Different mechanisms of the ionospheric influence on GPS occultation signals

A local mechanism for strong ionospheric effects on radio occultation (RO) global positioning satellite system (GPS) signals is described. Peculiar zones centered at the critical points (the tangent points) in the ionosphere, where the gradient of the electron density is perpendicular to the RO ray trajectory, strongly influence the amplitude and phase of RO signals. It follows from the analytical model of local ionospheric effects that the positions of the critical points depend on the RO geometry and the structure of the ionospheric disturbances. Centers of strong ionospheric influence on RO signals can exist, for example, in the sporadic E-layers, which are inclined by 3–6° relative to the local horizontal direction. Also, intense F2 layer irregularities can contribute to the RO signal variations. A classification of the ionospheric influence on the GPS RO signals is introduced using the amplitude data, which indicates different mechanisms (local, diffraction, etc.) for radio waves propagation. The existence of regular mechanisms (e.g., local mechanism) indicates a potential for separating the regular and random parts in the ionospheric influence on the RO signals.     

Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon) : comparison between organic-poor and organic-rich waters

This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment.     

Stratigraphie séquentielle du Carbonifère inférieur du Haut Atlas central et des Jebilet (Maroc): un exemple de bassins à turbidites contrôlées par la tectonique

Marine deposits of Visean age are well exposed in the Marrakesh area. Two third order sequences are identified in the central High Atlas and Jebilet: SA, which is of Middle Visean age (CM); SB of Upper Visean age (Cf6αβγ); and a complex with olistoliths of Upper Visean-Lower Namurian age (Cf6δ-Cf7). The SA and SIB sequences consist of a relative low-lying system tract with turbidites, a retrograde transgressive system tract and a prograde high-lying system tract. The relative low level comprises a turbiditic fan fed by tectonic uplift, which does not strictly coincide with eustatic processes. The transgressive system tract retrogrades firstly on the slope during tectonic reactivation with slumps, channels and silty levees, secondly on the shelf edge with a mixture of turbiditic and storm deposits and finally on the shelf with storm deposits and reef building. The high level system tract progrades on the shelf by a delta fan. This model is similar to sequences described in Spain and Italy by Mutti (1992), where tectonism is dominant.Nevertheless, eustasy, as described by Vail et al. (1977) played a part, since the same sequences are found in the chart of Ross and Ross (1987): S1, which of Middle Visean age (Cf5) and S2 which is of Upper Visean age (Cf6αβγ). Only the comparison between regional sequences described in Morocco and the sequences of the European platform allow tectonics and eustasy to be taken into consideration.     

面向建设实践,促进地理学的发展

以经济建设为中心是我国长期的、基本的国策，可持续发展纲领从总体战略上、社会发展上、经济发展上、生态发展上为经济建设提供了框架。在此框架下，地理学可以在人地关系、区域可持续发展、全球环境变化及地理信息技术等领域发挥学科优势，同时也面临着巩固理论基础、扩展应用领域方面的机遇与挑战。     

An Improved Experimental Calibration of the Olivine-Spinel Geothermometer

The calibration of the olivine-spinel geothermometer by Fabries(1979) is commonly adopted by a number of petrologists.But the temperatures calculated in this way for ultramafic focks are significantly lower than those obtained by the pyroxene geothermometers.These O1-Sp temperatures are also lower than those measured experi-mentally in the natural system (four-phase lherzolite).Different rates of cation diffusion cannot fully account for these differences.The temperature deviation is actually related to the inconsistencies between natural and experimental data which support the calibration .A re-evaluation of the calibration is proposed on the basis of a set of new experimental data.     

Gabbro and related rock emplacement beneath rifting continental crust: UPb geochronological and geochemical constraints for the Galicia passive margin (Spain)

The thinned continental crust of the west Galicia margin is bound by a belt of serpentinized peridotites (‘peridotite ridge’) lying about 300 km off the coast in the North Atlantic ocean. From this ridge, a gabbro and a chlorite rock were studied in an attempt to substantiate rift-related subcontinental magmatism, occurring prior to sea-floor spreading. U-Pb dating of 13 different zircon fractions yields a precise age of 122.1 ± 0.3 Ma (2σ) for the emplacement of the chlorite rock protolith, from which more than 50% of Si and alkali-calc-alkali elements were lost during greenschist facies tectonometamorphism. Sr and Nd isotope signatures suggest that the gabbro and chlorite rock protoliths were derived from mantle sources that were moderately depleted in LILE, relative to a chondritic reservoir. No evidence for the presence of continental material in the magma source regions can be observed. From the new zircon age of 122.1 ± 0.3 Ma, and earlier determined³⁹Ar⁴⁰Ar age of 122.0 ± 0.6 Ma for amphibole from the same locality, it can be documented that magma formation, solidification and unroofing of the mantle rocks occurred during a short period of time of about 3.4 Ma, which means that the peridotite ridge detached from the continent and rose to the surface immediately after, or even coevally with mantle melting.     

The search for weak harmonic signals in a spectrum with application to gravity data

When considering the search for discovery or amplitude estimation of a spectral line with a probabilistic approach, great attention must be paid to the meaning of each step. We give the probability law for the amplitude of a spectral peak in the presence of random noise appearing in a periodogram and discuss the effective probability of the existence of the corresponding wave. We find that the estimated amplitude of a spectral peak is biased and should be corrected when the signal-to-noise ratio is small. As a first application to gravity data, it results in a re-estimation of the gravimetric amplitude factors (delta factors) provided by least-squares tidal analysis. We also estimate the probability of observing a spectral line above a given level in the spectrum of a purely random noise. This allows us to compute for given spectrum the number of peaks expected to overcross the classical levels used in statistical analysis (like nσ, where σ is the standard deviation of the temporal noise distribution and n is an integer with typical values equal to 2 or 3). A specific application to real data is investigating the gravity spectrum derived from a 5 year record of the French superconducting gravimeter and we show that the predicted statistics are indeed in agreement with the observations. We also show the statistical consequence of using longer observing periods to obtain the spectral estimations. The problem of detecting translational motion of the Earth's solid inner core (Slichter modes) in a gravity spectrum is analyzed and the probabilities of having a triplet of random peaks thresholding specific levels in a given frequency window are computed. We show that, in the case of a typical gravity spectrum (1 year of hourly data and a frequency window of 0.03 cycle h⁻¹), the probability of having a random set of three peaks exceeding a level of 3 σ, is very high. This emphasizes the need for a very careful analysis of spectral lines before inferring the existence of a true physical signal.     

TL stratigraphy of pre-Weichselian loess from NW Europe using feldspar coarse grains

A new feldspar relative TL dating method is proposed that enables dating of pre-Weichselian loess older than 130 ka, by applying the additive γ dose technique and the Mejdahl's exponential extrapolation to alkali feldspar coarse grains. The method is applied to loess deposits from various reference loessic sections of NW Europe. Our relative TL age estimates are consistent with the information provided by the regional stratigraphy; furthermore, they lead to a clear separation of the pre-Weichselian periods of loess deposition in the time period 130 ka–300 ka.     

Transfer and deposition of gold in the Congo watershed

Gold has been measured in water and suspended particulate matter samples coming from the Oubangui-Congo system. Gold anomalies up to 800 pico M/l were measured at two different locations. These are interpreted as the result of gold transport by dissolved organic complexes. Everywhere else the gold content is in the range of 10⁻¹¹M/l and gold is present as an aurous hydroxichloride complex.The knowledge of both discharge rates and gold content allows a quantification of the gold input into the Atlantic ocean. Respective values for dissolved and particulate gold input are equal to 2.86 t/a and 2.95 t/a. Both chemical denudation and physical weathering rates were computed from this new set of data.