Detection of Pharmaceuticals and Personal Care Products in Agricultural Soils Receiving Biosolids Application

Increasing research has suggested that biosolids generated from municipal wastewater treatment can be a major sink for many pharmaceuticals and personal care products (PPCPs) and their land application potentially introduces these contaminants into the terrestrial and aquatic environments. In this study, methods were developed for the analysis of 14 PPCPs in biosolids and soils using pressurized liquid extraction, solid phase extraction and liquid chromatography‐tandem mass spectrometry. Recoveries were over 50% for all analytes except diphenhydramine (?30%) in soils. Soil properties or type of biosolids showed minor effects on method recoveries. Estimated method limits of quantification (LOQ) range from 0.1–15 ng g^–1 for soil and 0.3–27 ng g^–1 for biosolids. A field study utilizing the methods revealed that other than carbamazepine‐10,11‐epoxide, all targeted compounds were detected in biosolids. Diphenhydramine, fluoxetine, triclosan and triclocarban were detected up to the μg g^–1 range with the highest concentration of 23 μg g^–1 for triclocarban. Seven of the PCCPs found in biosolids were also detected in agricultural soils amended with these biosolids and several (carbamazepine, diphenhydramine, and triclocarban) appeared to be persistent in soils. Triclocarban was also found most abundant in soils with the highest average concentration of 0.2 μg g^–1 while the rest of compounds were in the lower ng g^–1 range. Generally, the concentrations found on the fields were 2–3 degrees of magnitude lower than in the biosolids, which is likely to be due to dilution, degradation and leaching processes.     

Identifying sources of organic matter in sediments of shallow lakes using multiple geochemical variables

We analyzed ²¹⁰Pb-dated sediment cores from four relatively shallow lakes (z_max < 10 m) in the Upper Ocklawaha River Basin, Florida, USA to compare primary producer community structure before and after anthropogenic impacts. We measured physical and chemical sediment variables including density, organic matter (OM), water-soluble phosphorus, polyphosphate (Poly-P), total P (TP), total carbon to total nitrogen mass ratios of OM (TC:TN), biogenic silica (diatoms, sponge spicules), total amorphous silica, and stable carbon and nitrogen isotope ratios of bulk OM. Principal component analysis showed that diatom biogenic silica, TC:TN, Poly-P and TP displayed discernible stratigraphic changes associated with the shift in the primary producer community. We applied k-means cluster analysis to these variables to identify macrophyte-derived, transitional, and phytoplankton-derived sediments. Our approach provides an objective method for identifying sediment sources that may be applied to shallow lakes in other regions. The four study lakes shifted from a macrophyte-dominated state to a transitional state before major anthropogenic disturbances, and became phytoplankton-dominated after ~1950.     

Collapse simulation of a four‐story steel moment frame by a distributed online hybrid test

The collapse of a one‐bay, four‐story steel moment frame is simulated in this study by the proposed peer‐to‐peer (P2P) Internet online hybrid test system. The typical beam hinging mechanism, which is ensured by a strong‐column, weak‐beam design, is reproduced. The plastic hinges at the column bases are taken as the experimental portions, while the superstructure is analyzed numerically by a general‐purpose finite element program. The implicit plastic rotations of the two column bases are treated as boundary displacements. In order to account for the complex behavior of the column bases, the P2P system is modified to use the secant stiffness during iterations, and the physical specimens are designed such that the plastic hinge behavior can be obtained. For this study, the three substructures are distributed to different locations. A large ground motion is repeatedly imposed until the column bases lose their capacity to sustain the gravity load. As a result, significant deterioration is observed at both column bases. The proposed P2P system is thus demonstrated to be able to accommodate multiple‐tested substructures involving unstable behavior. The results suggest that the P2P Internet online hybrid test system provides a reliable means of studying structures up to collapse. Copyright © 2008 John Wiley & Sons, Ltd.     

Medium timescale stability of tidal mudflats in Bridgwater Bay,Bristol Channel,UK: Influence of tides,waves and climate

This paper presents the results of an 11-year study into mudflat elevation changes within the intertidal zone at Stert Flats in Bridgwater Bay, Somerset. This site is located in the outer Severn Estuary/inner Bristol Channel which is a macro-hypertidal regime dominated by physical processes, characterized by strong tidal currents, high turbidity and a significant degree of exposure to wind generated waves. Two transects of stakes were installed perpendicular to the coast, extending seawards 300 m from the edge of the saltmarsh onto the mudflats, against which variations in accretion or erosion could be measured. The mudflats themselves consisted of an underlying consolidated clay of Holocene age and a surface veneer of fluid mud and/or mobile sand patches which varied both spatially and temporally. Mudflat development was recorded over both short-term (monthly/seasonal) and medium-term (inter-annual) timescales. The results display a significant degree of scatter over all timescales. Such variability in response may be expected in such a dynamic system where noise can be attributed to a combination of factors such as the mobility of surface fluid mud and sand patches and the migration of the underlying ridge–runnel drainage network. Despite this, the expected short-term variations related to neap–spring tidal conditions and seasonal influences were observed at a number of locations on the transects although these were weakly expressed. The over-riding feature of the profiles is a consistent long-term trend of erosion which appears to be masking shorter term trends within the dataset. Viewed over the 11-year period, the changes in mudflat elevation closely match the pattern of the index of the North Atlantic Oscillation (NAO) during the 1990s, suggesting a strong climatic control over mudflat development on a medium-term/decadal scale. Most profiles display a strong erosional trend during the early 1990s when the NAO index was positive. The erosional trend peaked in 1995 at a time during which the values for monthly winter mean significant wave height were notably high. Between 1996 and 2001 the profiles generally record accretion and the data display significant variability. This corresponds with a shift to a strongly negative and then weakly positive NAO index phase. The fact that such a general atmospheric factor correlates so closely with medium timescale elevation change is attributed to relative weakness of biological binding and burrowing at this site, and more-so to the overwhelming dominance of the physical regime, especially the tidal current and the wind–wave regime. Both the background erosional trend and the influence of the index of the NAO in controlling mudflat evolution have important implications relating to coastal management. These are discussed in relation to coastal defence measures, morphological response to major civil engineering projects (e.g. Severn Tidal Power Barrage) and the prospect of climate change, sea-level rise and a possible increase in strength of NAO conditions in the future.     

Valuing visitors' economic benefits of public beach access points

An increase in the population of coastal counties and popularity of coastal beaches as tourism destinations create difficulties for management agencies responsible for providing public beach access. The objective of this paper is to determine non-resident visitors to South Carolina beaches economic value for public beach access. Visitors are willing to pay an extra $6.60 per day for additional beach access points and parking or an aggregate of $93 million. Visitors' economic value of public beach access allows decision-makers the ability to better compare management policies in their efforts to provide sufficient public beach access through a target effective strategy.     

Linkages between the North Pacific Oscillation and central tropical Pacific SSTs at low frequencies

The North Pacific Oscillation (NPO) recently (re-)emerged in the literature as a key atmospheric mode in Northern Hemisphere climate variability, especially in the Pacific sector. Defined as a dipole of sea level pressure (SLP) between, roughly, Alaska and Hawaii, the NPO is connected with downstream weather conditions over North America, serves as the atmospheric forcing pattern of the North Pacific Gyre Oscillation (NPGO), and is a potential mechanism linking extratropical atmospheric variability to El Ni?o events in the tropical Pacific. This paper explores further the forcing dynamics of the NPO and, in particular, that of its individual poles. Using observational data and experiments with a simple atmospheric general circulation model (AGCM), we illustrate that the southern pole of the NPO (i.e., the one near Hawaii) contains significant power at low frequencies (7–10?years), while the northern pole (i.e., the one near Alaska) has no dominant frequencies. When examining the low-frequency content of the NPO and its poles separately, we discover that low-frequency variations (periods >7?years) of the NPO (particularly its subtropical node) are intimately tied to variability in central equatorial Pacific sea surface temperatures (SSTs) associated with the El Ni?o-Modoki/Central Pacific Warming (CPW) phenomenon. This result suggests that fluctuations in subtropical North Pacific SLP are important to monitor for Pacific low-frequency climate change. Using the simple AGCM, we also illustrate that variability in central tropical Pacific SSTs drives a significant fraction of variability of the southern node of the NPO. Taken together, the results highlight important links between secondary modes (i.e., CPW-NPO-NPGO) in Pacific decadal variability, akin to already established relationships between the primary modes of Pacific climate variability (i.e., canonical El Ni?o, the Aleutian Low, and the Pacific Decadal Oscillation).     

Evaluating Weather Research and Forecasting Model Sensitivity to Land and Soil Conditions Representative of Karst Landscapes

Due to their particular physiographic, geomorphic, soil cover, and complex surface-subsurface hydrologic conditions, karst regions produce distinct land–atmosphere interactions. It has been found that floods and droughts over karst regions can be more pronounced than those in non-karst regions following a given rainfall event. Five convective weather events are simulated using the Weather Research and Forecasting model to explore the potential impacts of land-surface conditions on weather simulations over karst regions. Since no existing weather or climate model has the ability to represent karst landscapes, simulation experiments in this exploratory study consist of a control (default land-cover/soil types) and three land-surface conditions, including barren ground, forest, and sandy soils over the karst areas, which mimic certain karst characteristics. Results from sensitivity experiments are compared with the control simulation, as well as with the National Centers for Environmental Prediction multi-sensor precipitation analysis Stage-IV data, and near-surface atmospheric observations. Mesoscale features of surface energy partition, surface water and energy exchange, the resulting surface-air temperature and humidity, and low-level instability and convective energy are analyzed to investigate the potential land-surface impact on weather over karst regions. We conclude that: (1) barren ground used over karst regions has a pronounced effect on the overall simulation of precipitation. Barren ground provides the overall lowest root-mean-square errors and bias scores in precipitation over the peak-rain periods. Contingency table-based equitable threat and frequency bias scores suggest that the barren and forest experiments are more successful in simulating light to moderate rainfall. Variables dependent on local surface conditions show stronger contrasts between karst and non-karst regions than variables dominated by large-scale synoptic systems; (2) significant sensitivity responses are found over the karst regions, including pronounced warming and cooling effects on the near-surface atmosphere from barren and forested land cover, respectively; (3) the barren ground in the karst regions provides conditions favourable for convective development under certain conditions. Therefore, it is suggested that karst and non-karst landscapes should be distinguished, and their physical processes should be considered for future model development.     

The effect of clouds on aerosol growth in the rural atmosphere

Measurements of accumulation mode aerosol in the atmospheric boundary layer under cloudy and cloud-free conditions, and in the lower free troposphere under cloud-free conditions, were conducted over the rural northwest of England. Normalised size distributions in the cloud-free boundary layer (CFBL) and the cloud-free free troposphere (CFFT) exhibited almost identical spectral similarities with both size distributions possessing a concentration peak mode-radius of ≈0.05 μm or less. By comparison, aerosol distributions observed in cloudy air exhibited a distinctive log-normal distribution with mode-radii occurring at ≈0.1 μm concomitant with a local minimum at ≈0.05 μm. The consistent and noticeable difference in spectral features observed between cloudy and cloud-free conditions suggest that a greater amount of gas-to-particle conversion occurs on cloudy days, presumably through in-cloud aqueous phase oxidation processes, leading to larger sized accumulation mode particles. Apart from the distinct difference between cloudy and cloud-free aerosol spectra on cloudy days, aerosol concentration and mass were observed to be significantly enhanced above that of the ambient background in the vicinity of clouds. Volatility analysis during one case of cloud processing indicated an increase in the relative contribution of aerosol mass volatile at temperatures characteristic of sulphuric acid, along with a smaller fraction of more volatile material (possibly nitric acid and/or organic aerosol). Growth-law analysis of possible growth mechanisms point to aqueous phase oxidation of aerosol precursors in cloud droplets as being the only feasible mechanism capable of producing the observed growth. The effect of cloud processing is to alter the cloud condensation nuclei (CCN) supersaturation spectrum in a manner which increases the availability of CCN at lower cloud supersaturations.     

Effects of local drought condition on public opinions about water supply and future climate change

A growing body of research indicates that opinions about long-term climate change and other natural resource issues can be significantly affected by current weather conditions (e.g., outside air temperature) and other highly contingent environmental cues. Although increased severity and frequency of droughts is regarded as a likely consequence of anthropogenic climate change, little previous research has attempted to relate the experience of drought with public attitudes about water supply or water-related climate change issues. For this study, a large set (n?=?3,163) of public survey data collected across nine states of the southern United States was spatio-temporally linked with records of short-term (~12 weeks) and long-term (~5 years) drought condition at the level of each respondent’s zip code. Multivariate ordinal logistic regression models that included numerous other independent variables (environmental ideology, age, gender, education, community size, residency duration, and local annual precipitation) indicated highly significant interactions with long-term drought condition, but showed no significant effect from short-term drought condition. Conversely, attitudes about water-related climate change showed highly significant interactions with short-term drought, with weaker to no effects from long-term drought. While the finding of significant effects from short-term drought condition on opinions about future drought is broadly consistent with previous public opinion research on climate change, the finding of water supply attitudes being more responsive to longer term drought condition is, to our knowledge, a novel result. This study more generally demonstrates the methodological feasibility and applied importance of accounting for local drought condition when public opinion information is used to evaluate outreach programs for water conservation and climate change.     

Estimation and correction of model bias in the NASA/GMAO GEOS5 data assimilation system: Sequential implementation

This study presents a simplified multivariate bias correction scheme that is sequentially implemented in the GEOS5 data assimilation system and compared against a control experiment without model bias correction. The results show considerable improvement in terms of the mean biases of rawinsonde observation-minus-background (OmB) residuals for observed water vapor, wind and temperature variables. The time series spectral analysis shows whitening of bias-corrected OmB residuals, and mean biases for rawinsonde observation-minus-analysis (OmA) are also improved. Some wind and temperature biases in the control experiment near the equatorial tropopause nearly vanish from the bias-corrected experiment. Despite the analysis improvement, the bias correction scheme has only a moderate impact on forecast skill. Significant interaction is also found among quality-control, satellite observation bias correction, and background bias correction, and the latter positively impacts satellite bias correction.