Evidence of polycyclic aromatic hydrocarbon (PAH) exposure in fish from the Antarctic peninsula

PAH exposure was assessed in fish from Arthur Harbor, Antarctica and sites remote from human activities by measuring the concentrations of polycyclic aromatic hydrocarbon (PAH) metabolites in bile and PAH in tissues and stomach contents. The highest concentrations of biliary metabolites and tissue PAH were present in fish captured near an Argentine supply ship (Bahia Paraiso) that ran aground in Arthur Harbor in 1989. The presence of biliary PAH metabolites in fish collected near Palmer Station, a small US scientific station in Arthur Harbor, suggests low level exposure to contaminants. However, PAH tissue concentrations in fish from Palmer Station were similar to those from remote sites. Both tissue PAH and metabolite concentrations were low in fish captured at sites remote from human activities. The confirmation of PAH metabolites in the bile of fish from Arthur Harbor is direct evidence that the presence of humans has resulted in Antarctic fish being exposed to petroleum-derived PAH.     

Anomalous structural evolution of the Shimanto Accretionary Prism at Murotomisaki, Shikoku Island, Japan

Abstract The Late Oligocene-Early Miocene Nabae Sub-belt of the Shimanto Accretionary Prism was created coevally (ca 25-15 Ma) with the opening of the Shikoku back-arc basin, located to the south of the southwest Japan convergent margin. The detailed geology of the sub-belt has been controversial and the interaction of the Shimanto accretionary prism and the opening of the Shikoku Basin has been ambiguous. New structural analysis of the sub-belt has led to a new perception of its structural framework and has significant bearing on the interpretation of the Neogene tectonics of southwest Japan. The sub-belt is divided into three units: the Nabae Complex; the Shijujiyama Formation; and the Maruyama Intrusive Suite. The Nabae Complex comprises coherent units and mélange, all of which show polyphase deformation. The first phase of deformation appears to have involved landward vergent thrusting of coherent units over the mélange terrane. The second phase of deformation involved continued landward vergent shortening. The Shijujiyama Formation, composed mainly of mafic volcanics and massive sandstone, is interpreted as a slope basin deposited upon the Nabae Complex during the second phase of deformation. The youngest deformational pulse involved regional flexing and accompanying pervasive faulting. During this event, mafic rocks of the Maruyama Intrusive Suite intruded the sub-belt. Fossil evidence in the Nabae Complex and radiometric dates on the intrusive rocks indicate that this tectonic scheme was imprinted upon the sub-belt between ～23 and ～14 Ma. The timing of accretion and deformation of the sub-belt coincides with the opening of the Shikoku Basin; hence, subduction and spreading operated simultaneously. Accretion of the Nabae Sub-belt was anomalous, involving landward vergent thrusting, magmatism in newly accreted strata and regional flexing. It is proposed that this complex and anomalous structural history is largely related to the subduction of the active Shikoku Basin spreading ridge and associated seamounts.     

Gulf of Mexico hydrocarbon seep communities—IX. Sterol biosynthesis of seep mussels and its implications for host-symbiont association

The sterol analysis of six hydrocarbon seep mussels (mytilid II and mytilid Ib) from the Alaminos Canyon in the Gulf of Mexico is reported. The sterol composition of the mussel-symbiotic bacteria complex reflects a preponderant synthesis of 4α-methyl sterols (seep mytilid II), and a predominant biosynthesis of 4-desmethyl sterols with some amounts of 4α-methyl sterols (seep mytilid Ib). This suggests a methane-based symbiotic relationship between the mussels and methanotrophic bacteria. It also suggests that the biosynthesis of sterols in the mussel-bacteria complex is completed to the level of cholest-5-en-3ß-ol (mytilid II) or 5α-cholestan-3ß-ol (mytilid Ib).     

Sr-Isotope record of Quaternary marine terraces on the California coast and off Hawaii

Strontium-isotopic ratios of dated corals have been obtained from submerged reefs formed during Quaternary glacial periods off the Hawaiian islands. These data, combined with data from deep-sea sediments, tightly constrain the secular variation of marine ⁸⁷Sr/⁸⁶Sr for the past 800,000 yr. Although long-term trends are apparent, no significant (>0.02‰), rapid (<100,000 yr) excursions in ⁸⁷Sr/⁸⁶Sr were resolved nor did we observe any samples with ⁸⁷Sr/⁸⁶Sr greater than that of modern seawater. Strontium in mollusks from elevated marine terraces formed during interglacial periods on the southern California coast show resolvable and consistent variations in ⁸⁷Sr/⁸⁶Sr which, when compared to the trend of Quaternary marine ⁸⁷Sr/⁸⁶Sr, can be used to infer uplift rates and define approximate ages for the higher terraces. The Sr-isotope age estimates indicate that uplift rates vary among crustal blocks and were not necessarily constant with time. No contrast in Sr-isotopic ratios between similar-age Hawaiian and California fossils was observed, confirming that any change in marine ⁸⁷Sr/⁸⁶Sr from glacial to interglacial periods must be small. A realistic appraisal of the potential of Sr-isotope stratigraphy for chronometric applications in the Quaternary suggests that the technique will be limited to relatively coarse distinctions in age.     

Internal wave characteristics in the eastern Arabian Sea during summer monsoon

The time series BT profiles and surface winds and atmospheric pressure, collected in the deep waters off Ratnagiri and Karwar during summer monsoon were utilized to document the characteristics of internal waves (IW). Low-frequency (≤2, cycle per day (cpd)) IW off Ratnagiri are found to propagate at 83 cm/s with wavelengths of 45 km and wave heights upto 40 m. These parameters for high-frequency (>2 cpd) IW off Karwar correspond to 99 cm/s, 3 km and 23 m. The IW off Karwar appear to leave the station at 70° (±10°) (measured from the horizontal). The data sets were further analysed to address the harmonic composition of the IW and identify the possible sources for the observed IW fields. Power spectra of the IW indicated energy peaks at inertial (0·6 cpd) and tidal (1 and 2 cpd) frequencies off Ratnagiri and in the high-frequency band of 0·5–2·0 cycles per hour off Karwar. The coherence between the IW and wind/tide is found to be good at several frequencies within the IW spectrum. This feature probably suggests tides as a source for the IW of tidal frequencies and winds and tides as a joint source for the IW at the remaining frequencies.     

Nd isotopic evidence for the position of southernmost Indian terranes within East Gondwana

Sm-Nd model ages of orthopyroxene-bearing massif charnockites from the Cardamom Hills Massif and adjoining supracrustal rocks from the Kerala Khondalite Belt in southernmost India are used to infer some of the relationships within these rocks and between them and neighboring areas. Most of these rocks have model ages of 2.1–2.8 Ga with most charnockites in the range 2.2–2.6 Ga. Thus, 3.0–3.4 Ga Archean rocks to their north did not contribute material to either suite and the two suites may have been juxtaposed after formation of the supracrustal rocks. The similarity of Sm-Nd isotope systems in the two units studied here supports an argument that the massif charnockites were the primary sole source of the detritus incorporated into the supracrustal rocks. A cordierite gneiss, representative of a relatively minor lithology in the supracrustal belt, has a model age of 1.3 Ga. The protolith of this gneiss not only formed from much younger material than the rest of the belt but also formed significantly after the other metasedimentary rocks. The source material of the gneiss protolith may have been located in the Wanni and Vijayan Complexes of Sri Lanka. The overlap of the model ages of rocks in this area and those in the Highland Complex of Sri Lanka supports the notion that these two sets of rocks were joined to each other in Gondwana. They belong to a belt that ran from Antarctica through Sri Lanka and India into Madagascar. This belt was involved in Pan-African tectono-metamorphism, as reflected in the 550 Ma age of the last, granulite-forming, event throughout the belt.     

Optimum damping in linear isolation systems

Optimum isolation damping for minimum acceleration response of base-isolated structures subjected to stationary random excitation is investigated. Three linear models are considered to account for the energy dissipation mechanism of the isolation system: a Kelvin element, a linear hysteretic element and a standard solid linear element, commonly used viscoelastic models for isolation systems comprising natural rubber bearings and viscous dampers. The criterion selected for optimality is the minimization of the mean-square floor acceleration response. The effects of the frequency content of the excitation and superstructure properties on the optimum damping and on the mean-square acceleration response are addressed. The study basically shows that the attainable reduction in the floor acceleration largely depends on the energy dissipation mechanism assumed for the isolation system as well as on the frequency content of the ground acceleration process. Special care should be taken in accurately modelling the mechanical behaviour of the energy dissipation devices.     

Seismic response of heavily damped base isolation systems

The development of an efficient energy-dissipating mechanism that works in conjunction with laminated elastomeric bearings in order to reduce the lateral deformation of the isolation system has always been a goal of base isolation research. Theoretically, this deformation will be reduced to the minimum if damping augmentation of the isolation system can reach a critical value. However, augmenting the isolation damping may cause some unwanted side effects. The purpose of this paper is to study the influence of isolation damping on the seismic response of heavily damped base-isolated buildings. The base isolation system is assumed to be linearly viscoelastic and is analysed using the complex mode method. Solutions derived by using perturbation techniques for a two-degree-of-freedom system and the computer simulation for a multiple-degree-of-freedom system reveal that augmenting the isolation damping can reduce efficiently the deformation of the isolation system, but at the price of increasing the high-frequency vibration in the superstructure. When the damping ratio of the isolation system is beyond some level, increasing the isolation damping will enlarge the extreme values of the base and superstructural accelerations. It is also found that approximate solutions derived from the use of classical damping and classical modes of vibration in the seismic analysis of heavily damped base isolation systems can be substantially in error.