Origin of dacites of Taupo Volcanic Zone, New Zealand

Dacites form a relatively small proportion of lavas in the Taupo Volcanic Zone, New Zealand (5km³), and occur mainly on the eastern side. In this paper their origin is considered in terms of three processes: (a) partial melting of crustal rocks; (b) fractional crystallisation of basalt and andesite; and (c) sub-surface mixing of basic and acid magma. Modelling techniques are used to calculate the most acceptable degree of fractional crystallisation and magma mixing to fit major-element data, and these values are used to compare calculated and observed trace-element values. The success or failure of the model is determined by the closeness of the two sets of values. For partial-melt models, trace-element values alone are calculated by the batch-melting equation.Results indicate that White Island dacite can best be modelled by fractional crystallisation; Manawahe by fractional crystallisation plus limited crustal contamination; Maungaongaonga by partial melting of Western Basement greywacke, and Tauhara by partial melting of this greywacke together with minor mixing with a more basic magma. Results from Parekauau and Horohoro indicate that these lavas are unlikely to have formed by any of the processes examined.     

Oceanic magnetic anomaly amplitudes: variation with sea-floor spreading rate and possible implications

A qualitative examination of oceanic magnetic anomalies suggests that their amplitudes increase with the spreading rate of the ocean floor. This suggestion has been investigated quantitatively by inversion of the anomalies. A variance matching technique has been used to calculate the average magnetisation of the crust with crustal thickness held constant or to calculate the thickness with the magnetisation fixed. In spite of variations in the computed intensities of magnetisation and thickness when compared to spreading rates the results show an over-all increase in the intensities with the rate of spreading. The mechanisms responsible for this could include greater irregularity in distribution of magnetic polarities within the crust at slow spreading ridges, greater intensity of magnetisation in crust produced at fast spreading due to initial chemical properties or enhanced hydrothermal alteration, and a dependence of crustal thickness on spreading rate.     

Mesozoic interaction of the Kula plate and the western margin of north america

Oceanic crust west of North America at the beginning of the Jurassic belonged to the Kula plate. The development of the western margin of North America since the Jurassic reflects interaction with the Kula plate, the Kula-Farallon spreading center and the Farallon plate. The Kula plate ceased to exist in the Paleocene and later developments were caused by interaction of the Farallon plate and, subsequently, collision with the East Pacific Rise.At the beginning of the Jurassic, when spreading between North and South America began, the Kula-Farallon-Pacific triple junction moved to the north relative to North America, and the eastern end of the Kula-Farallon spreading center swept northwards along the continental margin.During the Paleocene, Kula-Pacific spreading ceased and the Kula plate fused to the Pacific plate. Throughout the Mesozoic, subduction of the Kula plate took place along the Alaskan continental margin. When the Kula plate joined the Pacific plate a new subduction zone formed along the line of the present Aleutian chain.Wrangellia and Stikinia, anomalous terrains in Alaska and northwestern Canada respectively, were emplaced by transport on the Kula plate from lower latitudes. Hypotheses which require transport of these plates in the Mesozoic from the “far reaches of the Pacific” ignore the problem of transport across either the Kula-Pacific or Kula-Farallon spreading centers. The interaction of the Kula plate and western North America throughout the Jurassic and the Cretaceous should result in emplacement of these terrains by motion oblique to the continental margin. Tethyan faunas in Stikinia must come from the western end of Tethys between North and South America, not the Indonesian region at the eastern end of Tethys.As the northeastern end of the Kula-Farallon ridge moved northward, the sense of motion changed from right lateral shear between the Kula and North American plates to collision or left lateral shear between the Farallon and North American plates. Left lateral shear along zones analogous to the Mojave-Sonora megashear may have been the means by which anomalous terrains were transported to the southeast into the gap between North and South America forming present day Central America. Such a model overcomes the overlap difficulties suffered in previous attempts to reconstruct the Mesozoic paleogeography of Central America.     

Siderophile and chalcophile metal variations in Tertiary picrites and basalts from West Greenland with implications for the sulphide saturation history of continental flood basalt magmas

Sixty-five million year old continental flood basalts crop out on Qeqertarssuaq Island and the Nuussuaq Peninsula in West Greenland, and they include ～1,000 m of picritic lavas and discrete 10- to 50-m-thick members of highly contaminated basalts. On Qeqertarssuaq, the lavas are allocated to the Vaîgat and Maligât Formations of which the former includes the Naujánguit member, which consists of picrites with 7–29 wt% MgO, 80–1,400 ppm Ni, 5.7–9.4 ppb Pt and 4.2–12.9 ppb Pd. The Naujánguit member contains two horizons of contaminated basalts, the Asûk and Kûgánguaq, which have elevated SiO2 (52–58 wt%) and low to moderate MgO (7.5–12.8 wt%). These lavas are broadly characterized by low Cu and Ni abundances (average, 40 ppm Ni and 45 ppm Cu) and very low Pt (0.16–0.63 ppb) and Pd (0.13–0.68 ppb) abundances, and in the case of the Asûk, they contain shale xenoliths and droplets of native iron and troilite. The contaminated basalts from Nuussuaq, the B0 to B4 members, are also usually Ni-, Cu-, and platinum-group elements (PGE)-depleted. The geochemical signatures (especially the ratios of incompatible trace elements such as Th/Nb) of all of the contaminated basalts from Qeqertarssuaq and some of those from Nuussuaq record what appears to be a chemical contribution from deltaic shales that lie immediately below the lavas. This suggests that the contamination of the magmas occurred during the migration of the magmas through plumbing systems developed in sedimentary rocks, and hence, at a high crustal level. Nickel, Cu, and PGE depletion together with geochemical signatures produced by crustal contamination are also a feature of Siberian Trap basalts from the Noril’sk region. These basalts belong to the 0- to 500-m thick, ～5,000- to 10,000-km³ Nadezhdinsky Formation, which is centered in the Noril’sk Region. A major difference between Siberia and West Greenland is that PGE depletion in the Nadezhdinsky Formation samples with the lowest Cu and Ni contents is much more severe than that of the West Greenland contaminated basalts. Moreover, the volumes of the contaminated and metal-depleted volcanic rocks in West Greenland pale is significant when compared to the Nadezhdinsky Formation; local centers rarely contain more than 15 thin flows with a combined thickness of <50 m and more typically 10–20 m, so the volume of the eruptive portions of each system is probably two orders of magnitude smaller than the Nadezhdinsky edifice. The West Greenland centres are juxtaposed along fault zones that appear to be linked to the subsidence of the Tertiary delta, and so emplacement along N–S structures appears to be a principal control on the distribution of lavas and feeder intrusions. This leads us to suggest that the Greenland system is small and segregation of sulphide took place at high levels in the crust, whereas at Noril’sk, the saturation event took place at depth with subsequent emplacement of sulphide-bearing magmas into high levels of the crust. As a consequence, it may be unreasonable to expect that the West Greenland flood basalts experienced mineralizing processes on the scale of the Noril’sk system.     

Accuracy of ozonesonde measurements in the troposphere

Measurements of atmospheric ozone at concentrations typical of the free troposphere have been compared for ECC sondes and a UV-absorption photometer, using a Bendix chemiluminescent analyser as a transfer standard. Comparisons were conducted in the laboratory and in the tropospheric part of the atmosphere. It was found that the measurements agreed to within 4% provided that the background current for the ECC sonde was measured before exposure to ozone in the preparation procedure, and was assumed to be constant throughout the sonde flight. These results confirm those of earlier experiments and mean that the methods currently used to correct for the background current in the troposphere need to be revised.     

Extreme Ultraviolet Emission Lines of ca xv in Solar and Laboratory Spectra

New R-matrix calculations of electron impact excitation rates in Caxv are used to derive theoretical electron density diagnostic emission line intensity ratios involving 2s ²2p ²–2s2p ³ transitions, specifically R ₁=I(208.70 Å)/I(200.98 Å), R ₂=I(181.91 Å)/I(200.98 Å), and R ₃=I(215.38 Å)/I(200.98 Å), for a range of electron temperatures (T _e=10^6.4–10^6.8 K) and densities (N _e=10⁹–10¹³ cm^–3) appropriate to solar coronal plasmas. Electron densities deduced from the observed values of R ₁, R ₂, and R ₃ for several solar flares, measured from spectra obtained with the Naval Research Laboratory's S082A spectrograph on board Skylab, are found to be consistent. In addition, the derived electron densities are in excellent agreement with those determined from line ratios in Caxvi, which is formed at a similar electron temperature to Caxv. These results provide some experimental verification for the accuracy of the line ratio calculations, and hence the atomic data on which they are based. A set of eight theoretical Caxv line ratios involving 2s ²2p ²–2s2p ³ transitions in the wavelength range 140–216 Å are also found to be in good agreement with those measured from spectra of the TEXT tokamak plasma, for which the electron temperature and density have been independently determined. This provides additional support for the accuracy of the theoretical line ratios and atomic data.     

Wide-Field Camera for Gravitational Microlensing Survey: MOA-cam2

We have constructed a large, mosaic CCD camera called MOA-cam2 which has 4096 × 6144-pixelsto search for gravitational microlensing events. MOA-cam2 has three4096 × 2048-pixel SITe CCD chips, which have a very high quantum efficiency (nearly 80% in the wave region 500 to 800 nm),and three buttable sides. We have placed the threechips side by side with 100 m dead space. MOA-cam2 has been installed on the 61 cm Boller and Chivens telescope of the MOA collaboration at the Mt. John University Observatory (MJUO) in NewZealand since July 1998. The field coverage is 0.92° × 1.38° per exposure. The technical details of MOA-cam2 and the first images obtained with the Boller and Chivens telescope are presented. MOA-cam2 introduces a second phase of research on gravitational microlensing by the MOA collaboration.     

Photobleaching of chromophoric dissolved organic matter (CDOM) in rainwater

Significant photodegradation of chromophoric dissolved organic matter (CDOM) in rainwater was observed after exposure to simulated sunlight. Fluorescence excitation emission spectra (EEMS) of precipitation revealed the presence of four major peaks all of which degraded upon photolysis with the greatest loss in the region characteristic of marine CDOM. Photobleaching of absorbance also occurred in the wavelength region between 250 and 375 nm with the greatest loss of absorbance in the upper end of the UV-A region near 275 nm. There was a strong positive correlation between absorbance loss and total integrated fluorescence loss suggesting these optical properties and the degree to which they are photobleached in rainwater are directly related. The quantum yield of CDOM photodegradation in rainwater decreased dramatically with increasing wavelength and decreasing energy of incoming radiation with the average quantum yield at 325 nm approximately an order of magnitude greater than at 460 nm. The similarity of photolytic response between rainwater and Cape Fear estuarine CDOM indicates that some fraction of the compounds that make up rainwater CDOM may be derived from surface sources and/or that the processes that produce or modify humic-like substances in the atmosphere result in similar types of compounds as non-atmospheric processes.     

Does variable channel morphology lead to dynamic salmon habitat?

Stream channel morphology forms the template upon which hydraulic aspects of aquatic habitat are created, yet spatial and temporal variability in habitat imposed by changing morphology is not well understood. This paper presents a conceptual model linking sediment supply patterns to spatial and temporal variability in channel form and aquatic habitat. To evaluate this model, change over time in three habitat variables is quantified using a 2D hydrodynamic modeling approach. A 45-year record of topographic data from Carnation Creek, a catchment in coastal British Columbia, is used for the flow modeling. Using the Nays2DH modeling platform, water depths and velocities are simulated in eight channel segments located at different positions relative to locations of historical colluvial input using seven flow levels ranging from 3% to 400% of mean annual discharge (0.02 to 3.31 m s ). Results indicate that habitat availability changes through time as a result of sediment supply-driven changes to channel morphology and wood loads, but patterns in habitat vary as a function of dominant channel segment morphology. Spatial and temporal variability in morphology also influences the relationship between habitat availability and river discharge, leading to non-stationary habitat-discharge rating curves. When habitat areas are predicted by applying these curves to daily flow series spanning annual dry seasons, over 50% of the variance in cumulative seasonal habitat area can be explained by year-to-year changes in channel morphology and wood loading, indicating that changing morphology is an important factor for driving temporal habitat variability. This variance is related to the morphological variability of a channel segment, which in turn is associated with the segment position relative to zones of colluvial input. Collectively, these results suggest that variability in habitat is impacted by channel morphology, and can be evaluated partly on the basis of a channel's sediment supply regime. © 2019 John Wiley & Sons, Ltd.     

Temporal variation of228Ra in the near-surface Gulf of Mexico

The Mn-fiber technique for extracting radium from seawater has proved useful for studying the marine geochemistry of²²⁸Ra. In the Gulf of Mexico, this technique was used to measure the surface and near-surface distribution of²²⁶Ra and²²⁸Ra. The observed surface distribution of²²⁸Ra, and particularly the radium activity ratio (228/226) can be explained by known circulation patterns, or, when local surface currents are not well understood, may provide insight into their general characteristics.The radium activity ratio has increased from 0.5 in 1968 to 0.7 in 1973 in the surface Gulf of Mexico. This observed increase cannot be attributed to known anthropogenic or natural source perturbations within the Caribbean Sea-Gulf of Mexico system. Possible causes include a change in the residence time for near-surface water, or variations in the relative dominance of the two sources for water entering the eastern Caribbean; the North Equatorial Current and the Guiana Current.The temporal distribution of²²⁸Ra is unstable and naturally variable over a time period less than or equal to five years in the Gulf of Mexico and by extrapolation, the Caribbean Sea. Therefore, its usefulness in calculations of eddy diffusion coefficients for these regions is greatly diminished.