Relevance of Pentane- and Hexane-Utilizing Bacterial Indicators for Finding Hydrocarbon Microseepage: A Study from Jamnagar Sub-basin, Saurashtra, Gujarat, India

Mesozoic sediments are source rocks for nearly half the world’s hydrocarbon reserves. Hence, there is great interest in the oil industry to know the trap and sub-trappean sediment thickness and their extent in the trap covered regions of Jamnagar study area. The microbial prospecting method is applied in the Jamnagar sub-basin, Gujarat for evaluating the prospects for hydrocarbon exploration by investigating the anomalous abundance of n-pentane- and n-hexane-oxidizing bacteria of this area. A total of 150 near-surface soil samples were collected in Jamnagar sub-basin, Gujarat for the evaluation of hydrocarbon resource potential of the basin. In this study, bacterial counts for n-pentane-utilizing bacteria range between 1.09 × 10² and 9.89 × 10⁵ cfu/g and n-hexane-utilizing bacteria range between 1.09 × 10² and 9.29 × 10⁵ cfu/g. The adsorbed hydrocarbon gases consisting of ethane plus hydrocarbons (ΣC₂₊) of 1–977 ppb and n-pentane (nC₅) of 1–23 ppb. The integrated geomicrobial and adsorbed soil gas studies showed the anomalous hydrocarbon zones nearby Khandera, Haripur, and Laloi areas which could probably aid to assess the true potential of the basin. Integrated geophysical studies have shown that Jamnagar sub-basin of Saurashtra has significant sediment thickness below the Deccan Traps and can be considered for future hydrocarbon exploration.     

ON THE THEORY OF HITCH-HIKING AS A SPATIAL STOCHASTIC PROCESS

Hitch-hiking has been ignored by traditional geography. In this article it is shown that ideas and techniques from the new geography yield substantial insights into its character as a spatial process.     

FluBiDi – a model to estimate flood based on runoff: validation using extreme and natural basin conditions

FluBiDi is a two-dimensional model created to simulate real events that can take days and months, as well as short events (minutes or hours) and inclusive laboratory tests. To verify the robustness of FluBiDi, it was tested using a previous study with both designed and real digital elevation models. The results highlight good agreement between the models (i.e. Mike Flood, SOBEK, ISIS 2D, and others) tested and FluBiDi (around 90% for a specific instant and 95% for the complete time simulation). In the simulated hydrographs, the discharge peak value, time to peak, and water level results were accurate, reproducing them with an error of less than 5%. The velocity differences observed in a couple of tests in FluBiDi were associated with very short periods of time (seconds). However, FluBiDi is highly accurate for simulating floods under real topographical conditions with differences of around 2 cm when water depth is around 150 cm. The average water depth and velocities are precise, and the model describes with high accuracy the pattern and extent of floods. FluBiDi has the capability to be adjusted to different types of events and only requires limited input data.     

Sea-level rise impacts on longitudinal salinity for a low-gradient estuarine system

Climatic Change - Salinity response to sea-level rise is evaluated for a low-gradient, tidally active estuary, the lower St. Johns River, Florida. A high-resolution numerical model is forced by...     

Alteration processes in the CV chondrite parent body based on analysis of NWA 2086 meteorite

Analysis of the NWA 2086 CV3 chondrite showed a matrix/chondrule ratio of 52%, similar to Bali, Mokoia, and Grosanaja. Nearly twice as many chondrule fragments as intact ones demonstrate that an early fragmentation phase occurred prior to final accretion. After this event, no substantial mechanical change or redeposition is evident. Rims with double‐layered structures were identified around some chondrules, which, in at least one case, is attributed to an accretionary origin. The rim's outer parts with a diffuse appearance were formed by in situ chemical alteration. During this later process, Mg content decreased, Fe content increased, and olivine composition was homogenized, producing a rim composition close to that of the matrix. This alteration occasionally happened along fractures and at confined locations, and was probably produced by fluid interactions. Iron oxides are the best candidate for a small grain‐sized alteration product; however, technical limitations in the available equipment did not allow exact phase identification. These results suggest that NWA 2086 came from a location (possible more deeply buried) in the CV parent body than Mokoia or Bali, and suffered less impact effects—although there is no evidence of sustained thermal alteration. This meteorite may represent a sample of the CV parent asteroid interior and provide a useful basis for comparison with other CV meteorites in the future.     

The impact of the Laacher See Volcano (11 000 yr B.P.) on terrestrial vegetation and diatoms

Late-glacial lake sediments containing the Laacher See Tephra (LST, 11 000 yr B.P.) have been analyzed for their pollen and diatom content at three sites at varying distances from the volcano and on different bedrock geologies. The aim was to test the null hypothesis that this major volcanic eruption had no effect on terrestrial pollen or aquatic diatom assemblages. The pollen spectra at all sites show a short-lived increase in grass pollen following the LST. Partial redundancy analysis and associated Monte Carlo permutation tests suggest, however, that the LST had no statistically significant effect at two sites but it had a statistically significant impact on the pollen assemblages at the site nearest (60 km) to the volcano.The diatom assemblages at the three sites changed individualistically after the LST deposition, with increases inAchnanthes minutissima at one site, an expansion ofAulacoseira species at another, and an increase ofAsterionella formosa andFragilaria brevistriata at the third site. Partial redundancy analysis and associated permutation tests suggest a statistically significant change in diatoms in relation to the LST and associated changes in sediment lithology at the one site situated on acidic bedrock. No significant impacts were found at the sites on volcanic or calcareous rocks. Due to the interaction between tephra and sediment lithology, it is not possible to conclude if the statistically significant diatom changes were a direct result of the LST deposition or an indirect result of lithological changes following LST deposition.This is the first paper in a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Paeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.     

The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.     

The mineralogical composition of precursor sediments of calcareous rhythmites: a new approach

Previous studies in Silurian carbonates from Gotland (Sweden) have led to a model for the development of limestone-marl alternations. This model postulates that early diagenesis of precursor sediments without strong primary differences can result in a differentiation by selective dissolution of aragonite in marl beds and reprecipitation of calcite cement in limestone beds. This model is described as a set of mathematical equations that quantify the diagenetic processes (aragonite dissolution and calcite reprecipitation) that occur during the formation of limestone-marl interbeds from a hypothetical homogeneous precursor sediment. The calculations demonstrate that resulting hypothetical limestone-marl alternations show characteristic mathematical relationships between the ratios of the bed thicknesses of limestones and marls on one side, and the carbonate contents, on the other. By reversing this model, the original mineralogical composition of the precursor sediment of real-world rhythmic successions can be determined. In this study, alternations from the Silurian of Gotland, the Cambrian, Devonian, and Mississippian of North America, the Jurassic of France and Germany, and the Cretaceous of France are shown to exhibit mathematical relationships similar to those calculated for hypothetical precursor sediments without primary differences. Therefore, the mineralogical composition of their precursor sediments can be estimated. In contrast, the clear mismatch shown by the Lower Jurassic Belemnite Marls from Dorset indicates that these rhythms did not suffer an early diagenetic overprint. Our model helps to differentiate between rhythmites with strong depositional variations and those without; however, it cannot indicate whether a given alternation is the product of rhythmic diagenesis of a homogeneous precursor sediment or the result of diagenetic enhancement of subtle underlying sedimentary rhythms. For horizontally correlated patterns, such as laterally extensive beds and layers of nodules, an a priori unknown external signal has to be assumed.