Helical fields and filamentary molecular clouds – I

We study the equilibrium of pressure truncated, filamentary molecular clouds that are threaded by rather general helical magnetic fields. We first apply the virial theorem to filamentary molecular clouds, including the effects of non-thermal motions and the turbulent pressure of the surrounding ISM. When compared with the data, we find that many filamentary clouds have a mass per unit length that is significantly reduced by the effects of external pressure, and that toroidal fields play a significant role in squeezing such clouds.
We also develop exact numerical MHD models of filamentary molecular clouds with more general helical field configurations than have previously been considered. We examine the effects of the equation of state by comparing 'isothermal' filaments, with constant total (thermal plus turbulent) velocity dispersion, with equilibria constructed using a logatropic equation of state.
Our theoretical models involve three parameters: two to describe the mass loading of the toroidal and poloidal fields, and a third that describes the radial concentration of the filament. We thoroughly explore our parameter space to determine which choices of parameters result in models that agree with the available observational constraints. We find that both equations of state result in equilibria that agree with the observational results. Moreover, we find that models with helical fields have more realistic density profiles than either unmagnetized models or those with purely poloidal fields; we find that most isothermal models have density distributions that fall off as r ^−1.8 to r ⁻², while logatropes have density profiles that range from r ⁻¹ to r ^−1.8. We find that purely poloidal fields produce filaments with steep radial density gradients that are not allowed by the observations.     

Confounded by forgotten legacies: Effectively managing watersheds in the contemporary age of unknown unknowns

Contemporary watershed management practices can reflect oversimplifications of relationships between anthropogenic pressures and resource degradation. Remediation and restoration efforts often focus on recent land use practices as the primary driver of hydrologic regime changes. We present a case study that serves as an example to the scientific and watershed management communities of the lasting influences of historic land use practices and natural physical processes on a stream in the central United States listed as impaired by the federal government. Abnormal spatiotemporal streamflow relationships, determined by means of an experimental watershed study, alerted the authors to possible sink/source behavior in the upper‐watershed. Subsequent research uncovered archival evidence of coal mining, which may provide at least partial explanation. Additional investigation identified hydrologic processes associated with natural landscape evolution, noted by early‐20th‐century researchers, which are considered in the context of the current water quality and flow regime. Despite best‐intended management practices, regulatory agencies, scientists, and local decision makers have not accounted for such practices and processes, instead relying on recent development as the proximate cause of designated impairment. We present argumentation that historic land use (coal mining) and landscape processes comprise cumulative yet unconsidered legacy effects that contribute systemically to the observed hydrologic regime of the watershed. Results hold important implications for contemporary watershed management, and support rethinking the case‐by‐case appropriateness of federal and state water impairment listings, and the achievability of restoration efforts in many developing watersheds.     

Insights on stream temperature processes through development of a coupled hydrologic and stream temperature model for forested coastal headwater catchments

Stream temperature controls a number of biological, chemical, and physical processes occurring in aquatic environments. Transient snow cover and advection associated with lateral throughflow inputs can have a dominant influence on stream thermal regimes for headwater catchments in the rain‐on‐snow zone. Most existing stream temperature models lack the ability to properly simulate these processes. We developed and evaluated a conceptual‐parametric catchment‐scale stream temperature model that includes the role of transient snow cover and lateral advection associated with throughflow. The model consists of routines for simulating canopy interception, snow accumulation and melt, hillslope throughflow runoff and temperature, and stream channel energy exchange processes. The model was used to predict discharge and stream temperature for a small forested headwater catchment near Vancouver, Canada, using long‐term (1963–2013) weather data to compute model forcing variables. The model was evaluated against 4 years of observed stream temperature. The model generally predicted daily mean stream temperature accurately (annual RMSE between 0.57 and 1.24 °C) although it overpredicted daily summer stream temperatures by up to 3 °C during extended low streamflow conditions. Model development and testing provided insights on the roles of advection associated with lateral throughflow, channel interception of snow, and surface–subsurface water interactions on stream thermal regimes. This study shows that a relatively simple but process‐based model can provide reasonable stream temperature predictions for forested headwater catchments located in the rain‐on‐snow zone.     

Holocene relative sea‐level changes in Harris,Outer Hebrides,Scotland, UK

Evidence for relative sea‐level changes during the middle and late Holocene is examined from two locations on the Atlantic coast of Harris, Outer Hebrides, Scotland, using morphological mapping and survey, stratigraphical, grain size and diatom analysis, and radiocarbon dating. The earliest event identified is a marine flood, which occurred after 7982–8348 cal. a (7370 ± 80 ¹⁴C a) BP, when the sea crossed a threshold lying at ?0.08 m Ordnance Datum Newlyn (OD) (?2.17 m mean high water springs (MHWS)) before withdrawing. This could have been due to a storm or to the Holocene Storegga Slide tsunami. By 6407–6122 cal. a (5500 ± 60 ¹⁴C a) BP, relative sea levels had begun to fall from a sandflat surface with an indicated MHWS level of between 0.08 and ?1.96 m (?2.01 to ?4.05 m). This fall reached between ?0.30 and ?2.35 m (?2.39 to ?4.44 m) after 5841–5050 cal. a (4760 ± 130 ¹⁴C a) BP, but was succeeded by a relative sea‐level rise which reached between 0.54 and ?1.57 m (?1.55 to ?3.66 m) by 5450–4861 cal. a (4500 ± 100 ¹⁴C a) BP. This rise continued, possibly with an interruption, until a second sandflat surface was reached between 2.34 and ?0.26 m (0.25 to ?2.35 m) between 2952–3375 cal. a (3000 ± 80 ¹⁴C a) and 1948–2325 cal. a (2130 ± 70 ¹⁴C a) BP, before present levels were reached. The regressive episode from the earliest sandflat is correlated with the abandonment of the Main Postglacial Shoreline. It is maintained that the fluctuations in relative sea level recorded can be correlated with similar events elsewhere on the periphery of the glacio‐isostatic centre and may therefore reflect secular changes in nearshore sea surface levels. Despite published evidence from trim lines of differential ice sheet loading across the area, no evidence of variations in uplift between the locations concerned could be found. Copyright © 2009 John Wiley & Sons, Ltd.     

Contributions of individual countries?? emissions to climate change and their uncertainty

We have compiled historical greenhouse gas emissions and their uncertainties on country and sector level and assessed their contribution to cumulative emissions and to global average temperature increase in the past and for a the future emission scenario. We find that uncertainty in historical contribution estimates differs between countries due to different shares of greenhouse gases and time development of emissions. Although historical emissions in the distant past are very uncertain, their influence on countries?? or sectors?? contributions to temperature increase is relatively small in most cases, because these results are dominated by recent (high) emissions. For relative contributions to cumulative emissions and temperature rise, the uncertainty introduced by unknown historical emissions is larger than the uncertainty introduced by the use of different climate models. The choice of different parameters in the calculation of relative contributions is most relevant for countries that are different from the world average in greenhouse gas mix and timing of emissions. The choice of the indicator (cumulative GWP weighted emissions or temperature increase) is very important for a few countries (altering contributions up to a factor of 2) and could be considered small for most countries (in the order of 10%). The choice of the year, from which to start accounting for emissions (e.g. 1750 or 1990), is important for many countries, up to a factor of 2.2 and on average of around 1.3. Including or excluding land-use change and forestry or non-CO₂ gases changes relative contributions dramatically for a third of the countries (by a factor of 5 to a factor of 90). Industrialised countries started to increase CO₂ emissions from energy use much earlier. Developing countries?? emissions from land-use change and forestry as well as of CH₄ and N₂O were substantial before their emissions from energy use.     

Porosity and Permeability in Ternary Sediment Mixtures

Permeability, k, and porosity, φ, were measured in mixtures of fine, medium, and coarse sand, where the volume fraction of each of the three components was systematically varied. The k was modeled well by the Kozeny‐Carman equation for three‐component mixtures by using a representative grain size parameter, d, computed by averaging the grain diameters of components recursively, with averaging methods based on whether finer components exist in sufficient volume to fill the pores within coarser components. The φ was modeled well by using linear interpolation with piecewise‐planar models. We explored the use of differing numbers of piecewise‐planar elements in the model, and illustrate the trade‐off between the increased accuracy and the increased data requirements that both come from adding more elements. The k model is a function of both d and φ, but more sensitive to d. The k model gave results consistent with measured values when computed using either measured φ values, or values from any of the φ models.     

SIMS analyses of silicon and oxygen isotope ratios for quartz from Archean and Paleoproterozoic banded iron formations

Banded iron formations (BIFs) are chemical marine sediments dominantly composed of alternating iron-rich (oxide, carbonate, sulfide) and silicon-rich (chert, jasper) layers. Isotope ratios of iron, carbon, and sulfur in BIF iron-bearing minerals are biosignatures that reflect microbial cycling for these elements in BIFs. While much attention has focused on iron, banded iron formations are equally banded silica formations. Thus, silicon isotope ratios for quartz can provide insight on the sources and cycling of silicon in BIFs. BIFs are banded by definition, and microlaminae, or sub-mm banding, are characteristic of many BIFs. In situ microanalysis including secondary ion mass spectrometry is well-suited for analyzing such small features. In this study we used a CAMECA IMS-1280 ion microprobe to obtain highly accurate (±0.3‰) and spatially resolved (∼10 μm spot size) analyses of silicon and oxygen isotope ratios for quartz from several well known BIFs: Isua, southwest Greenland (∼3.8 Ga); Hamersley Group, Western Australia (∼2.5 Ga); Transvaal Group, South Africa (∼2.5 Ga); and Biwabik Iron Formation, Minnesota, USA (∼1.9 Ga). Values of δ¹⁸O range from +7.9‰ to +27.5‰ and include the highest reported δ¹⁸O values for BIF quartz. Values of δ³⁰Si have a range of ∼5‰ from −3.7‰ to +1.2‰ and extend to the lowest δ³⁰Si values for Precambrian cherts. Isua BIF samples are homogeneous in δ¹⁸O to ±0.3‰ at mm- to cm-scale, but are heterogeneous in δ³⁰Si up to 3‰, similar to the range in δ³⁰Si found in BIFs that have not experienced high temperature metamorphism (up to 300 °C). Values of δ³⁰Si for quartz are homogeneous to ±0.3‰ in individual sub-mm laminae, but vary by up to 3‰ between multiple laminae over mm-to-cm of vertical banding. The scale of exchange for Si in quartz in BIFs is thus limited to the size of microlaminae, or less than ∼1 mm. We interpret differences in δ³⁰Si between microlaminae as preserved from primary deposition. Silicon in BIF quartz is mostly of marine hydrothermal origin (δ³⁰Si < −0.5‰) but silicon from continental weathering (δ³⁰Si ∼ 1‰) was an important source as early as 3.8 Ga.     

Mapping Phytoplankton Community Physiology on a River Impacted Continental Shelf: Testing a Multifaceted Approach

Seasonal phosphorus limitation occurs on the Louisiana continental shelf as a result of high nitrogen loads in the spring and early summer. Prior studies have assessed such nutrient limitation by laborious and time-consuming nutrient analyses, enzyme assays, and nutrient addition bioassays. We undertook surface (0.5–1 m) mapping of fast repetition rate fluorescence (FRRF) parameters to assess nutrient limitation in real time on the Louisiana continental shelf and Mississippi River plume from 29 June to 08 July, 2002 in an effort to further understand phytoplankton productivity in this region, as well as to better inform effective nutrient management strategies. Surface nutrient concentrations (NO₃⁻, NO₂⁻, NH₄⁺, PO₄³⁻), chlorophyll a biomass, alkaline phosphatase (AP) activity, and four FRRF parameters: the maximum quantum yield of photochemistry (F _v /F _m ), the functional absorption cross section for PSII, the time constant for Q _A reoxidation, and the connectivity factor, were measured during continuous underway mapping. Results from traditional methods to assess phytoplankton nutrient stress indicated widespread phosphorus limitation from the Mississippi River plume to the Atchafalaya River, manifested as high inorganic N/P ratios and elevated AP activities associated with phytoplankton biomass. The FRRF data indicated complex patterns of phytoplankton physiology that were likely driven by the rapidly changing conditions in local surface waters and heterogeneous phytoplankton community structure. Correlations of nutrient data and enzyme assays with FRRF parameters were significant but low, potentially due to differences in the manner and time scale with which nutrient limitation affects the different techniques used, indicating that further work is needed to interpret FRRF parameters in large, heterogeneous environments such as estuaries and continental shelves.