Diagenesis, palaeoclimate and tectono-sedimentary influences on clay mineralogy and stable isotopes from Upper Cretaceous marine successions of the Basque-Cantabrian Basin (N Spain)

Clay mineralogy and whole-rock stable isotopes (δ¹⁸O and δ¹³C) of Upper Cretaceous marly sediments on the Basque-Cantabrian Basin have been integrated to determine the main effects of diagenesis, palaeoclimate and tectono-sedimentary factors in sections belonging to deep- (Barrika) and platform-marine (Isla de Castro, Villamartín and Olazagutía) settings.The mean values for the clay assemblages and δ¹⁸O exhibit notable differences among the sections, partially explainable by the influence of diagenesis. The Barrika sediments, with more diagenetically advanced illite-smectite (I-S) mixed-layer (R1, 70% illite), authigenic chlorite, and low δ¹⁸O (−4.05‰ PDB), experienced higher diagenetic grade than Isla de Castro and Olazagutía, which have R0 I-S (20% illite) and heavier δ¹⁸O. Villamartín was also affected by higher diagenesis than Isla de Castro and Olazagutía, given the occurrence of R1 I-S (60% illite) and low δ¹⁸O (−4.11‰ PDB). However, the absence of other clays in Villamartín (e.g. authigenic chlorite) is indicative of less diagenetic grade than Barrika. These results show the useful integration of clay mineralogy and stable isotopes to detect different diagenetic grades in distinct marine successions of the same basin.Despite being influenced by diagenesis, the clay mineralogy partially preserves its inherited signature. This allows detection of major contents of I-S and mica, and minor kaolinite, interpreted as indicative of warm palaeoclimatic conditions. High kaolinite content in Villamartín and absence of kaolinite in Isla de Castro, though, are considered to be a product of neither diagenesis nor palaeoclimatic influences. Instead, tectono-sedimentary causes, related to unsuitable conditions for clay formation and transport from the local source areas, contributed to original clay differences. The inferred effects of diagenesis, palaeoclimate and tectono-sedimentary factors make this work important to show the potentially great variety of controls on the clay mineralogy of marine sections, which are often uncritically treated in studies concerning the Late Cretaceous.     

Recent trends in mean maximum and minimum air temperatures over Spain (1961–2006)

This study analyzes the mean maximum and minimum temperature trends on a monthly, seasonal, and annual timescale by applying various statistical tools to data from 476 Spanish weather stations during the period between 1961 and 2006. The magnitude of the trends was derived from the slopes of the regression lines using the least squares method, and the nonparametric Mann–Kendall test was used to determine the statistical significance of the trends. Temperature significantly increased in over 60% of the country in March, June, spring, and summer in the case of maximum temperatures and in March, May, June, August, spring, and summer for minimum temperatures. At the annual resolution, temperatures significantly increased in over 90% of Spain with a rise of around 0.3°C/decade. The maximum temperature increased at a higher rate than the minimum temperature from midsummer to early winter as well as in winter, spring, and summer and also on an annual basis.     

Exploring seven hundred years of transhumance,climate dynamic,fire and human activity through a historical mountain pass in central Spain

A high-altitude peat sequence from the heart of the Spanish Central System (Gredos range) was analysed through a multi-proxy approach to determine the sensitivity of high-mountain habitats to climate, fire and land use changes during the last seven hundred years, providing valuable insight into our understanding of the vegetation history and environmental changes in a mountain pass close to a traditional route of transhumance. The pollen data indicate that the vegetation was dominated by shrublands and grasslands with scattered pines in high-mountain areas, while in the valleys cereals, chestnut and olive trees were cultivated. Strong declines of high-mountain pines percentages are recorded at 1540, 1675, 1765, 1835 and 1925 cal AD, which may be related to increasing grazing activities and/or the occurrence of anthropogenic fires. The practice of mountain summer farming and transhumance deeply changed and redesigned the landscape of the high altitudes in central Spain (Gredos range) since the Middle Ages, although its dynamics was influenced in some way by climate variability of the past seven centuries.     

Interannual to decadal variations of precipitation and daily maximum and daily minimum temperatures in southern Brazil

The interannual to decadal variability of precipitation and daily maximum and daily minimum temperature (TMAX and TMIN) in southern Brazil for the 1913–2006 period is investigated using indices for these variables. Relations of these indices and the sea surface temperature (SST) variability in the eastern equatorial Pacific (Niño 3.4 index) and southwestern subtropical Atlantic (SSA index) are also investigated. Analyses are based on the Morlet wavelet transform. The interannual precipitation variability during the 1913–2006 period is mostly due to the high variances that occurred in specific sub-periods. The TMAX and TMIN indices also show significant interannual variability. The coherency and phase difference analyses of the precipitation index and the SST indices show higher coherency with the Niño 3.4 than with the SSA index. On the other hand, examining the coherencies and phase difference between the temperature indices and the SST indices, weaker coherencies with the Niño 3.4 index than with the SSA index are noted. These differences are discussed in the context of previous results. The new results here, with possible application for climate monitoring tasks, refer to the spectral differences between TMIN and TMAX.     

A special-relativistic approach to gravitation and its astrophysical consequences

In the framework of Rastall's conservative program for the construction of gravitation theory we present a variant of modified classical gravitation theory based on Einstein's energy-mass equivalence principle. We pursue further the special-relativistic arguments and obtain a theory for the static spherically-symmetric gravitation field that is based only on the well-established physical principles and accounts for all experimental tests known in gravitation. Some astrophysical consequences of the modified classical gravitation theory (e.g., the non-existence of black holes, the creation of real particles in a strong gravitation field) are also discussed.     

The supergene origin of ruthenian hexaferrum in Ni‐laterites

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.