Strain localization in sand: an overview of the experimental results obtained in Grenoble using stereophotogrammetry

Experimental results are presented from the extensive program of drained plane strain compression tests on sand carried out in Grenoble over the last two decades. Systematic analysis of photographs of the deforming specimen allowed for measuring deformations and determining strain fields throughout the test, that is: prior to, at, and after the onset of strain localization. The principles, details and accuracy of the procedure are described, as well as its suitability to properly depict the patterns of deformation. Findings concerning the occurrence and progression of strain localization are discussed. The issues of shear band orientation and thickness are addressed, as well as temporary and persistent complex localization patterns, and the volumetric behaviour inside a band after its formation. The influence of such variables as initial state of the sand (effective stress and relative density), specimen size and slenderness, as well as grain size, is discussed. Copyright © 2004 John Wiley & Sons, Ltd     

Runoff responses to afforestation in a watershed of the Loess Plateau,China

Afforestation has been suggested as a means of improving soil and water conservation in north‐western China, especially on the Loess Plateau. Understanding of the hydrological responses to afforestation will help us develop sustainable watershed management strategies. A study was conducted during the period of 1956 to 1980 to evaluate runoff responses to afforestation in a watershed on the Loess Plateau with an area of 1·15 km², using a paired watershed approach. Deciduous trees, including locust (locusta L.), apricot (praecox L.) and elm (ulmus L.), were planted on about 80% of a treated watershed, while a natural grassland watershed remained unchanged. It was estimated that cumulative runoff yield in the treated watershed was reduced by 32% as a result of afforestation. A significant trend was also observed that shows annual runoff reduction increases with the age of the trees planted. Reduction in monthly runoff occurred mainly from June to September, which was ascribed to greater rainfall and utilization by trees during this period. Afforestation also resulted in reduction in the volume and peak flow of storm runoff events in the treated watershed with greater reduction in peak flow. Copyright © 2003 John Wiley & Sons, Ltd.     

Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

The bituminous mixtures of Tall-e Abu Chizan: A Vth millennium BC settlement in southwestern Iran

Various bituminous artifacts were excavated from the Tall-e Abu Chizan, a late prehistoric (Middle Susiana to Middle Uruk) settlement on the middle of the Curvy plain, between the Karun River and the Ram Hormoz Plain. All samples dated from the Vth millennium BC and cover three periods: 5000–4700 BC (Late Middle Susiana), 4700–4200 BC (Late Susiana 1) and 4200–3900 BC (Late Susiana 2). The bitumens were studied using the techniques of petroleum geochemistry and were compared both to the unaltered crude oils produced from the main oil fields in the area and to the famous Mamatain oil seeps. All samples are very rich in bitumen (average 46 wt%) which has been biodegraded and oxidized. Despite these alteration phenomena, δ¹³C of asphaltenes occur within a narrow range of less than 1‰ PDB. Biodegradation affected the steranes, terpanes, dibenzothiophenes and mono- and triaromatic steroids. Molecular characteristics of terpanes, especially the occurrence of 18α (H)-oleanane, suggest that the bitumen from Tall-e Abu Chizan is a mixture generated from Cretaceous Kazdhumi and Eocene Pabdeh petroleum source rocks. In that respect, bitumens from Tall-e Abu Chizan belong to the same oil family as oil from the Naft Safid field, which is in the vicinity of the archaeological site. In fact, the bitumen at Tall-e Abu Chizan likely originated from oil seepages at Naft Safid. These oil seeps have not yet been sampled or analysed.     

Iron (III)-silica interactions in aqueous solution: insights from X-ray absorption fine structure spectroscopy

The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions (m_Fe ∼ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH < 2.5), Fe is hexa-coordinated with 6 oxygens of H₂O- and/or OH-groups in the first coordination sphere of the metal, at an Fe-O distance of 2.00 ± 0.01 Å. With increasing pH (2.7 < pH < 13), these groups are rapidly replaced by bridging hydroxyls (-OH-) or oxygens (-O-), and polymerized Fe hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ∼3.47 ± 0.03 Å). The Fe-Fe coordination numbers (N_edge = 1-2; N_corner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3.At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05-m Si solutions (pH ∼ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Fe_edge ∼ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (∼12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe₂Si_1-2 and Fe₃Si_2-3 at pH < 3; (2) structures composed of Fe-Fe dimers and trimers sharing one or two edges of FeO₆-octahedra; and (3) silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ∼ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ∼20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell (R_Fe-O = 1.84 Å). This new finding implies that Fe may partially substitute for Si in the tetrahedral network of the silica polymers in Si-rich solutions.The results of this study demonstrate that aqueous silica can significantly inhibit iron polymerization and solid-phase formation, and thus increase the stability and mobility of Fe(III) in natural waters. The silica “poisoning” of the free corner sites of iron-hydroxide colloids should reduce the adsorption and incorporation of trace elements by these colloids in Si-rich natural waters.     

Spatial analysis weighting algorithm using Voronoi diagrams

Data layers that represent geographical constraints in a multidimensional GIS model must be appropriately weighted to effectively account for the diversity as well as the functional and spatial interrelationships between the constraints. This paper presents a spatial analysis weighting algorithm (SAWA) using Voronoi diagrams. The basic functions of the SAWA are defined so that the spatialization of weights is done according to two approaches: a global spatialization method based on the statistical distribution of the original data and a contextual approach where neighbourhood defined by Voronoi diagrams is integrated into the weighting functions. Different simulations on artificial and real maps applied to the problem of shortest path optimisation are analysed. The results show that the effective integration of the spatial dimension in a weighting process is not only possible but also improves the optimisation of shortest paths. Research is continuing to improve the contextual phase of the algorithm.     

The product spectra of gravity and barometric pressure in Europe

A total of 111 000 hourly values of gravity and barometric pressure from stations in Europe is analysed. The data consist of two sets of records from Brussels, an early set of 36 000 h length and a more recent set of 21 000 h length, a set of records from Bad Homburg of 24 000 h length, and a set of records from Strasbourg of 30 000 h length. All of the gravity measurements were made with similar superconducting instruments and the pressure data were recorded simultaneously at each superconducting gravimeter site. The four sets of records have different time bases, and to bring out common features and suppress individual station systematic errors, the product spectrum is introduced. Spectral density estimates are first computed for a common spectral window for each record, and the product spectrum is formed by multiplying individual spectral estimates across records. The cumulative distribution function is found for the product spectrum and confidence intervals are calculated from it by iteration. The product spectrum in gravity reveals a triplet of resonances in the subtidal band which are shown by an automated computer search to be uniquely associated with the translational modes of the solid inner core. The product spectrum in barometric pressure clearly reveals the first 10 solar heating tides in the atmosphere, but otherwise does not show common features with the gravity product spectrum. In particular, the triplet of resonances in the subtidal band of the gravity product spectrum do not show up in the product spectrum of barometric pressure, climinating the atmosphere as their source.     

Episyénitisation dans le Gisement d'Uranium du Bernardan (Marche): Comparaison avec des Gisements Similaires du Nord-Ouest du Massif Central Français

Résumé Le gisement d'uranium du Bernardan exploité dans le granite à deux micas de la Marche Occidentale appartient au groupe des gisements «d'imprégnation». La minéralisation uranifère (pechblende, coffinite, «produits noirs», autunite, ...) est disseminée dans une roche vacuolaire appelée «épisyénite». Cette dernière résulte d'une altération hydrothermale du granite par des solutions chaudes (370–260°C; 2–5,7% poids équiv. NaCl). Le quartz est dissout; les feldspaths (principalement les plagioclases) et les biotites sont partiellement transformés en phengites. Les muscovites et orthoses granitiques se réequilibrent avec perte de sodium. Cette altération est guidée par un réseau de fractures à différentes échelles. Une altération comparable a été observée dans d'autres gisements du Nord Ouest du Massif Central français, comme Margnac et Fanay dans le massif de St Sylvestre et Hyverneresse dans celui du Millevaches. Les transformations minéralogiques, à l'exception de la quantité de phengites secondaires, les changements chimiques (lessivage de silice et métasomatisme potassique), les conditions P-T et le contrôle tectonique sont les mêmes dans tous ces gisements.

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The Bernardan uranium deposit, mined in the Marche Occidentale two-mica granite, is a disseminated type deposit. Similar deposits are known in hercynian belt. Uraniferous mineralizations (pitchblende, coffinite, black minerals, autunite, ...) are disseminated in a vuggy rock called episyenite. It results from an hydrothermal alteration of the granite by hot aqueous solutions (370 to 260°C, 2–5.7 wt% equiv. NaCl). Quartz is dissolved; feldspars (mainly plagioclases) and biotites are partially transformed into phengites. Granitic muscovites and orthoclases are reequilibrated with loss of sodium. This alteration is controlled by fractures at several scales. Such an alteration can be observed in other deposits of the North West part of the French Massif Central, as Margnac and Fanay in the St Sylvestre massif and Hyverneresse in the Millevaches massif. Mineralogical transformations except the content in secondary phengites, chemical changes (SiO₂ decrease and potassic metasomatism), P-T conditions and tectonic control are the same in all these deposits.