The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

LEVINSON INVERSION OF EARTHQUAKE GEOMETRY SH-TRANSMISSION SEISMOGRAMS IN THE PRESENCE OF NOISE*

The Kunetz-Claerbout equation for the acoustic transmission problem in a layered medium in its original form establishes the relation between the transmission and the reflec tion response for P-waves in an horizontally layered medium and with vertical incidence. It states that the reflection seismogram due to an impulsive source at the surface, is one side of the autocorrelation of the seismogram due to an impulsive source at depth and a surface receiver. By adapting Claerbout's formulation to the transmission of SH-waves, the Kunetz-Claerbout equation also holds for reflection and transmission coefficients dependent on the incident angle. Thus, earthquake geometry SH-transmission seismograms can be used to caculate corresponding pseudoreflection seismograms which, in turn, can be inverted for the impedance structure using the Levinson algorithm. If the average incidence angle is known, a geometrical correction on the resulting impedance model can improve the resolution of layer thicknesses. In contrast to the inversion of reflection seismograms, the Levinson algorithm is shown to yield stable results for the inversion of transmission seismograms even in the presence of additive noise. This noise stabilization is inherent to the Kunetz-Claerbout equation. Results of inverted SH-wave microearthquake seismograms from the Swabian Jura, SW Germany, seismic zone obtained at recording site Hausen im Tal have been compared with sonic-log data from nearby exploration drilling at Trochtelfingen. The agreement of the main structural elements is fair to a depth of several hundred metres.     

Microbial community dynamics and biodegradation of polycyclic aromatic hydrocarbons in polluted marine sediments in Hong Kong

Dynamics of microbial community and biodegradation of polycyclic aromatic hydrocarbons (PAHs) in polluted marine sediments, artificially spiked with a mixture of PAHs (fluorene, phenanthrene, fluoranthene and pyrene), were examined for a period of 60 days. Microbial communities were characterised by bacterial counts, ester-linked fatty acid methyl ester (EL-FAME) analysis and denaturing gradient gel electrophoresis (DGGE). A noted reduction in species diversity occurred only in the high PAH level treatment at onset. Both EL-FAME and DGGE demonstrated a marked shift in microbial community, in all the PAH level treatments, afterwards, with increases in the number of fatty acid degraders, the relative abundance of fatty acid biomarkers for gram-negative bacteria and a decrease in species diversity. The shift was also accompanied by the significant decrease in PAH concentrations. By the end of the experiment, diversity indices, based on both approaches, recovered when PAH concentrations declined to their background levels, except in the high PAH level treatment.     

Comparison of ecophysiological characteristics between introduced and indigenous mangrove species in China

Due to its rapid growth, the introduced mangrove species Sonneratia apetala from Bangladesh has been widely used in mangrove restoration in southeastern China since 1985. As an indigenous mangrove species in Hainan, China, Sonneratia caseolaris was also planted in Guangdong Province for afforestation purposes. Both species have developed well in their new habitats, but their ecophysiological differences with the native mangrove species have not been studied. In this study, leaf gas exchange, water and nitrogen use efficiencies of two Sonneratia species were compared with those of selected native mangrove species (Avicennia marina, Aegiceras corniculatum, Kandelia candel, and Excoecaria agallocha) in Hainan and Shenzhen. The introduced S. apetala maintained lower carbon assimilation rate (A) and photosynthetic nitrogen use efficiency (PNUE) than the indigenous S. caseolaris. In Shenzhen, the two introduced Sonneratia had comparable photosynthetic rates and water use efficiency (WUE) with the native mangrove species, except that PNUE in S. caseolaris was significantly higher than in the native mangrove species. The two Sonneratia species showed significant overlap in PNUE and long-term WUE. Photosynthetic parameters derived from leaf photosynthetic light–response curves and A–C_i curves also suggested lower carbon assimilation capacities for the introduced Sonneratia than for the native mangrove species in both study sites. The lower light compensation point (LCP) of two introduced Sonneratia in both study sites also indicated a better adaptation to a low light regime than the native mangrove species. The results of photosynthetic capacities indicated that the introduced mangrove species have little competitive advantage over local native mangrove species in their respective new habitats.     

Risk Management for Petroleum Reservoir Production: A Simulation-Based Study of Prediction

We consider numerical solutions of the Darcy and Buckley–Leverett equations for flow in porous media. These solutions depend on a realization of a random field that describes the reservoir permeability. The main content of this paper is to formulate and analyze a probability model for the numerical coarse grid solution error. We explore the extent to which the coarse grid oil production rate is sufficient to predict future oil production rates. We find that very early oil production data is sufficient to reduce the prediction error in oil production by about 30%, relative to the prior probability prediction.     

Über den Eisengehalt von Alumosilikaten aus Quarzknauern

Zusammenfassung Der Eisengehalt von Andalusiten und Disthenen aus Quarzknauern im Gebiet des Ötztaler—Stubaier Altkristallins wurde regional untersucht. Der Gehalt and Gesamteisen in primären Disthen liegt zwischen 0,17 und 0,22 Gew.% Fe₂O₃, während primäre Andalusite zwischen 0,26 und 1,93 Gew.% Fe₂O₃ schwanken. Dieser Unterschied in den Andalusiten wird auf ein wechselndes Angebot von Fe₂O₃ aus dem Nachbargestein der Knauern zurückgeführt.Ein Zusammenhang zwischen dem Eisengehalt der Andalusite und den verschiedenen Umwandlungsstadien Andalusit—Disthen konnte nicht nachgewiesen werden.

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On the iron content of alumosilicates in quartz nodules

Summary A determination of the regional distribution of the ironcontent of andalusites and kyanites in quartz-segregations of the Oetztal—Stubai crystalline complex gave values of 0.17–0.22% for the total iron in primary kyanite and 0.26–1.93% in andalusite. This difference is probably due to a variation in the Fe₂O₃-content in the country rocks of the quartz veins. No relationship between the iron-content in andalusite and the different stages of transformation from andalusite to kyanite could be established.

     

First Data on the Isotopic Age of Zircons from Rocks of the Roseta Ultramafic Massif,Southern Margin of the São Francisco Craton (Brazil)

Doklady Earth Sciences - The results of isotope U–Pb dating of zircons from lherzolite and vein olivine orthopyroxenite composing the Roseta ultramafic massif are presented. The zircons...     

The role of prior model calibration on predictions with ensemble Kalman filter

This paper, based on a real world case study (Limmat aquifer, Switzerland), compares inverse groundwater flow models calibrated with specified numbers of monitoring head locations. These models are updated in real time with the ensemble Kalman filter (EnKF) and the prediction improvement is assessed in relation to the amount of monitoring locations used for calibration and updating. The prediction errors of the models calibrated in transient state are smaller if the amount of monitoring locations used for the calibration is larger. For highly dynamic groundwater flow systems a transient calibration is recommended as a model calibrated in steady state can lead to worse results than a noncalibrated model with a well-chosen uniform conductivity. The model predictions can be improved further with the assimilation of new measurement data from on-line sensors with the EnKF. Within all the studied models the reduction of 1-day hydraulic head prediction error (in terms of mean absolute error [MAE]) with EnKF lies between 31% (assimilation of head data from 5 locations) and 72% (assimilation of head data from 85 locations). The largest prediction improvements are expected for models that were calibrated with only a limited amount of historical information. It is worthwhile to update the model even with few monitoring locations as it seems that the error reduction with EnKF decreases exponentially with the amount of monitoring locations used. These results prove the feasibility of data assimilation with EnKF also for a real world case and show that improved predictions of groundwater levels can be obtained.     

Spectroscopic binaries near the North Galactic Pole paper 6: BD 33° 2206

Photoelectric radial-velocity measurements have confirmed O. C. Wilson’s finding that BD 33° 2206, the secondary star in the wide visual binary ADS 8470, is a spectroscopic binary. It has an eccentric orbit with a period of 100 days. Its γ-velocity is close to the constant radial velocity of the visual primary, confirming the physical association of the stars.