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191.
James D Sidaway 《Area》2005,37(4):373-377
This paper examines a key aspect of how the global geometries of finance and trade articulate the euro–dollar relationship. Here, European integration extends into a global financial and trading system replete with contradictions. The paper examines these, drawing upon a literature from international political economy, foregrounding the spatialities that they signal. 相似文献
192.
Kelly Addy Arthur Gold Barbara Nowicki James McKenna Mark Stolt Peter Groffman 《Estuaries and Coasts》2005,28(6):896-908
Coastal waters are severely threatened by nitrogen (N) loading from direct groundwater discharge. The subterranean estuary,
the mixing zone of fresh groundwater and sea water in a coastal aquifer, has a high potential to remove substantial N. A network
of piezometers was used to characterize the denitrification capacity and groundwater flow paths in the subterranean estuary
below a Rhode Island fringing salt marsh.15N-enriched nitrate was injected into the subterranean estuary (in situ push-pull method) to evaluate the denitrification capacity
of the saturated zone at multiple depths (125–300 cm) below different zones (upland-marsh transition zone, high marsh, and
low marsh). From the upland to low marsh, the water table became shallower, groundwater dissolved oxygen decreased, and groundwater
pH, soil organic carbon, and total root biomass increased. As groundwater approached the high and low marsh, the hydraulic
gradient increased and deep groundwater upwelled. In the warm season (groundwater temperature >12 °C), elevated groundwater
denitrification capacity within each zone was observed. The warm season low marsh groundwater denitrification capacity was
significantly higher than all other zones and depths. In the cool season (groundwater temperature <10.5 °C), elevated groundwater
denitrification capacity was only found in the low marsh. Additions of dissolved organic carbon did not alter groundwater
denitrification capacity suggesting that an alternative electron donor, possibly transported by tidal inundation from the
root zone, may be limiting. Combining flow paths with denitrification capacity and saturated porewater residence time, we
estimated that as much as 29–60 mg N could be removed from 11 of water flowing through the subterranean estuary below the
low marsh, arguing for the significance of subterranean estuaries in annual watershed scale N budgets. 相似文献
193.
The sources of carbon, which fuel water column respiration, remain unresolved for most estuaries; our objective was to examine
carbon dynamics in a shallow subtropical estuary. We sampled the Sabine-Neches estuary, Texas, during low (November 1999)
and high (May 2000) freshwater inflow and measured stable carbon isotope ratios of the dissolved inorganic and orgnaic carbon
(δ13C-DIC, δ13C-DOC), as well as quantifying accessory parameters (salinity, nutrients, total suspended solids, and photosynthetic pigments).
Pigment analysis indicated that diatoms were the predominant phytoplankton. Data from the May 2000 sampling event exhibited
conservative mixing, indicating that the system was acting as a conduit between the watershed and the Gulf of Mexico. During
November, mixing was generally nonconservative indicating extensive recycling of allochthonous and autochthonous carbon sources.
Our data imply that both carbon sources had similar isotope, ratios that made it impossible to unambiguously determine the
dominant source supporting respiration. The nonconservative DIC concentration data indicating an autotrophic sink as well
as the strong relationship between δ13C-DOC and chlorophylla, suggest that in situ production was an important component of the DOC pool. We hypothesize that uncharacteristically calm
wind conditions during sampling may have promoted phytoplankton settling, removing autotrophs, from the water column, but
leaving behind a dissolved biogeochemical signature. Interpretation of carbon dynamics may be confounded by spatial and temporal
decoupling of producers and consumers from biogeochemical indicators. 相似文献
194.
Continental rift systems and anorogenic magmatism 总被引:1,自引:0,他引:1
Precambrian Laurentia and Mesozoic Gondwana both rifted along geometric patterns that closely approximate truncated-icosahedral tessellations of the lithosphere. These large-scale, quasi-hexagonal rift patterns manifest a least-work configuration. For both Laurentia and Gondwana, continental rifting coincided with drift stagnation, and may have been driven by lithospheric extension above an insulated and thermally expanded mantle. Anorogenic magmatism, including flood basalts, dike swarms, anorthosite massifs and granite-rhyolite provinces, originated along the Laurentian and Gondwanan rift tessellations. Long-lived volcanic regions of the Atlantic and Indian Oceans, sometimes called hotspots, originated near triple junctions of the Gondwanan tessellation as the supercontinent broke apart. We suggest that some anorogenic magmatism results from decompression melting of asthenosphere beneath opening fractures, rather than from random impingement of hypothetical deep-mantle plumes. 相似文献
195.
James C. Hower Cortland F. Eble Jeffrey C. Quick 《International Journal of Coal Geology》2005,62(4):223-236
Mercury emissions from US coal-fired power plants will be regulated by the US Environmental Protection Agency (USEPA) before the end of the decade. Because of this, the control of Hg in coal is important. Control is fundamentally based on the knowledge of the amounts of Hg in mined, beneficiated, and as-fired coal. Eastern Kentucky coals, on a reserve district level, have Hg contents similar to the USA average for coal at mines. Individual coals show greater variation at the bench scale, with Hg enrichment common in the top bench, often associated with enhanced levels of pyritic sulfur. Some of the variation between parts of eastern Kentucky is also based on the position relative to major faults. The Pine Mountain thrust fault appears to be responsible for elemental enrichment, including Hg, in coals on the footwall side of the thrust.Eastern Kentucky coals shipped to power plants in 1999, the year the USEPA requested coal quality information on coal deliveries, indicate that coals shipped from the region have 0.09 ppm Hg, compared to 0.10 ppm for all delivered coals in the USA. On an equal energy basis, and given equal concentrations of Hg, the high volatile bituminous coals from eastern Kentucky would emit less Hg than lower rank coals from other USA regions. 相似文献
196.
IPCC reports provide a synthesis of the state of the science in order to inform the international policy process. This task is made difficult by the presence of deep uncertainty in the climate problem that results from long time scales and complexity. This paper focuses on how deep uncertainty can be effectively communicated. We argue that existing schemes do an inadequate job of communicating deep uncertainty and propose a simple approach that distinguishes between various levels of subjective understanding in a systematic manner. We illustrate our approach with two examples. To cite this article: M. Kandlikar et al., C. R. Geoscience 337 (2005). 相似文献
197.
Kevin R. T. Whelan Thomas J. Smith Donald R. Cahoon James C. Lynch Gordon H. Anderson 《Estuaries and Coasts》2005,28(6):833-843
We measured monthly soil surface elevation change and determined its relationship to groundwater changes at a mangrove forest
site along Shark River, Everglades National Park, Florida. We combined the use of an original design, surface elevation table
with new rod-surface elevation tables to separately track changes in the mid zone (0–4 m), the shallow root zone (0–0.35 m),
and the full sediment profile (0–6 m) in response to site hydrology (daily river stage and daily groundwater piezometric pressure).
We calculated expansion and contraction for each of the four constituent soil zones (surface [accretion and erosion; above
0 m], shallow zone [0–0.35 m], middle zone [0.35–4 m], and bottom zone [4–6]) that comprise the entire soil column. Changes
in groundwater pressure correlated strongly, with changes in soil elevation for the entire profile (Adjusted R2 = 0.90); this relationship was not proportional to the depth of the soil profile sampled. The change in thickness of the
bottom soil zone accounted for the majority (R2 = 0.63) of the entire soil profile expansion and contraction. The influence of hydrology on specific soil zones and absolute
elevation change must be considered when evaluating the effect of disturbances, sea level rise, and water management decisions
on coastal wetland systems. 相似文献
198.
The influence of edge sites on the development of surface charge on goethite nanoparticles: A molecular dynamics investigation 总被引:1,自引:0,他引:1
Large-scale molecular simulation of proton accumulations were carried out on (i) (110) and (021) slabs immersed in aqueous solution and (ii) a series of model goethite nanoparticles of dimension 2 to 8 nm with systematically varying acicularity and (110)/(021) surface areas. In the slab systems, the (021) surface exhibits 15% more proton charge per unit area than the (110) surface. In the particulate systems, the acicular particles having the highest (110)/(021) ratio accumulate the most charge, opposite to the trend expected from the slab simulations, indicating that, at length scales on the order of 10 nm, the slab results are not a good indicator of the overall charging behavior of the particles. The primary reason for the discrepancy between the particulate systems and slab systems is the preferential accumulation of protons at acute (110)-(110) intersections. Charge accumulates preferentially in this region because excess proton charge at an asperity is more effectively solvated than at a flat interface. 相似文献
199.
13C/12C and 18O/16O ratios of aragonite shells of modern land snails from the southern Great Plains of North America were measured for samples from twelve localities in a narrow east-west corridor that extended from the Flint Hills in North Central Oklahoma to the foothills of the Sangre de Cristo Mountains in Northern New Mexico, USA. Across the study area, shell δ18O values (PDB scale) ranged from −4.1‰ to 1.2‰, while δ13C values ranged from −13.2‰ to 0.0‰. δ18O values of the shell aragonite were predicted with a published, steady state, evaporative flux balance model. The predicted values differed (with one exception) by less than 1‰ from locality averages of measured δ18O values. This similarity suggests that relative humidity at the time of snail activity is an important control on the δ18O values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells. Correlated δ13C values of coexisting Vallonia and Gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern Great Plains plant ecology. Although there is considerable scatter, multispecies, transect average δ13C values of the modern aragonite shells are related to variations in the type of photosynthesis (i.e., C3, C4) in the local plant communities. The results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals, species, etc., and thus better represent the “neighborhood” scale temporal and/or spatial environmental variations of interest in studies of modern and ancient systems. 相似文献
200.
Critical rainfall statistics for predicting watershed flood responses: rethinking the design storm concept 下载免费PDF全文
Recent advances have been made to modernize estimates of probable precipitation scenarios; however, researchers and engineers often continue to assume that rainfall events can be described by a small set of event statistics, typically average intensity and event duration. Given the easy availability of precipitation data and advances in desk‐top computational tools, we suggest that it is time to rethink the ‘design storm’ concept. Design storms should include more holistic characteristics of flood‐inducing rain events, which, in addition to describing specific hydrologic responses, may also be watershed or regionally specific. We present a sensitivity analysis of nine precipitation event statistics from observed precipitation events within a 60‐year record for Tompkins County, NY, USA. We perform a two‐sample Kolmogorov–Smirnov (KS) test to objectively identify precipitation event statistics of importance for two related hydrologic responses: (1) peak outflow from the Six Mile Creek watershed and (2) peak depth within the reservoir behind the Six Mile Creek Dam. We identify the total precipitation depth, peak hourly intensity, average intensity, event duration, interevent duration, and several statistics defining the temporal distribution of precipitation events to be important rainfall statistics to consider for predicting the watershed flood responses. We found that the two hydrologic responses had different sets of statistically significant parameters. We demonstrate through a stochastic precipitation generation analysis the effects of starting from a constrained parameter set (intensity and duration) when predicting hydrologic responses as opposed to utilizing an expanded suite of rainfall statistics. In particular, we note that the reduced precipitation parameter set may underestimate the probability of high stream flows and therefore underestimate flood hazard. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献