Stable isotope variations in modern tropical speleothems: Evaluating equilibrium vs. kinetic isotope effects

Applications of speleothem calcite geochemistry in climate change studies require the evaluation of the accuracy and sensitivity of speleothem proxies to correctly infer paleoclimatic information. The present study of Harrison’s Cave, Barbados, uses the analysis of the modern climatology and groundwater system to evaluate controls on the C and O isotopic composition of modern speleothems. This new approach directly compares the δ¹⁸O and δ¹³C values of modern speleothems with the values for their corresponding drip waters in order to assess the degree to which isotopic equilibrium is achieved during calcite precipitation. If modern speleothems can be demonstrated to precipitate in isotopic equilibrium, then ancient speleothems, suitable for paleoclimatic studies, from the same cave environment may also have been precipitated in isotopic equilibrium. If modern speleothems are precipitated out of isotopic equilibrium, then the magnitude and direction of the C and O isotopic offsets may allow specific kinetic and/or equilibrium isotopic fractionation mechanisms to be identified.Carbon isotope values for the majority of modern speleothem samples from Harrison’s Cave fall within the range of equilibrium values predicted from the combined use of (1) calcite-water fractionation factors from the literature, (2) measured temperatures, and (3) measured δ¹³C values of the dissolved inorganic carbon of drip waters. Calcite samples range from ∼0.8‰ higher to ∼1.1‰ lower than predicted values. The ¹³C depletions are likely caused by kinetically driven departures in the fractionation between HCO₃⁻ (aq) and CaCO₃ from equilibrium conditions, caused by rapid calcite growth. ¹³C enrichments can be accounted for by Rayleigh distillation of the HCO₃⁻ (aq) reservoir during degassing of ¹³C-depleted CO₂.Modern speleothems from Harrison’s Cave are not in O isotopic equilibrium with their corresponding drip waters and are 0.2‰ to 2.3‰ enriched in ¹⁸O relative to equilibrium values. δ¹⁸O variations in modern calcite are likely controlled by kinetically driven changes in the fractionation between HCO₃⁻ (aq) and CaCO₃ from equilibrium conditions to nonequilibrium conditions, consistent with rapid calcite growth. In contrast to δ¹³C, δ¹⁸O values of modern calcite may not be affected by Rayleigh distillation during degassing because CO₂ hydration and hydroxylation reactions will buffer the O isotopic composition of the HCO₃⁻ (aq) reservoir. If the effects of Rayleigh distillation manifest themselves in the O isotopic system, they will result in ¹⁸O enrichment in the HCO₃⁻ (aq) reservoir and ultimately in the precipitated CaCO₃.     

A decade of sedimentation in ice-contact, proglacial lakes, Bering Glacier, AK

Bathymetric surveys during the 1991–2000 decade in two ice-contact, proglacial lakes on the eastern sector of Bering piedmont lobe captured the buildup effects of the 1993–1995 surge. Following ice-front advance of 1.0–1.5 km into Tsivat and Tsiu Lakes, the basins were significantly altered by surge-related sedimentation including the impact of a subglacial outburst into Tsivat Lake. The subsequent changes in basin shape, size, and morphology were monitored by six bathymetric surveys. Measured changes in water depth serve as a proxy for determining increments of sediment accumulation.

Upwelling, ice-front vents fed by subglacial tunnels transported suspended fine sediment directly into the lake system. The rate of suspension settling within both lakes varied from 0.6 to 1.2 m year⁻¹ prior to the surge. Suspended load during surge years increased sixfold from 1.7 to 13.9 g l⁻¹, accompanied by increased sediment accumulation of 2.2–3.1 m year⁻¹. Vent-related aggradation and subsequent filling of Tsivat Lake caused sediment bypassing to Tsiu Lake, where encroachment by delta growth contributed to a postsurge rate of bottomset accumulation of 3.0 m year⁻¹.

The total sediment influx from subglacial sources is represented by the sum of bathymetrically determined accumulation, plus an estimated volume of sediment that remained suspended, thus passing through the lake system. Total sediment flux along the eastern Bering piedmont lobe from 1991 to 2000 is approximately 227 million cubic meters.     

Mechanism and regulation of land degradation in Yulin district

Yulin district is located in the transitional zone between Mu Us Desert and Loess Plateau of northern Shaanxi Province, thus it is particularly vulnerable to degradation due to its fragile ecosystem and intense human activities there. The purpose of this study is to explore the mechanism, process and driving force of land degradation in area with vulnerable eco-environment within the context of increasing population and intensifying human economic activities, and then find out the patterns and countermeasures of how to control them using the economic and technological ways. In detail, this study includes three main sections: the first section analyzes the mechanism, causes and characteristics of land degradation, which can be achieved by the typical field investigations and systematical analysis within the regional natural, social and economic context. Based on the technologies of remote sensing and GIS, and combined with the modeling methods, the second section reveals the change characteristics of land use and its driving force from 1990 to 2000; As to the third section, feasible countermeasures of how to prevent the degradation and rehabilitate the regional ecology are proposed, which are studied from the perspective of harmony between nature and economy, and the conception of regional sustainable development.     

Seismic anisotropy in the core–mantle transition zone

Split S waves observed at Hockley, Texas from events in the Tonga–Fiji region of the southwest Pacific show predominantly vertically polarized shear-wave ( SV  ) energy arriving earlier than horizontally polarized ( SH ) energy for rays propagating horizontally through D" . After corrections are made for the effects of upper-mantle anisotropy beneath Hockley, a time lag of 1.5 to 2.0  s remains for the furthest events (93.9°–100.6° ), while the time lags of the nearer observations (90.5°–92.9° ) nearly disappear. At closer distances, the S waves from these same events do not penetrate as deeply into the lower mantle, and are not split. These observations suggest that a patch of D" beneath the central Pacific is anisotropic, while the mantle immediately above the patch is isotropic. The thickness of the anisotropic zone appears to be of the order of 100–200  km.
  Observations of shear-wave splitting have previously been made for paths that traverse D" under the Caribbean and under Alaska. SH leads SV , the reverse of the Hockley observations, but in these areas the fact that SV  leads SH in the HKT data shown here suggests a different sort of anisotropy under the central Pacific from that under Alaska and the Caribbean. The case of SH travelling faster than SV  is consistent with transverse isotropy with a vertical axis of symmetry (VTI) and does not require variations with azimuth. The case of SV  leading SH is consistent with transverse isotropy with a horizontal axis of symmetry (HTI), an azimuthally anisotropic medium, and with a VTI medium formed by a hexagonal crystal. Given that (Mg,Fe)SiO₃ perovskite appears unlikely to form anisotropic fabrics on a large scale, the presence of anisotropy may point to chemical heterogeneity in the lowermost mantle, possibly due to mantle–core interactions.     

Pleistocene sediment sources, debris transport mechanisms, and depositional environments: a Bering Glacier model applied to northeastern Appalachian Plateau deglaciation, central New York

A modified ice-tongue model suggests that subglacial, saturated, fine sediment derived from local bedrock sources reduced basal shear strength and lowered the ice surface gradient sufficiently to produce ice tongues 20 km long in all major north-south oriented valleys on the northeastern Appalachian Plateau, while adjacent uplands were virtually ice-free. Associated environments of deposition produced two different landform assemblages, one representative of active ice retreat in through valleys and another that depicts widespread stagnation in non-through valleys.Pebble count data indicate that sediment transport by glacial flow was important to the moraine-building process, but the occurrence of isolated kame fields suggests an origin linked to inwash from major upland tributaries.All coarse valley fill (sand and gravel) is derived from two basic sources: (1) re-worked upland drift, and (2) resedimented debris from upvalley sources, including the glacier. Processes common to through valleys favor upvalley sources and active ice landforms, whereas inwash and stagnant ice sedimentation are typical of non-through valleys. Although extensive ice-free uplands served as a source of some fine sediment, a comparison of sediment volume to upland area indicates that inwash processes could not have yielded sufficient fines to account for the volume of fine sand and silt found within the valley fill. Meltwater flow via subglacial tunnels discharged saturated, fine sediment directly into proglacial lakes and served as the major source and transport mechanism for most sand and silt.The Laurentide deglacial environment throughout the upper Susquehanna region was characterized by proglacial lakes, detached remnant ice masses, dead-ice sedimentation and collapsed ice tongues. Stagnation and downwasting in ice-contact lakes peripheral to the eastern Bering Piedmont Glacier, Alaska, serve to depict analog conditions for retreat in central New York.     

The sequential megafaunal collapse hypothesis: Testing with existing data

Springer et al. [Springer, A.M., Estes, J.A., van Vliet, G.B., Williams, T.M., Doak, D.F., Danner, E.M., Forney, K.A., Pfister, B., 2003. Sequential megafaunal collapse in the North Pacific Ocean: an ongoing legacy of industrial whaling? Proceedings of the National Academy of Sciences 100 (21), 12,223–12,228] hypothesized that great whales were an important prey resource for killer whales, and that the removal of fin and sperm whales by commercial whaling in the region of the Bering Sea/Aleutian Islands (BSAI) in the late 1960s and 1970s led to cascading trophic interactions that caused the sequential decline of populations of harbor seal, northern fur seal, Steller sea lion and northern sea otter. This hypothesis, referred to as the Sequential Megafaunal Collapse (SMC), has stirred considerable interest because of its implication for ecosystem-based management. The SMC has the following assumptions: (1) fin whales and sperm whales were important as prey species in the Bering Sea; (2) the biomass of all large whale species (i.e., North Pacific right, fin, humpback, gray, sperm, minke and bowhead whales) was in decline in the Bering Sea in the 1960s and early 1970s; and (3) pinniped declines in the 1970s and 1980s were sequential. We concluded that the available data are not consistent with the first two assumptions of the SMC. Statistical tests of the timing of the declines do not support the assumption that pinniped declines were sequential. We propose two alternative hypotheses for the declines that are more consistent with the available data. While it is plausible, from energetic arguments, for predation by killer whales to have been an important factor in the declines of one or more of the three populations of pinnipeds and the sea otter population in the BSAI region over the last 30 years, we hypothesize that the declines in pinniped populations in the BSAI can best be understood by invoking a multiple factor hypothesis that includes both bottom–up forcing (as indicated by evidence of nutritional stress in the western Steller sea lion population) and top–down forcing (e.g., predation by killer whales, mortality incidental to commercial fishing, directed harvests). Our second hypothesis is a modification of the top–down forcing mechanism (i.e., killer whale predation on one or more of the pinniped populations and the sea otter population is mediated via the recovery of the eastern North Pacific population of the gray whale). We remain skeptical about the proposed link between commercial whaling on fin and sperm whales, which ended in the mid-1960s, and the observed decline of populations of northern fur seal, harbor seal, and Steller sea lion some 15 years later.