U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.     

Onshore and offshore seismic and lithostratigraphic analysis of a deeply incised Quaternary buried valley system in the Northern Netherlands

High-resolution seismic data (onshore and offshore), geophysical borehole data as well as detailed lithofacies from airlift boreholes were acquired in northern Netherlands on and around the island of Ameland. Marine and land seismic data combined with information from land boreholes have been explored with the objective of providing a sedimentary model. Qualitative seismic facies analysis of the valley fill commonly shows a thin unit with high amplitude reflectors at the base. Thick units of variable seismic facies (transparent to high amplitude) occur higher up in the sequence. Onlap is common at mid–upper levels within the sandy valley fill (with clay in mm layering), and a transparent seismic facies, corresponding to firm clays, is common at the top. Almost all lithological unit boundaries recognised within core parameters correspond with seismic unconformities within error margins. Subunits contain multiple cyclical trends in gamma ray and grain size. Cyclical trends show lower order fluctuations in gamma radiation on a scale of less than 1 m. Gamma-ray pattern variability between units, e.g. in general coarsening-up or fining-up units, suggests migration of subaqueous outwash fans or ice margin fluctuations. Seismic results could support a headward excavation and backfilling process suggested by Praeg [Morphology, stratigraphy and genesis of buried Elsterian tunnel valleys in the southern North Sea basin [PhD thesis]: University of Edinburgh, 207 pp.; Journal of Applied Geophysics, (this volume)] as being responsible for the formation of buried valleys. On a lithological scale, a more complicated, detailed and cyclical pattern arises. Catastrophic processes are considered unlikely as being responsible for the infill sequence because of the observed small-scale facies variability and because of the presence of diamicton layers. Diamicton layers at the base of basal unconformities as well as higher in sequence could suggest subglacial deformation by grounded ice before and during the valley-fill process.     

Estimating the orientation error of the Dahan Downhole Accelerometer using the maximum cross-correlation coefficient between the observed and synthetic waves

A new algorithm to correct the orientation error of the accelerometerat the Dahan Downhole Array, Hualien, Taiwan is developed. This algorithmconsists of three stages: (1) rotating two horizontal ground motions on thefree surface to the SH-SVdirection and SH axis offers a reference direction.(2) computing the synthetic downhole SH waves at a downhole station and (3)searching a rotation angle for downhole observation that yields a best waveformmatch between the synthetic and observed downhole seismograms. At this point, the rotated angle corresponding to the best waveform match can be considered as the orientation error. We selected five earthquakes with good data qualityfor analysis. Results show that this algorithm gives a more stable estimationthan a conventional method because it allows the selection of data from a wider time window for analyses. The estimated orientation error of the accelerometers at the Dahan Downhole Array after the 1999 reinstallation are40°, 114° and 285° at depths of 50, 100 and 200 m, respectively.     

Seismic scattering at the top of the mantle Transition Zone

We document strong seismic scattering from around the top of the mantle Transition Zone in all available high resolution explosion seismic profiles from Siberia and North America. This seismic reflectivity from around the 410 km discontinuity indicates the presence of pronounced heterogeneity in the depth interval between 320 and 450 km in the Earth’s mantle. We model the seismic observations by heterogeneity in the form of random seismic scatterers with typical scale lengths of kilometre size (10-40 km by 2-10 km) in a 100-140 km thick depth interval. The observed heterogeneity may be explained by changes in the depths to the α-β-γ spinel transformations caused by an unexpectedly high iron content at the top of the mantle Transition Zone. The phase transformation of pyroxenes into the garnet mineral majorite probably also contributes to the reflectivity, mainly below a depth of 400 km, whereas we find it unlikely that the presence of water or partial melt is the main cause of the observed strong seismic reflectivity. Subducted oceanic slabs that equilibrated at the top of the Transition Zone may also contribute to the observed reflectivity. If this is the main cause of the reflectivity, a substantial amount of young oceanic lithosphere has been subducted under Siberia and North America during their geologic evolution. Subducted slabs may have initiated metamorphic reactions in the original mantle rocks.     

Explosion seismic reflections from the Earth’s core

Recent seismological studies have presented evidence for the existence of a layer with ultra-low seismic velocities at the core-mantle boundary at ca. 2900 km depth. We report high-amplitude, high-frequency, and laterally coherent seismic arrivals from three nuclear explosions in Siberia. With recording station intervals of 15 km, the seismic phases are readily correlated and show the presence of a thin, ultra-low velocity zone in a region where it was not previously reported. The duration and complexity of the arrivals are inconsistent with a simple core-mantle boundary and require a hitherto unidentified, kilometre-scale, fine structure in the ultra-low velocity zone. The observations may be explained by a ca. 7 km thick, two-layer, ultra-low velocity zone with exceptional low velocities, which indicate the presence of high percentages of melt (>15%), in particular in the lower part of the zone. Waveform variation implies lateral change in the thickness and physical properties of the ultra-low velocity zone with a wavelength of less than 100 km.     

Evaluating foundation mass,damping and stiffness by the least‐squares method

This paper discusses how to use the three‐dimensional (3D) time‐domain finite‐element method incorporating the least‐squares method to calculate the equivalent foundation mass, damping and stiffness matrices. Numerical simulations indicate that the accuracy of these equivalent matrices is acceptable when the applied harmonic force of 1+sine is used. Moreover, the accuracy of the least‐squares method using the 1+sine force is not sensitive to the first time step for inclusion of data. Since the finite‐element method can model problems flexibly, the equivalent mass, damping and stiffness matrices of very complicated soil profiles and foundations can be established without difficulty using this least‐squares method. Copyright © 2003 John Wiley & Sons, Ltd.     

An Efficient Numerical Method for Computing Synthetic Seismograms for a Layered Half-space with Sources and Receivers at Close or Same Depths

— It is difficult to compute synthetic seismograms for a layered half-space with sources and receivers at close to or the same depths using the generalized R/T coefficient method (Kennett, 1983; Luco and Apsel, 1983; Yao and Harkrider, 1983; Chen, 1993), because the wavenumber integration converges very slowly. A semi-analytic method for accelerating the convergence, in which part of the integration is implemented analytically, was adopted by some authors (Apsel and Luco, 1983; Hisada, 1994, 1995). In this study, based on the principle of the Repeated Averaging Method (Dahlquist and Björck, 1974; Chang, 1988), we propose an alternative, efficient, numerical method, the peak-trough averaging method (PTAM), to overcome the difficulty mentioned above. Compared with the semi-analytic method, PTAM is not only much simpler mathematically and easier to implement in practice, but also more efficient. Using numerical examples, we illustrate the validity, accuracy and efficiency of the new method.     

Environmental Emission of Mercury During Gold Mining by Amalgamation Process and its Impact on Soils of Gympie, Australia

— The aims of this study were to estimate the total amount of mercury released to the environment during 60 years of gold mining (1867–1926) at Gympie, Queensland, Australia and to measure the mercury levels in soil samples surrounding the mining activity. We estimated that 1902 tonnes of mercury was released to the environment and about 1236 tonnes of which was released to the air. The mean mercury in the soil samples in the vicinity of the Scottish battery varied from 1.07 to 99.26 μg g^?1 as compared to 0.075 μg g^?1 as background mercury concentrations. The maximum mercury concentration measured in sediments of the Langton Gully was 6.12 μg g^?1. These results show that large amount of mercury was used in this area during gold mining. Since mining is active in the area and Langton Gully flows into Mary River, we therefore, recommend that mercury concentration in air and fish should be monitored.     

Characterisation of the 1997 Vulcanian explosions of Soufrière Hills Volcano,Montserrat, by video analysis

The activity of Convention at Montserrat Soufrière Hills Volcano, Montserrat, during the period 1995–1999 included numerous violent explosions. Two major cycles of Vulcanian explosions occurred in 1997: a first of 13 explosions between 4 and 12 August and a second of 75 between 22 September and 21 October. The explosions were short-lived events lasting a few tens of seconds during which partial fountain collapse generated pyroclastic surges and pyroclastic flows, and buoyant plumes ascended 3–15 km into the atmosphere. Each explosion discharged on average 3×10⁵ m³ (dense-rock equivalent, DRE) of magma, draining the conduit to depths of 1–2 km. The paper focuses on the first few seconds of three explosions of the 75 that occurred in September/October 1997: 6 October 1997 at 17:50, 7 October 1997 at 16:02 and 9 October 1997 at 12:32. Physical parameters such as exit velocities, magmatic water contents and magma pressures at fragmentation are estimated by following and modelling the ascent of individual momentum-dominated finger jets visible on videos during the initial stages of each explosion. The model treats each finger jet as an incompressible flow sustained by a steady flux of gas and particles during the few seconds of ascent, and produces results that compare favourably with those using a multiphase compressible code run using similar eruptive parameters. Each explosion reveals a progressive increase in eruptive intensity with time, jet exit velocities increasing from 40 m s^–1 at the beginning of the explosion up to 140 m s^–1 after a few seconds. Modelling suggests that the first magma to exit was largely degassed, whereas that discharged after a few seconds contained up to 2 wt% water. Magma overpressures up to ~10 MPa are estimated to have existed in the conduit immediately prior to each explosion. Progressive increases in jet exit velocity with time over the first few seconds of each explosion provide direct evidence for strong pre-eruptive gradients in water content and magma pressure in the upper reaches (probably 100–500 m) of the conduit. Fountain collapse occurred during the first 10–20 s of each explosion because the discharging jets had bulk densities up to 100 times that of the atmosphere and were unable to entrain enough air to become buoyant. Such high eruptive densities were due to the presence of partially degassed magma in the conduit.Editorial responsibility: A. Woods     

Indoor Radon Radioactivity at the University of Brunei Darussalam

— Indoor radon radioactivity in the rooms on the ground floor and first floor of the Physics Department, Faculty of Science, Universiti Brunei Darussalam was measured using a system that consists of an air filter pump, ZnS detector, photomultiplier tube and counter. Ground floor rooms' radon radioactivity was found to be about three times higher than that of the first floor. The maximum ground floor indoor radioactivity is only 0.39 Bqm^?3, a value relatively low and safe compared to the mean outdoor radon concentration of 1.41 Bqm^?3 measured (HU and TAN, 2000). The main source of radon emanation originates from the ground soil rather than the building materials.