Development of push moraines in deeply frozen sediment adjacent to a cold-based glacier in the McMurdo Dry Valleys,Antarctica

Previous studies of push moraines have concluded that structural architecture is controlled by a combination of stress exerted by flowing ice and the rheology of the deforming sediment. However, the relationship between deformation processes and the thermal/hydrologic conditions within the sediment remains ambiguous. Using a combination of surface mapping, logging exposures and ground penetrating radar we examine the relationships between surface morphology, material properties and development of deformation structures in deeply frozen sediment that has been deformed by Joyce Glacier, a cold-based glacier in the McMurdo Dry Valleys. The structural architecture of the push moraines is characterized by a combination of brittle and ductile deformation structures that have produced a structurally complex pattern of thrust faults, low angle listric thrusts and recumbent folds that extend 400 m beyond the glacier margin. Deformation is ductile where the ice concentration exceeds c. 65% volume and predominantly brittle where the ice concentration is less than c. 65%. The change in rheology reflects transition in behaviour from the material having a predominantly frictional character when the ice is limited to pore spaces to a non-frictional character in which strength is primarily determined by the cohesive strength of the ice. This work shows that glaciotectonic deformation can occur in deeply frozen permafrost where there is no liquid pore water. We conclude that the presence of liquid porewater is not a necessary condition for the development of glaciotectonic deformation or for the formation of push moraines. © 2019 John Wiley & Sons, Ltd.     

New insights into the heterogeneity of the Tagish Lake meteorite: Soluble organic compositions of variously altered specimens

The Tagish Lake carbonaceous chondrite exhibits a unique compositional heterogeneity that may be attributed to varying degrees of aqueous alteration within the parent body asteroid. Previous analyses of soluble organic compounds from four Tagish Lake meteorite specimens (TL5b, TL11h, TL11i, TL11v) identified distinct distributions and isotopic compositions that appeared to be linked to their degree of parent body processing (Herd et al. 2011; Glavin et al. 2012; Hilts et al. 2014). In the present study, we build upon these initial observations and evaluate the molecular distribution of amino acids, aldehydes and ketones, monocarboxylic acids, and aliphatic and aromatic hydrocarbons, including compound‐specific δ¹³C compositions, for three additional Tagish Lake specimens: TL1, TL4, and TL10a. TL1 contains relatively high abundances of soluble organics and appears to be a moderately altered specimen, similar to the previously analyzed TL5b and TL11h lithologies. In contrast, specimens TL4 and TL10a both contain relatively low abundances of all of the soluble organic compound classes measured, similar to TL11i and TL11v. The organic‐depleted composition of TL4 appears to have resulted from a relatively low degree of parent body aqueous alteration. In the case of TL10a, some unusual properties (e.g., the lack of detection of intrinsic monocarboxylic acids and aliphatic and aromatic hydrocarbons) suggest that it has experienced extensive alteration and/or a distinct organic‐depleted alteration history. Collectively, these varying compositions provide valuable new insights into the relationships between asteroidal aqueous alteration and the synthesis and preservation of soluble organic compounds.     

Size fractionation and optical properties of colloids in an organic-rich estuary (Thurso, UK)

The optical characteristics of a black water river estuary from the north coast of Scotland were examined in the filtered (0.4 µm), ultrafiltered (5 kDa) and colloid-enriched fractions of estuarine samples. The samples were collected over the full salinity range during a period when the pH was relatively constant (8.2–8.5) throughout the estuary, allowing the influence of salinity on estuarine colloidal processes to be distinguished. The properties examined in the bulk, the low molecular weight (LMW) and the colloidal fraction (HMW) were UV–visible absorption, 3-D fluorescence excitation–emission matrix (EEM) spectrum, inorganic and organic carbon, mean size (by dynamic light scattering), and size distribution by flow field-flow fractionation analysis (FlFFF). The combined results of these analyses support the view that river-borne, humic-rich colloids underwent two types of transformation upon mixing with the seawater end member. The first one resulted in an apparent increase in the abundance of LMW constituents and may be explained by coiling of the individual humic macromolecules. The second one resulted in an increase in the mean size measured in both the lower and higher colloidal size ranges, and may be explained by aggregation of colloids to form entities that were still mostly colloidal i.e., smaller than 0.4 µm. The LMW contribution to the bulk optical properties increased with increasing salinity. Very similar findings were obtained from simulated mixing experiments using a Nordic Reference NOM extract as a source of freshwater colloids. This indicates that changes in the molecular architecture and molar mass of river-borne colloids—not changes in their chemical nature—were responsible for the observed variations in the spectral characteristics of CDOM in this estuary.     

Incorporating geographies of health into public policy debates: The GeoHealth Laboratory

Abstract:  The restricted influence of geographers in the policy arena has been the source of some angst. This paper reports on a new initiative at the University of Canterbury, which aims to strengthen geography's contribution to health policy debates in New Zealand. The GeoHealth Laboratory is a joint initiative between the Department of Geography and Public Health Intelligence group at the Ministry of Health that seeks to provide a pathway for the integration of health geography research into policy development. This new facility aligns the expertise in health geography, GIS and other spatial analytical methods with policy-relevant research priorities. An overview of the strategic aims of the GeoHealth Laboratory is provided along with some examples of recent research activities that are contributing to understandings of the health landscape in New Zealand. It is argued that such partnerships provide important opportunities for geographers to engage with policy-relevant issues.     

地铁隧道施工引起地层位移规律的探讨

目前对城市隧道开挖所引起的地表以下地层的位移规律的认识还很不充分，长期以来只有定性地认识。英国学者Mair等人（1993年）根据在黏土中的有限实测资料，基于预测地表位移的Peck公式，考虑了沉降槽宽度随深度变化，从而提出了地表以下的位移计算公式。他们的研究成果被广泛引用，但是由于其仅适用于黏性土，且假定地表处沉降槽宽度参数为0.5，因此在应用上受到很大的限制。在Mair公式的基础上，着重讨论了沉降槽宽度参数随地层深度的变化趋势，并提出了修正计算公式，不仅可以考虑地表沉降槽宽度参数与0.5相差较大的情况，还适用于砂类土地层，因此比Mair公式具有更广泛的适用性。     

Verifying Inventory Predictions of Animal Methane Emissions with Meteorological Measurements

The paper examines the strengths and weaknesses of a rangeof meteorological flux measurement techniques that mightbe used to verify predictions of greenhouse gas inventories.Recent research into emissions of methane (CH₄)produced by enteric fermentation in grazing cattle and sheepis used to illustrate various methodologies. Quantifying thisimportant source presents special difficulties because the animalsconstitute moving, heterogeneously distributed, intermittent, pointsources. There are two general approaches: one, from the bottom up,involves direct measurements of emissions from a known number ofanimals, and the other, from the top down, infers areal emissions ofCH₄ from its atmospheric signature. A mass-balance methodproved successful for bottom-up verification. It permits undisturbedgrazing, has a simple theoretical basis and is appropriate for fluxmeasurements on small plots and where there are scattered pointsources. The top-down methodologies include conventional flux-gradientapproaches and convective and nocturnal boundary-layer (CBL and NBL)budgeting schemes. Particular attention is given to CBL budget methods inboth differential and integral form. All top-down methodologies require ideal weather conditions for their application, and they suffer from the scattered nature of the source, varying wind directions and low instrument resolution. As for mass-balance, flux-gradient micrometeorological measurements were in good agreement with inventory predictions of CH₄ production by livestock, but the standard errors associated with both methods were too large to permit detection of changes of a few per cent in emission rate, which might be important for inventory, regulatory or research purposes. Fluxes calculated by CBL and NBL methods were of the same order of magnitude as inventory predictions, but more improvement is needed before their use can be endorsed. Opportunities for improving the precision of both bottom-up and top-down methodologies are discussed.     

Temporal Variability of Iron Speciation in Coastal Rainwater

Iron occurs in rain as particulateand dissolved Fe and includes both Fe(II) and Fe(III)species. Model calculations and correlation analysisindicate Fe(II)(aq) occurs almost exclusively as thefree ion whereas Fe(III)(aq) occurs as both ironoxalate and Fe(OH)₂ ⁺(aq) with largevariations over the pH range from 4.0 to 5.0. Complexation with humic-like compounds may also beimportant for Fe(III)(aq); however, the concentrationand structural characteristics of these compounds haveyet to be determined. 112 rain samples were collectedfor iron analysis in Wilmington, North Carolina,between 1 July 1997, and 30 June 1999. Total iron,particulate iron and Fe(III)(aq) were higher inconcentration in summer and spring rain relative towinter and autumn rain. Fe(II)(aq) concentrations, incontrast, did not vary seasonally. Particulate iron,which was approximately half the total rainwater iron,was highest between noon and 6 p.m. (EST), probably dueto more intense regional convection including land-seabreezes during that time. The ratio ofFe(II)(aq)/Fe(III)(aq) was also highest in rainreceived between noon and 6 p.m., which most likelyreflects photochemical reduction of Fe(III)(aq)complexes to form Fe(II)(aq). A conceptual modeldepicting the interplay between iron species, lightintensity and organic ligands in rainwater ispresented.     

The Carboniferous Southern Pennine Basin,UK

Many of the Carboniferous outcrops located in the Derbyshire region of the Peak District National Park, UK, have provided sites for both significant and pioneering research relating to the clastic sedimentology of marine palaeoenvironments, particularly so during the 1960s and 1970s when early models describing the sedimentary architecture of fluvio‐deltaic, submarine‐slope and deep‐marine submarine‐fan sedimentation were first developed. The area was subject to hydrocarbon exploration from the 1920s to 1950s, which although unsuccessful in economic terms left a legacy of sub‐surface data. Despite a long‐history of sedimentological research, the deposits exposed at several classic localities in the Pennine Basin continue to broaden and challenge our current understanding of sedimentary processes to this day.     

Complete metamorphic cycle and long-lived anatexis in the c. 2.1 Ga Mistinibi Complex,Canada

Secular changes in the architecture, thermal state, and metamorphic style of global orogens are thought to have occurred since the Archean; however, despite widespread research, the driving mechanisms for such changes remain unclear. The Paleoproterozoic may prove to be a key era for investigating secular changes in global orogens, as it marks the earliest stage of an eon that saw the onset of modern-style global tectonics. The 2.1 Ga granulite-facies Mistinibi-Raude Domain (MRD), located in the Southeastern Churchill Province, Canada, offers a rare exposure of Paleoproterozoic high metamorphic grade supracrustal sequences (Mistinibi Complex, MC). Rocks from this domain were subjected to petrochronological investigations to establish P–T–t–X evolutions and to provide first order thermal state, burial and exhumation rates, and metamorphic gradients for the transient Paleoproterozoic times. To obtain comprehensive insight into the P–T–t–X evolution of the MRD, we used multi-method geochronology—Lu–Hf on garnet and U–Pb on zircon and monazite—integrated with detailed petrography, trace element chemistry, and phase equilibria modelling. Despite the extensive use of zircon and monazite as geochronometers, their behaviour in anatectic conditions is complex, leading to substantial ambiguity in interpreting the timing of prograde metamorphism. Our results indicate a clockwise metamorphic path involving significant melt extraction from the metasedimentary rocks, followed by cooling from >815°C to ~770°C at ~0.8 GPa. The timing of prograde burial and cooling from supra- to subsolidus conditions is constrained through garnet, monazite, and zircon petrochronology at 2,150–2,120 Ma and at 2,070–2,080 Ma, respectively. These results highlight long-lived residence of the rocks at mid-crustal supra-solidus conditions (55–70 Ma), with preserved prograde and retrograde supra-solidus monazite and zircon. The rocks record extremely slow burial rates (0.25–0.30 km/Ma) along a high metamorphic gradient (900–1,000°C/GPa), which appears symptomatic of Paleoproterozoic orogens. The MC did not record any significant metamorphism after 2,067 Ma, despite having collided with terranes that record high-grade metamorphism during the major 1.9–1.8 Ga Trans-Hudson orogeny. The MC would therefore represent a remnant of a local early Paleoproterozoic metamorphic infrastructure, later preserved as superstructure in the large hot Trans-Hudson orogen.     

On the Importance of Time for GIS View Measures and Their Use in Hedonic Property Models: Does Being Temporally Explicit Matter?

Progress in GIScience has advanced the ability to represent and analyze view characteristics. GIS‐derived view measures requiring digital elevation surface models are used in hedonic property models to quantify the amenity value of view for parcel sales transactions. Ideally models should represent surface elevations that are temporally synchronized with parcel sale dates. Temporal synchronization for studies spanning multiple years may require significant effort. Few studies have undertaken this effort, leading us to investigate in this research the need to be temporally explicit. We evaluate two competing surface model approaches based on: (1) a single year 2000 LiDAR surface product; and (2) annual‐specific surface products for 1995–2002. Two competing view measures based on the different surface approaches are constructed for 561 parcel transactions during 1995–2002 in a coastal North Carolina county and are input into hedonic regression models. Results showed that being temporally explicit did matter in terms of finding significantly different view measures but did not matter in terms of finding significantly different effects of view on parcel sales prices. Despite mixed results for our case study, we advise that future research involving GIS‐based view measurement should consider the spatial and temporal contexts of study area development patterns when evaluating the need to be temporally explicit.