Progress in Carrier Phase Time Transfer

The progress of the joint Pilot Project for time transfer, formed by the International GPS Service (IGS) and the Bureal International des Poids et Mesures (BIPM), was recently reviewed. Three notable milestones were set. (1) The IGS will implement, at least in a test mode, an internally realized time scale based on an integration of combined frequency standards within the IGS network. This will eventually become the reference time scale for all IGS clock products (instead of the current GPS broadcast time). (2) A new procedure for combined receiver and satellite clock products will be implemented officially in November 2000. Receiver clocks are an entirely new product of the IGS. (3) The BIPM will coordinate an effort to calibrate all Ashtech Z12-T (and possibly other) receivers suitable for time transfer applications, either differentially or absolutely. Progress reports will be presented publicly in the spring 2001. ? 2001 John Wiley & Sons, Inc.     

Paleogeothermal gradient in the boskovice furrow

Summary A coalification data set from the first seam of the Rosice-Oslavany coal district in the Boskovice furrow was used to estimate the temperature gradient prevailing within the furrow during Autunian sedimentation. An appreciable scatter of the data reflects the complicated history of the sedimentary region. The northern part of the district displays a higher degree of coalification. The results of the evaluation suggest that the region ceased to subside in the upper Autunian, and that the extent of the post-Autunian erosion does not exceed 500 metres. This version of the burial history, which is consistent with geological data, yields a temperature paleogradient of 76 mK/m for the northern part and of 72 mK/m for the southern part of the district. The gradients estimated are higher than those prevailing during the Carboniferous sedimentation in the Central Bohemian Basin (45 – 53 mK/m), lower than values found for the Ostrava Formation in the Upper Silesian Basin during its Namurian A sedimentation (about 95 mK/m), but comparable with values evaluated for the Karviná Formation of the same basin deposited during the Namurian B - C and Westphalian A (60 – 77 mK/m).Dedicated to the Memory of Professor Karel P     

Zinc and sulfur isotope variation in sphalerite from carbonate-hosted zinc deposits,Cantabria, Spain

We studied zinc and sulfur isotopes and the chemical composition of sphalerite samples from Picos de Europa (Aliva mine) and sphalerite and hydrozincite samples from La Florida mine, two carbonate-hosted Mississippi Valley-type (MVT) deposits located in northern Spain; despite being close, they are hosted in carbonatic rocks of different ages, Lower Carboniferous and Lower Cretaceous, respectively. The two generations of sphalerite at Picos de Europa show different δ⁶⁶Zn values (stage 1 sphalerite +0.24 per mil and stage 2 sphalerite from ?0.75 to +0.08 per mil). Both generations also differ in the sulfur isotope composition (stage 1 has δ³⁴S?=?+6.6 and stage 2 has δ³⁴S?=??0.9 to +2.9 per mil) and the chemical composition (stage 1 sphalerite, compared to stage 2 sphalerite, is significantly enriched in Pb, As, Mn, Sb, slightly enriched in Ag, Ni, and Cu and depleted in Co, Ga, Tl, Te, Ge, and Sn). We suggest that Zn isotope fractionation was controlled predominantly by pH and T changes. High Zn isotope values reflect rapid precipitation of sphalerite from higher-temperature acidic fluids that carried Zn mostly as chloride species after interaction with carbonate rocks while lower Zn isotope values most likely resulted from a longer precipitation process from fluid at higher pH and decreasing T that carried dominantly Zn sulfide species. At La Florida, sphalerite samples show light ⁶⁶Zn-depleted signatures with δ⁶⁶Zn values from ?0.80 to ?0.01 per mil (mostly between ?0.80 and ?0.24 per mil) and δ³⁴S values from +10.7 to +15.7 per mil without any relationship between the δ⁶⁶Zn and δ³⁴S values. Here, the variation in Zn isotope values is interpreted as related to mixing of fluids from two reservoirs. The Zn was carried by a single deep-seated and higher T (~250–320 °C) fluid, and precipitation took place after mixing with a connate S-rich fluid in a system with mH₂S?>?mZn²⁺ as a result of change in pH, T, and Zn predominant species. The light δ⁶⁶Zn accompanied by heavy δ³⁴S values resulted from fractionation of Zn aqueous sulfides at near-neutral pH and decreasing T. Hydrozincite samples show much heavier δ⁶⁶Zn values (+0.21 to +0.33 per mil), consistent with fractionation during supergene processes.     

Electrical conductivity of some rocks from the Indian subcontinent

Summary Results on electrical conductivity, chemical analysis and age of the rock samples from the Indian Subcontinent are presented. The old Precambrian Indian rocks tend to be less conductive than characteristic rocks of crustal and upper mantle structures.

---

nuam mam uu mnm¶rt;mu, uu aaua u n¶rt;u u uu n¶rt; u ¶rt;uu. ma nauu n¶rt; u ¶rt;uu naam mn¶rt;m aamumuu n¶rt; u amuu.

     

Estimating environmentally relevant fixed nitrogen demand in the 21st century

Human activities affect the impact of the nitrogen cycle on both the environment and climate. The rate of anthropogenic nitrogen fixation from atmospheric N₂ may serve as an indicator to the magnitude of this impact, acknowledging that relationship to be effect-dependent and non-linear. Building on the set of Representative Concentration Pathway (RCP) scenarios developed for climate change research, we estimate anthropogenic industrial nitrogen fixation throughout the 21st century. Assigning characteristic key drivers to the four underlying scenarios we arrive at nitrogen fixation rates for agricultural use of 80 to 172 Tg N/yr by 2100, which is slightly less to almost twice as much compared with the fixation rate for the year 2000. We use the following key drivers of change, varying between scenarios: population growth, consumption of animal protein, agricultural efficiency improvement and additional biofuel production. Further anthropogenic nitrogen fixation for production of materials such as explosives or plastics and from combustion are projected to remain considerably smaller than that related to agriculture. While variation among the four scenarios is considerable, our interpretation of scenarios constrains the option space: several of the factors enhancing the anthropogenic impact on the nitrogen cycle may occur concurrently, but never all of them. A scenario that is specifically targeted towards limiting greenhouse gas emissions ends up as the potentially largest contributor to nitrogen fixation, as a result of large amounts of biofuels required and the fertilizer used to produce it. Other published data on nitrogen fixation towards 2100 indicate that our high estimates based on the RCP approach are rather conservative. Even the most optimistic scenario estimates that nitrogen fixation rate will remain substantially in excess of an estimate of sustainable boundaries by 2100.     

Expanding global mapping of the foliage clumping index with multi-angular POLDER three measurements: Evaluation and topographic compensation

The clumping index measures the spatial aggregation (clumped, random and regular) of foliage elements. The global mapping of the clumping index with a limited eight-month multi-angular POLDER 1 dataset is expanded by integrating new, complete year-round observations from POLDER 3. We show that terrain-induced shadows can enhance bi-directional reflectance distribution function variation and negatively bias the clumping index (i.e. indicating more vegetation clumping) in rugged terrain. Using a global high-resolution digital elevation model, a topographic compensation function is devised to correct for this terrain effect. The clumping index reductions can reach up to 30% from the topographically non-compensated values, depending on terrain complexity and land cover type. The new global clumping index map is compared with an assembled set of field measurements from 32 different sites, covering four continents and diverse biomes.     

Historical trends in Florida temperature and precipitation

Because of its low topographic relief, unique hydrology, and the large interannual variability of precipitation, Florida is especially vulnerable to climate change. In this paper, we investigate a comprehensive collection of climate metrics to study historical trends in both averages and extremes of precipitation and temperature in the state. The data investigated consist of long‐term records (1892–2008) of precipitation and raw (unadjusted) temperature at 32 stations distributed throughout the state. To evaluate trends in climate metrics, we use an iterative pre‐whitening method, which aims to separate positive autocorrelation from trend present in time series. Results show a general decrease in wet season precipitation, most evident for the month of May and possibly tied to a delayed onset of the wet season. In contrast, there seems to be an increase in the number of wet days during the dry season, especially during November through January. We found that the number of dog days (above 26.7 °C) during the year and during the wet season has increased at many locations. For the post‐1950 period, a widespread decrease in the daily temperature range (DTR) is observed mainly because of increased daily minimum temperature (Tmin). Although we did not attempt to formally attribute these trends to natural versus anthropogenic causes, we find that the urban heat island effect is at least partially responsible for the increase in Tmin and its corresponding decrease in DTR at urbanized stations compared with nearby rural stations. In the future, a formal trend attribution study should be conducted for the region. Copyright © 2012 John Wiley & Sons, Ltd.     

Extremely slow slope movements influencing the stability of Spis Castle,UNESCO site

Spis Castle, a monument included in the UNESCO World Heritage Site list (Eastern Slovakia) is built on a travertine mound overlying soft Paleogene rocks. Lateral spreading resulting from the subsidence of strong upper travertine into soft claystone strata has fractured and separated the castle rock into several cliffs. The differential movement of individual cliff faces is the primary influence on the stability of the monument. In order to monitor and quantify the movement, two techniques were adopted: a mechanical-optical TM-71 crack gauge and a demec gauge (demountable mechanical—SOMET type crack gauge). This paper presents the results and interpretation of medium and short-term monitoring at the site.     

Comparison between cell-centered and nodal-based discretization schemes for linear elasticity

In this paper, we study newly developed methods for linear elasticity on polyhedral meshes. Our emphasis is on applications of the methods to geological models. Models of subsurface, and in particular sedimentary rocks, naturally lead to general polyhedral meshes. Numerical methods which can directly handle such representation are highly desirable. Many of the numerical challenges in simulation of subsurface applications come from the lack of robustness and accuracy of numerical methods in the case of highly distorted grids. In this paper, we investigate and compare the Multi-Point Stress Approximation (MPSA) and the Virtual Element Method (VEM) with regard to grid features that are frequently seen in geological models and likely to lead to a lack of accuracy of the methods. In particular, we look at how the methods perform near the incompressible limit. This work shows that both methods are promising for flexible modeling of subsurface mechanics.