon dioxide. The presence of methane inhibits the formation of hydrogen peroxide by serving as a trap for hydroxyl radicals. The distribution of photochemical products is broadly similar to that previously conducted using ion and electron sources, with some differences possibly attributable to the difference in radiation source. The results are applicable to a variety of icy bodies in the Solar System. On Enceladus, where methane mixed with water is measured in the plumes, methane in the surface ices is subject to oxidation and will eventually be converted to CO₂. The CH stretch feature detected in the VIMS spectra of the Enceladus surface ice suggests that methane is currently being supplied to the surface ice, likely from re-condensation of the plume gas.     

Diffusion and partitioning of magnesium in quartz grain boundaries

Experiments were conducted to study Mg diffusion in quartz grain boundaries. A detector particle method was used to study grain-boundary diffusion because Mg was confined exclusively to the grain boundaries. Diffusion couples were assembled by placing a MgF₂ disk against a disk of quartzite, which was placed against a disk of quartzite that contained fayalite (Fe₂SiO₄) ‘detector particles.’ During diffusion experiments, Mg diffused along the grain boundaries of the central quartzite toward the fayalite quartzite where it was incorporated into fayalite detector particles. The only pathway for transport from the diffusant source to fayalite detector particles was through the grain boundaries in the central quartzite. The cross-sectional area of the grain boundaries that delivered Mg to the fayalite detector particles was determined from scanning electron microscope images. The Mg contents of the fayalite detector particles were used to calculate the mass of Mg that fluxed through the grain boundaries. During the diffusion experiments, pyroxene crystallites nucleated and grew in the central quartzites from Mg and Fe that was transported along quartz grain boundaries. The Mg contents of the crystallites vary linearly throughout the quartzites, suggesting that steady-state transport conditions were rapidly established in the quartz grain boundaries. Magnesium concentrations in the pyroxene crystallites are proportional to concentration gradients in the grain boundaries of the central quartzite. Grain-boundary fluxes and linear concentration gradients were used to calculate diffusion of Mg in grain boundaries of the central quartzite component in the diffusion couples.     

The causes and environmental effects of land use conversion during agricultural restructuring in Northeast China

1IntroductionLand use change has received lots of attention internationally (Turner etal., 1994). Understanding of the mechanism of land use change and its adverse effect on the environment is conducive to understanding of population, resources, environment and sustainable economic development on the global, national and regional scales. With the rapid rise in human population, human-induced changes in land use form an important component of regional environmental change. In China, to emphasi…