Strain localization in sand: an overview of the experimental results obtained in Grenoble using stereophotogrammetry

Experimental results are presented from the extensive program of drained plane strain compression tests on sand carried out in Grenoble over the last two decades. Systematic analysis of photographs of the deforming specimen allowed for measuring deformations and determining strain fields throughout the test, that is: prior to, at, and after the onset of strain localization. The principles, details and accuracy of the procedure are described, as well as its suitability to properly depict the patterns of deformation. Findings concerning the occurrence and progression of strain localization are discussed. The issues of shear band orientation and thickness are addressed, as well as temporary and persistent complex localization patterns, and the volumetric behaviour inside a band after its formation. The influence of such variables as initial state of the sand (effective stress and relative density), specimen size and slenderness, as well as grain size, is discussed. Copyright © 2004 John Wiley & Sons, Ltd     

Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

Iron (III)-silica interactions in aqueous solution: insights from X-ray absorption fine structure spectroscopy

The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions (m_Fe ∼ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH < 2.5), Fe is hexa-coordinated with 6 oxygens of H₂O- and/or OH-groups in the first coordination sphere of the metal, at an Fe-O distance of 2.00 ± 0.01 Å. With increasing pH (2.7 < pH < 13), these groups are rapidly replaced by bridging hydroxyls (-OH-) or oxygens (-O-), and polymerized Fe hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ∼3.47 ± 0.03 Å). The Fe-Fe coordination numbers (N_edge = 1-2; N_corner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3.At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05-m Si solutions (pH ∼ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Fe_edge ∼ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (∼12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe₂Si_1-2 and Fe₃Si_2-3 at pH < 3; (2) structures composed of Fe-Fe dimers and trimers sharing one or two edges of FeO₆-octahedra; and (3) silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ∼ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ∼20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell (R_Fe-O = 1.84 Å). This new finding implies that Fe may partially substitute for Si in the tetrahedral network of the silica polymers in Si-rich solutions.The results of this study demonstrate that aqueous silica can significantly inhibit iron polymerization and solid-phase formation, and thus increase the stability and mobility of Fe(III) in natural waters. The silica “poisoning” of the free corner sites of iron-hydroxide colloids should reduce the adsorption and incorporation of trace elements by these colloids in Si-rich natural waters.     

A Time Monte Carlo method for addressing uncertainty in land-use change models

One of the main objectives of land-use change models is to explore future land-use patterns. Therefore, the issue of addressing uncertainty in land-use forecasting has received an increasing attention in recent years. Many current models consider uncertainty by including a randomness component in their structure. In this paper, we present a novel approach for tuning uncertainty over time, which we refer to as the Time Monte Carlo (TMC) method. The TMC uses a specific range of randomness to allocate new land uses. This range is associated with the transition probabilities from one land use to another. The range of randomness is increased over time so that the degree of uncertainty increases over time. We compare the TMC to the randomness components used in previous models, through a coupled logistic regression-cellular automata model applied for Wallonia (Belgium) as a case study. Our analysis reveals that the TMC produces results comparable with existing methods over the short-term validation period (2000–2010). Furthermore, the TMC can tune uncertainty on longer-term time horizons, which is an essential feature of our method to account for greater uncertainty in the distant future.     

地球化学场精细结构解析方案与应用

为满足勘查地球化学对化探数据处理越来越精细的要求,把人工神经网络和统计分析结合起来形成地球化学场精细结构解析方案。该方案包括对地球化学样品的分类和对各类样品性质的详细研究,目的在于提供便捷的数学和计算机软件工具,以提取化探数据中的深层信息。可以用于:①研究各组样品中元素含量水平和组合特征以解释可能的矿种;②研究元素组合特征与指示元素的关联和区别以揭示可能的成矿作用过程;③研究异常样品的空间组合属性以揭示地球化学场的精细结构;④研究异常样品之间的差异性以缩小找矿靶区;⑤综合分析以确定剥蚀深度和找矿前景。该方案也适用于环境地球化学及矿产资源预测研究。     

Determination of the mean principal directions of stresses for a given fault population

New methods of determination of stress axes, from field measurements of the orientations of faults and slickenslides, are discussed. Results show that the approximation which assumes that relative motion along any fault is controlled by a single common mean stress tensor is valid.     

郯庐断裂带(安徽段)及邻区的动力学分析与区域构造演化

依据区域构造层次划分,采用构造筛分法,层层深入,层层筛分,确定发生于各个不同时代地层/岩层内的断裂活动的同期及叠加的应力场特征。综合所有的同期应力场特征及辅以叠加的应力场特征来验证,从而确定了一个连续的、完整的断裂活动的应力场演化序列;结合区域构造变形特征分析,阐明郯庐断裂带(安徽段)的构造演化。应力场分析显示:晚三叠-早侏罗世应力场为北北西—南南东或近南北向挤压,属古特提斯构造域,断裂发生同造山走滑;早白垩世早期,应力场为北西—南东向挤压,断裂发生左行走滑运动,中国东部处于西环太平洋构造域;早白垩世晚期—古新世(始新世),区域发生北西—南东向伸展作用,断裂处于伸展断陷作用阶段;新生代,受区域上近东西向的挤压作用影响,断裂发生挤压逆冲兼右行走滑作用。     

Gravimetry on the Erimo Seamount, Japan

A gravimetric survey on the sea-bottom was performed on the Erimo Seamount by the French submersible “Nautile”. It took place during the second phase of the Kaiko French-Japanese Program. The reference station was established on the Erimo submarine observatory at a depth of 3942 m and from this point the survey of four stations was carried out. The obtained accuracy of the gravity field measurements was about 0.1 mGal.

A three-dimensional model of the seamount and its surroundings was constrained by the free-air anomaly values from the sea surface and from the sea bottom and by the perfect Seabeam topography survey of the whole area. The model which fitted the observed values best, allowed us to identify a low-density layer of coral limestones and volcaniclastics capping the seamount and to define the geometry of the interface between basalts and coral rocks.