Element mapping the Merensky Reef of the Bushveld Complex

The Merensky Reef hosts one of the largest PGE resources globally.It has been exploited for nearly 100 years, yet its origin remains unresolved.In the present study, we characterised eight samples of the reef at four localities in the western Bushveld Complex using micro-X-ray fluorescence and field emission scanning electron microscopy.Our results indicate that the Merensky Reef formed through a range of diverse processes.Textures exhibited by chromite grains at the base of the reef are consistent with supercooling and in situ growth.The local thickening of the Merensky chromitite layers within troughs in the floor rocks is most readily explained by granular flow.Annealing and deformation textures in pyroxenes of the Merensky pegmatoid bear testament to recrystallisation and deformation.The footwall rocks to the reef contain disseminations of PGE rich sulphides as well as olivine grains with peritectic reaction rims along their upper margins suggesting reactive downward flow of silicate and sulphide melts.Olivine-hosted melt inclusions containing Cl-rich apatite, sodic plagioclase, and phlogopite suggest the presence of highly evolved, volatile-rich melts.Pervasive reverse zonation of cumulus plagioclase in the footwall of the reef indicates dissolution or partial melting of plagioclase, possibly triggered by flux of heat, acidic fluids, or hydrous melt.Together, these data suggest that the reef formed through a combination of magmatic, hydrodynamic and hydromagmatic processes.     

Palaeolimnological evidence for submerged plant loss in a floodplain lake associated with accelerated catchment soil erosion (Murray River,Australia)

Shallow lakes have been described as existing in two alternative equilibrium states, dominated by either submerged plants or phytoplankton. Causes of, often catastrophic, shifts between these states have been widely debated but may often result from displacement of the dominant community by stochastic influence. In Australian cut-off river meanders (also known as ‘billabongs’), anecdotal and palaeolimnological evidence suggests widespread loss of aquatic macrophytes since European occupation of the region c. post-1800. Our detailed and high-resolution stratigraphic study of a sediment core from Hogan’s Billabong (Murray River, Australia) seeks to identify the causes of the loss of aquatic macrophytes. Little direct evidence of the past extent and composition of submerged macrophyte communities was recovered. Nevertheless, results derived from other sediment proxies, including declines in the abundance of epiphytic diatoms and in plant-associated invertebrates, provide further indirect evidence of macrophyte disappearance. Despite limitations with radiometric dating, the sequence of events in the derived record suggests that a period of high abiotic turbidity, leading to a critical reduction in water transparency and caused by widespread erosion during the late 19th century, is the most likely factor contributing to loss of submerged vegetation from this billabong.     

The Merensky Cyclic Unit and its impact on footwall cumulates below Normal and Regional Pothole reef types in the Western Bushveld Complex

The Merensky Reef of the Bushveld Complex occurs in its highest stratigraphic position as a heterogeneous, pegmatitic, feldspathic melanorite bounded by two narrow chromitite stringers at the base of the Merensky Cyclic Unit (MCU). In the Swartklip Facies of the Rustenburg Layered Suite, the occurrence of widespread thermal and mechanical erosion termed “potholing” has led to the subdivision of the Merensky Reef into Normal Reef and Regional Pothole Reef sub-facies. The transition between the two sub-facies occurs where the MCU transgresses the lower chromitite stringer of the Normal Merensky Reef and cuts down into the underlying cumulate lithologies. In the Regional Pothole Reef at the Northam Platinum Mine, several economic reef types are identified, where the Merensky Reef becomes conformable to cumulate layering, in particular, to the footwall marker (NP2 reef type) and the upper pseudoReef (P2 reef type). The Normal Merensky Reef, as well as the P2 and NP2 Reefs, contains economic platinum group element (PGE) grades and includes the lower portion of the MCU melanorite and the Merensky Chromitite. Whole rock geochemistry indicates that this package is compositionally identical in Normal, P2, and NP2 Reefs, suggesting that the base of the MCU is a relatively homogeneous drape over both Normal and Regional Pothole Reef regions. However, the lower sections of the three Reefs are variables depending on the depth of transgression of the MCU. In the Normal and P2 reef types, transgression by the MCU was arrested within harzburgites, melanorites, and norites, resulting in coarse, pegmatitic textures in the immediate footwall units. For the NP2 Reef, transgression by the MCU was arrested within leucocratic rocks and resulted in the formation of troctolites below the Merensky Chromitite. These troctolites are characterised by a coupled relationship between olivine and sulphides and by changes in major element chemistry and PGE contents relative to equivalent units in the footwall of the Normal Reef. Along with micro-textural relationships, these features suggest that troctolization of leucocratic cumulates in the NP2 Reef beneath the Merensky chromitite was a result of a reactive infiltration of a chromite-saturated melt and an immiscible sulphide liquid from the overlying MCU, rather than a significant fluid flux from below. In all reef types, the concentration of S defines symmetrical peaks centred on the Merensky Chromitite (and chromitites from pre-existing cyclic units in Normal and P2 Reefs), whereas PGE concentrations define asymmetrical peaks with higher PGE contents in reconstituted footwall rocks relative to the MCU melanorite. This signature is attributable to a magmatic model of PGE collection followed by deposition towards the base of the MCU and within reconstituted footwall rocks. The continuity of the asymmetrical magmatic PGE signature between the Normal Reef and Regional Pothole Reef sub-facies indicates that PGE mineralization inherent to the Merensky magma occurred as a drape over a variably eroded and subsequent texturally and geochemically reworked or reconstituted footwall.     

A Seasonal Statistical Evaluation of COAMPS® over the Arabian Gulf Region

A statistical evaluation of the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS^®) was performed over the Arabian Gulf region for the period, 1 August to 5 October, 2004. Verification skill scores of bias and root-mean-square error were estimated for surface variables and for vertical profiles to investigate any diurnal variations. The model predictions of boundary-layer heights are compared with the observations at Abu Dhabi, United Arab Emirates. The Middle East presents challenges to numerical weather prediction due to complex land-ocean-land mesoscale processes. An independent data set of surface measurements from 50 stations in the UAE was available from the Department of Water Resources Studies, Abu Dhabi for model verification. The results indicate a diurnal variation in the model errors. The errors are small considering the magnitudes of the observed variables. Errors in the coastal region can be attributed to the differences in the timing of the onset of sea and land breeze circulations in the simulations as compared to the observations. Errors are relatively smaller in the offshore locations.     

Thermochronology of the Yidun Arc, central eastern Tibetan Plateau: constraints from Ar/Ar K-feldspar and apatite fission track data

Four K-feldspar samples from the Yidun Arc, eastern Tibetan Plateau, were analysed by the ⁴⁰Ar/³⁹Ar method with the aim of recovering information on their thermal history using multiple diffusion domain (MDD) theory. Arrhenius plots for each of the samples reveal low retentivity early in the heating experiments, a property that is attributed to their recrystallised nature. This low argon retentivity appears to violate the MDD assumption that volume diffusion is the only mechanism for argon transport within the crystals, thus the thermal histories derived from these analyses are considered suspect. Nevertheless, the age spectra themselves suggest that the majority of samples had cooled below 200 °C prior to the Eocene collision of India with Asia. Thermal history modelling from apatite fission track analyses from the same and nearby samples shows slow cooling through the apatite fission track partial annealing zone during the Cenozoic in samples from the high elevation, low relief areas of the Yidun Arc, while samples from the major Jinsha River valley show rapid cooling through the partial annealing zone beginning in the Miocene. These results suggest that significant Cenozoic denudation has been localised and that most parts of the Yidun Arc have experienced very little denudation during the Cenozoic.     

An earthquake sequence studied with ocean-bottom seismographs

Summary. A tripartite ocean-bottom seismograph array at the junction of the East Pacific Rise and Rivera Fracture Zone recorded an eathquake sequence, consisting of three main shocks ( m _B= 4.3, 4.3 and 4.8) and numerous aftershocks from the fracture zone, in the distance range 35–50 km. Delineation of the rupture zones by aftershocks indicates that the first two main shocks took place on overlapping fault areas, while the third occurred over a fault area separated from the first by several kilometres. Both rupture zones were about 4 km long. Surface wave spectra indicate a shallow (about 3 km below the sea floor) source, as does OBS array phase velocity data. The seismic moments, obtained from teleseismic surface wave data, of 1.3, 2.1 and 2.8 × 10²³ dyn cm, with the fault areas as delineated by aftershocks, imply a stress drop of about 8 bars for the main shocks. Aftershock sequences of each of the main shocks are similar, with a b -value of about 0.65. Teleseismic P travel times are similar to those from near-surface sources in Nevada.     

The effect of particle precipitation events on the neutral and ion chemistry of the middle atmosphere: II. Odd hydrogen

A one dimensional time-dependent model of the neutral and ion chemistry of the middle atmosphere has been used to examine the production of odd hydrogen (H, OH, and HO₂) during charged particle precipitation. At altitudes above about 65 km, odd hydrogen production depends on the ionization rate, and the atomic oxygen and water vapor densities. Odd hydrogen production is shown to exhibit diurnal and other time dependent variations during such an event at these altitudes, and the assumption that two odd hydrogen particles are always produced per ionization is reexamined.     

Cape Lyot Hα-heliograph results

The Lyot H-heliograph at the Royal Observatory, Cape of Good Hope was in almost daily operation from March 12, 1958 to December 31, 1965. From the records obtained, a definitive list of 2907 flares was compiled, their properties analyzed, and the results presented herein.The data on East-West distribution of activity, although inconclusive, shows an asymmetry of flare activity with 56.5% of the flares West of the central meridian; this is partially due, however, to an inhomogeneous density distribution in the filtergrams.Flare distribution with respect to heliographic longitude, association with spot types and number of spots in the group are also discussed. The frequency of flare areas, rise times, and durations are examined as is their relationship to distance from the disk centre.