The effects of a copper-based antifouling paint on mortality and enzymatic activity of a non-target marine organism

Antifouling paints are used on a wide range of underwater structures in order to protect them from the development of fouling organisms. The leaching of the toxic substances from the matrix of the paint causes toxic effects not only to the fouling organisms but also on other "non-target" biota. The present study addresses the impact of the antifouling paint Flexgard VI-II on brine shrimp nauplii selected as convenient test organisms. The surface to volume (S/V) concept developed by Persoone and Castritsi-Catharios (1989) was used to determine S/V-LC50s for the test biota exposed to PVC test panels of 400-1000 mm2 surface coated with the antifouling paint in test vessels containing 20 ml seawater. Total ATPase and Mg2+-ATPase were also analyzed for coated surface areas inducing less than 50% mortality in the brine shrimp nauplii. The calculated S/V-LC50 (24 h) was 24.6 mm2/ml, which shows the high toxic character of the antifouling paint. Decreased enzymatic activities were noted in the brine shrimp nauplii exposed to test panels of 50 and 100 mm2 in 20 ml seawater. The present study indicates that the "surface to volume" concept is an interesting methodology that can be applied with both lethal and sublethal effect criteria for the determination of toxic stress from leaches of painted surfaces.     

A note on estimating the vertical eddy diffusion coefficient from LANDSAT imagery

Boundary-Layer Meteorology - The vertical eddy diffusion coefficient (K z) for five smoke plumes entrapped in a stable marine layer is estimated from the published LANDSAT imagery data sets of...     

Distribution of Mantle Up-welling Determined from Plate Motions: A Case for Large-scale Bénard Convection

—?The number and geometric distribution of putative mantle up-welling centers and the associated convection cell boundaries are determined from the lithospheric plate motions as given by the 14 Euler poles of the observational NUVEL model. For an assumed distribution of up-welling centers (called “cell-cores”) the corresponding cell boundaries are constructed by a Voronoi division of the spherical surface; the resulting polygons are called “Bénard cells.” By assuming the flow-kinematics within a cell, the viscous coupling between the flow and the plates is estimated, and the Euler poles for the plates are computed under the assumption of zero-net-torque. The positions of the cell-cores are optimized for the HS2-NUVEL1 Euler poles by a method of successive approximation (“subplex”); convergence to one of many local minima occurred typically after ～20,000 iterations. Cell-cores associated with the fourteen HS2-NUVEL1 Euler poles converge to a relatively small number of locations (8 to 10, depending on interpretation), irrespective of the number of convection cells submitted for optimized distribution (from 6 to 50). These locations are correlated with low seismic propagation velocities in tomography, uniformly occur within hotspot provinces, and may specifically be associated with the Hawaiian, Iceland, Reunion/Kerguelen (Indian Ocean), Easter Island, Melanesia/Society Islands (South Pacific), Azores/Cape Verde/Canary Islands, Tristan da Cunha (South Atlantic), Balleny Islands, and possibly Yellowstone hotspots. It is shown that arbitrary Euler poles cannot occur in association with mantle Bénard convection, irrespective of the number and the distribution of convection cells. Nevertheless, eight of the observational Euler poles – including the five that are accurately determined in HS2-NUVEL1 (Australia, Cocos, Juan de Fuca, Pacific, and Philippine) – are “Bénard-valid” (i.e., can be explained by our Bénard model). Five of the remaining six observational poles must be relocated within their error-ellipses to become Bénard-valid; the Eurasia pole alone appears to be in error by ～115°, and may actually lie near 40°N, 154°E. The collective results strongly suggest Bénard-like mantle convection cells, and that basal shear tractions are the primary factor in determining the directions of the plate motions as given by the Euler poles. The magnitudes of the computed Euler vectors show, however, that basal shear cannot be the exclusive driving force of plate tectonics, and suggest force contributions (of comparable magnitude for perhaps half of the plates) from the lithosphere itself, specifically subducting slab-pull and (continental) collision drag, which are provisionally evaluated. The relationship of the putative mantle Bénard polygons to dynamic chaos and turbulent flow is discussed.     

An integrated approach to investigate saline water intrusion and to identify the salinity sources in the Central Godavari delta, Andhra Pradesh, India

The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO ₄ ^?2 /Cl^?and Na⁺²/Cl^?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.     

Evaluation of stratospheric ozone,temperature, and aerosol profiles from the LOANA lidar in Antarctica

We present an evaluation of observations from the Lidar Ozone and Aerosol for NDACC in Antarctica (LOANA) at the Dumont d’Urville station, Antarctica. This instrument is part of the Network for the Detection of Atmospheric Composition Change (NDACC), and ensures continuity with lidar measurements made since 1989 with the previous instrument at this site. This study is based on the dataset from 2008 to 2009, and comparisons are made with observations from balloon soundings, and from three satellite experiments: Aura/MLS, TIMED/SABER, and CALIOP/CALIPSO. The lidar ozone data are in very good agreement with the balloon sounding data (ECC sensor), revealing a bias of less than 3% between 17 and 34 km. For temperature, the lidar shows a low bias of ?3 K at 20 km when compared with Aura/MLS. Between 30 and 50 km, the bias is less than 2 K. We also present our initial results showing diurnal variations in temperature. The amplitude of these diurnal cycles is on the order of 1 K and is unlikely to account for the temperature biases between LOANA and the reference instruments. Comparisons of total attenuated backscatter reveal good qualitative agreement between LOANA and CALIOP, with differences of less than 30% in the derived optical depth.