Premelting and calcium mobility in gehlenite (Ca2Al2SiO7) and pseudowollastonite (CaSiO3)

 Premelting effects in gehlenite (Ca₂Al₂SiO₇) have been studied by Raman spectroscopy and calorimetry, and in gehlenite and pseudowollastonite (CaSiO₃) by electrical conductivity. The enthalpy of premelting of gehlenite is 17.3 kJ mol⁻¹ and represents 9% of the reported enthalpy of fusion, which is in the range of the reported fraction of other minerals. The Raman and electrical conductivity experiments at high temperatures, for gehlenite and pseudowollastonite, show that the premelting effects of both compositions are associated with enhanced dynamics of calcium atoms near the melting point. This conclusion agrees with the results obtained for other minerals like diopside, but contrasts with those found for sodium metasilicate in which the weaker bonding of sodium allows the silicate framework to distort near the melting temperature and deform in such a way to prefigure the silicate entities present in the melt. Received: 30 April 2002 / Accepted: 7 August 2002 Acknowledgements We thank Y. Linard for help with DSC measurements and two anonymous reviewers for their constructive comments. This work has been partly supported by the EU Marie-Curie fellowship contract no. HPMF-CT-1999-00329, the CNRS-Carnegie Institution of Washington program PICS no.192, and the NSF grants EAR-9614432 and EAR-9901886 to B.O.M.     

Variation and pattern in the responses of mammal faunas to Late Pleistocene climatic change in southeastern South Australia

We examined mammal occurrence and variability through the Late Pleistocene vertebrate fossil deposit of Grant Hall in Victoria Fossil Cave, Naracoorte, South Australia. To determine long‐term patterns of change, we compared the composition and relative abundance trends of the assemblage with a nearby Middle Pleistocene deposit in Cathedral Cave. Total species richness did not change through the Grant Hall sequence, dated from 93 ± 8 to 70 ± 5 ka. However, species relative abundances varied between ecologically divergent species, and in some cases between species that demonstrate similar environmental preferences. For some species this variation is comparable to that recorded in Cathedral Cave. Of those showing similar trends between the two deposits, the forest inhabitant, Pseudomys fumeus, recorded an 8.6% decline through Grant Hall, coincident with a 9.7% increase in the dry heath/mallee dweller Pseudomys apodemoides. These patterns indicate that climatic transition from relatively warm, moist to cooler, drier conditions impacted some species in similar ways through climatic cycles of the past. However, the majority of the fauna demonstrated complex responses that are individual and variable through time. Statistical tests of species trends from the Grant Hall assemblage caution that large fossil samples are required to validate patterns observed. Copyright © 2012 John Wiley & Sons, Ltd.     

Experimental Researches on Hydro-Mechanical Properties of Altered Rock Under Confining Pressures

Altered rock, as the abutment materials of Xiaowan Hydropower Station in China, is a kind of geological defective rock mass. It is loosely structured and its strength is low, with some development of pores and cavities. Research on the hydro-mechanical coupling of the altered rock are of important significance to hydropower projects. In this study, the advanced fully automatic triaxial fluid flow-rheological test servo system is employed to study the hydro-mechanical coupling characteristics of the altered rock, and the water pressures and confining pressures in the laboratory tests are set to simulate the conditions of excavation and impoundment of Xiaowan Hydropower Station. Based on the test results, the stress–strain laws of the rock specimens under the effect of complete hydro-mechanical coupling, as well as the lateral strain and volumetric strain characteristics, are studied. The fluid flow laws of the rock specimens and the effects of the confining pressures on the fluid flow are analyzed. The fluid flow failure characteristic under the effect of the complete hydro-mechanical coupling is discussed. The research achievements show that with the change of the stress states, the permeability of the rock also changes, and the permeability evolution shows the phase characteristic during the process of stress and strain. The impacts of the confining pressures on the strength and deformation and permeability of the altered rock are obvious. The failure behaviours of the rock specimens under the effect of coupling relates to the confining pressures, including two kinds of splitting failure and shear failure. The fluid flow failure characteristic of the rock specimens depend upon the initiation, growth and coalesce of micro-cracks, heterogeneity, confining pressures and properties of the rock.     

Isotope variations in a Sierra Nevada snowpack and their relation to meltwater

Isotopic variations in melting snow are poorly understood. We made weekly measurements at the Central Sierra Snow Laboratory, California, of snow temperature, density, water equivalent and liquid water volume to examine how physical changes within the snowpack govern meltwater δ¹⁸O. Snowpack samples were extracted at 0.1 m intervals from ground level to the top of the snowpack profile between December 1991 and April 1992. Approximately 800 mm of precipitation fell during the study period with δ¹⁸O values between −21.35 and −4.25‰. Corresponding snowpack δ¹⁸O ranged from −22.25 to −6.25‰. The coefficient of variation of δ¹⁸O in snowpack levels decreased from −0.37 to −0.07 from winter to spring, indicating isotopic snowpack homogenization. Meltwater δ¹⁸O ranged from −15.30 to −8.05‰, with variations of up to 2.95‰ observed within a single snowmelt episode, highlighting the need for frequent sampling. Early snowmelt originated in the lower snowpack with higher δ¹⁸O through ground heat flux and rainfall. After the snowpack became isothermal, infiltrating snowmelt displaced the higher δ¹⁸O liquid in the lower snowpack through a piston flow process. Fractionation analysis using a two-component mixing model on the isothermal snowpack indicated that δ¹⁸O in the initial and final half of major snowmelt was 1.30‰ lower and 1.45‰ higher, respectively, than the value from simple mixing. Mean snowpack δ¹⁸O on individual profiling days showed a steady increase from −15.15 to −12.05‰ due to removal of lower δ¹⁸O snowmelt and addition of higher δ¹⁸O rainfall. Results suggest that direct sampling of snowmelt and snow cores should be undertaken to quantify tracer input compositions adequately. The snowmelt sequence also suggests that regimes of early lower δ¹⁸O and later higher δ¹⁸O melt may be modeled and used in catchment tracing studies.     

Late Devensian environments in the Vale of Mowbray, North Yorkshire, UK: evidence from palynology

Two radiocarbon-dated Lateglacial pollen diagrams from the Vale of Mowbray (northern Vale of York) are presented from sites in the lowlands between the washlands courses of the rivers Swale and Ure in North Yorkshire, an area with little previous palynological research despite its proximity to the Devensian glacial advance limits in eastern England. The profiles, from Snape Mires and Nosterfield, include the Loch Lomond Stadial (Younger Dryas) and the Holocene transition, while that from Snape Mires also includes the period from the early part of the Lateglacial Interstadial. This profile differs from most published Interstadial diagrams from the Yorkshire region in having a long-delayed expansion of tree and shrub taxa. Juniperus (juniper) remains important after vegetation development takes place and the pollen record includes evidence of two cold climate oscillations before the maximum development of Betula (birch) woodland near the end of the Lateglacial Interstadial. At both profiles Artemisia (mugwort) frequencies are lower during the Loch Lomond Stadial than at many regional sites, probably due to edaphic factors in these lowland locations. The two sites provide valuable environmental data that enable comparison between the more wooded Lateglacial vegetation to the south in the Vale of York and Humberside and the more open contemporaneous vegetation to the north in the Durham and Northumberland lowlands.     

On Brown's conjecture

We examine the conjecture made by Brown (1911) that in the restricted three body problem, the long period family of periodic orbits aroundL ₄, ends on a homoclinic orbit toL ₃. By numerical integration we establish that for the mass ratio Sun-Jupiter such a homoclinic orbit toL ₃ does not exist but that there exists a family of homoclinic orbits to periodic orbits aroundL ₃.     

Report of the International Astronomical Union Division I Working Group on Precession and the Ecliptic

The IAU Working Group on Precession and the Equinox looked at several solutions for replacing the precession part of the IAU 2000A precession–nutation model, which is not consistent with dynamical theory. These comparisons show that the (Capitaine et al., Astron. Astrophys., 412, 2003a) precession theory, P03, is both consistent with dynamical theory and the solution most compatible with the IAU 2000A nutation model. Thus, the working group recommends the adoption of the P03 precession theory for use with the IAU 2000A nutation. The two greatest sources of uncertainty in the precession theory are the rate of change of the Earth’s dynamical flattening, ΔJ₂, and the precession rates (i.e. the constants of integration used in deriving the precession). The combined uncertainties limit the accuracy in the precession theory to approximately 2 mas cent⁻². Given that there are difficulties with the traditional angles used to parameterize the precession, z_A, ζ_A, and θ_A, the working group has decided that the choice of parameters should be left to the user. We provide a consistent set of parameters that may be used with either the traditional rotation matrix, or those rotation matrices described in (Capitaine et al., Astron. Astrophys., 412, 2003a) and (Fukushima Astron. J., 126, 2003). We recommend that the ecliptic pole be explicitly defined by the mean orbital angular momentum vector of the Earth–Moon barycenter in the Barycentric Celestial Reference System (BCRS), and explicitly state that this definition is being used to avoid confusion with previous definitions of the ecliptic. Finally, we recommend that the terms precession of the equator and precession of the ecliptic replace the terms lunisolar precession and planetary precession, respectively.     

Regular and chaotic orbits in a self-consistent triaxial stellar system with slow figure rotation

We created a self-consistent triaxial stellar system through the cold disipationless collapse of 100,000 particles whose evolution was followed with a multipolar code. The resulting system rotates slowly even though its total angular momentum is zero, i.e., it offers an example of figure rotation. The potential of the system was subsequently approximated with interpolating formulae yielding a smooth potential stationary in the rotating frame. The Lyapunov exponents could then be computed for a randomly selected sample of 3,472 of the bodies that make up the system, allowing the recognition of regular and partially and fully chaotic orbits. The regular orbits were Fourier analyzed and classified using their locations on the frequency map. A comparison with a similar non-rotating model showed that the fraction of chaotic orbits is slightly but significantly enhanced in the rotating model; alternatively, there are no significant differences between the corresponding fractions neither of partially and fully chaotic orbits nor of long axis tubes, short axis tubes, boxes and boxlets among the regular orbits. This is a reasonable result because the rotation causes a breaking of the symmetry that may increase chaotic effects, but the rotation velocity is probably too small to produce any other significant differences. The increase in the fraction of chaotic orbits in the rotating system seems to be due mainly to the effect of the Coriolis force, rather than the centrifugal force, in good agreement with the results of other investigations.     

Statistical properties of optical refractive index fluctuations in the marine boundary layer

The optical refractive index fluctuation has been determined from measurements of turbulent temperature and humidity fluctuations in the atmospheric surface layer over the ocean. Probability density, spectral density and even- and odd-order structure functions of the refractive index fluctuation are presented. The spectral density exhibits a significant -5/3 inertial subrange as a result of the existence of a -5/3 subrange in the spectra of temperature and humidity fluctuations and in the temperature-humidity co-spectrum. The behaviour in the inertial subrange of fourth- and sixth-order structure functions of the refractive index is in reasonable agreement with that predicted by the analysis of Antonia and Van Atta (1975, 1978). The third-order structure functions of the refractive index exhibit an approximately linear dependence on separation in the inertial subrange, in agreement with a ramp model for the large coherent structure of the motion.