Microlites and "nanolites" in rhyolitic glass: microstructural and chemical characterization

 We used transmission electron microscopy (TEM) and scanning electron microscopy (SEM) to study magmatic crystals in the Ben Lomond rhyolite lava dome, Taupo Volcanic Center, New Zealand. Using TEM and SEM to investigate the size distributions of these crystals, we identified three size populations: microphenocrysts (>1.2 μm wide), microlites (>0.6 μm wide), and smaller crystals (<0.6 μm wide) which we term "nanolites". The predominant mineral phases of the microlites and nanolites are augites, pigeonites, and hypersthenes. The compositions and microstructures within these pyroxenes indicate disequilibrium crystallization at approximately 850–900  °C and undercoolings as high as 300  °C from equilibrium crystallization temperatures. Complex microstructures resulting from subsolidus reactions in augite and pigeonite are consistent with moderate cooling rates within the upper obsidian layer of the Ben Lomond rhyolite dome. This study demonstrates the existence of sub-micron magmatic crystals in a rhyolite and illustrates the potential of TEM to provide unique information about the crystallization and cooling histories of glassy volcanic rocks. Received: May 8, 1995 / Accepted: November 27, 1995     

Detection of a new interstellar molecular ion, H2COH+ (protonated formaldehyde)

A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+.     

Octahedral-site Fe2+ quadrupole splitting distributions from Mössbauer spectroscopy along the (OH, F)-annite join

We have performed a detailed Mössbauer study of synthetic annites on the (OH, F)-join. Recently developed data treatment and spectral analysis methods were used to extract true intrinsic Fe²⁺ quadrupole splitting distributions (QSDs) that represent the most information that can be resolved from the spectra. The overall room temperature (RT) QSDs can be consistently interpreted in terms of four QSD contributions (or populations) centered at: QS_HH2.55 mm/s for Fe²⁺O₄(OH)₂ octahedra (cis and trans not resolved), QS_HF 2.35 mm/s for Fe²⁺O₄(OH)F octahedra (cis and trans not resolved), QS_cFF2.15 mm/s for cis-Fe²⁺O₄F₂ octahedra, and QS_tFF 1.5 mm/s for trans-Fe²⁺O₄F₂ octahedra. Each such contribution has a width ( 0.2 mm/s) caused by distortions of the octahedra. Minor contributions due to Fe²⁺O₅(OH) and Fe²⁺O₅F octahedra probably also contribute to the overall Fe²⁺ QSDs. The ferric iron spectral components were also characterized. Here, two distinct types of octahedral Fe³⁺ contributions are seen and interpreted as being due mainly to Fe³⁺O₅OH and Fe³⁺O₅F octahedra, respectively. Tetrahedral Fe³⁺ is seen only in the OH-annite end-member and the total Fe³⁺ content drops significantly on addition of F. On leave from: Department of Materials Physics, University of Science and Technology Beijing, 100083 Beijing, China     

Dislocations in CaTiO3 perovskite deformed at high-temperature: a transmission electron microscopy study

Dislocation configurations in natural single crystals of CaTiO₃ perovskite deformed in high-temperature creep were examined and characterized by transmission electron microscopy. Screw dislocations with Burgers vector [100]_pc and [011]_pc, dissociated on the $(01\bar 1)_{{\text{pc}}} $ plane, form rectangular networks with extended four-fold nodes in the shape of octagons, a configuration never observed in any of the previously investigated perovskites, except CaGeO₃. Screw dislocations with Burgers vector [101]_pc and $(\bar 101)_{{\text{pc}}} $ , on the (010)_pc plane, react to form a twist wall; the dislocations with Burgers vector [002] produced by the reaction decompose into two perfect dislocations [001]_pc. This results in a new configuration, never observed before, with three-fold nodes at the corners of rectangles. Both the octagonal extended nodes and the junctions decomposed into perfect dislocations are seen in samples deformed indifferently by slip on {100}_pc or {110}_pc planes, but they seem to appear only above 1520 K, in the cubic phase.     

Extreme value analysis of diamond-size distributions

Extreme value analysis provides a semiparametric method for analyzing the extreme long tails of skew distributions which may be observed when handling mining data. The estimation of important tail characteristics, such as the extreme value index, allows for a discrimination between competing distribution models. It measures the thickness of such long tailed distributions, if only a limited sample is available. This paper stresses the practical implementation of extreme value theory, which is used to discriminate a lognormal from a mixed lognormal distribution in a case study of size distributions for alluvial diamonds.     

Springs of Great Britain

Predictably, in a country such as Britain, with its preponderance of consolidated, sedimentary, mainly fissure-flow aquifers, there is a very large number of springs, many of which are, or have been, used for public supply. Migratory springs are a feature of the British (Ur. Cretaceous) Chalk, the most important British aquifer. The Chalk's low specific yield and high capillary moisture retention together give rise to very considerable fluctuations (more than 33 m in some areas) of the unconfined water table. Along the gentle dip slopes of the Chalk (North and South Downs of southern and southeastern England) springs may migrate laterally for several miles, giving rise to seasonal streams locally known as bournes or lavants. However, springs such as at Duncton, West Sussex, at the base of the much steeper scarp slopes of the Chalk, form point sources, the flows from which tend to be relatively steady; such springs commonly supply and are the original reason for the existence of many of the small towns and villages which nestle along the bases of the chalk scarps of Sussex and Kent.Where the Chalk forms coastal cliffs, a number of springs break out at the base of the cliff between high and low tide levels; there are major chalk coastal springs, for instance, at St. Margaret's Bay (Kent) and at Arish Mells, east of Lulworth Cove, Dorset. Such springs are not used for direct supply (their salinity is usually too high) but are indicators of the presence of local reserves of groundwater for possible future development.     

Integrated chronostratigraphy of Proterozoic-Cambrian boundary beds in the western Anabar region, northern Siberia

Carbonate-rich sedimentary rocks of the western Anabar region, northern Siberia, preserve an exceptional record of evolutionary and biogeochemical events near the Proterozoic/Cambrian boundary. Sedimentologically, the boundary succession can be divided into three sequences representing successive episodes of late transgressive to early highstand deposition; four parasequences are recognized in the sequence corresponding lithostratigraphically to the Manykal Formation. Small shelly fossils are abundant and include many taxa that also occur in standard sections of southeastern Siberia. Despite this coincidence of faunal elements, biostratigraphic correlations between the two regions have been controversial because numerous species that first appear at or immediately above the basal Tommotian boundary in southeastern sections have first appearances scattered through more than thirty metres of section in the western Anabar. Carbon- and Sr-isotopic data on petrographically and geochemically screened samples collected at one- to two-metre intervals in a section along the Kotuikan River, favour correlation of the Staraya Reckha Formation and most of the overlying Manykai Formation with sub-Tommotian carbonates in southeastern Siberia. In contrast, isotopic data suggest that the uppermost Manykai Formation and the basal 26 m of the unconformably overlying Medvezhya Formation may have no equivalent in the southeast; they appear to provide a sedimentary and palaeontological record of an evolutionarily significant time interval represented in southeastern Siberia only by the sub-Tommotian unconformity. Correlations with radiometrically dated horizons in the Olenek and Kharaulakh regions of northern Siberia suggest that this interval lasted approximately three to six million years, during which essentially all 'basal Tommotian' small shelly fossils evolved.     

Objective measures of the information density of satellite data

Summary We propose and objective method whereby the density of Shannon's information associated with the retrieval of a profile of atmospheric variables from satellite-derived infrared radiance measurements may be estimated. The technique is a natural extension of one we previously proposed to estimate the effective data density in a profile. We test the method in a comparison of simulated satellite instruments to show that the method does indeed provide an objective summary of the spatial distribution of each instrument's information content. We propose that further extensions of the method be developed to include other more traditional data sources in a fully three-dimensional scheme. We also note that analogous and compatible methods may be used to diagnose the information content of meteorological analysis and forecast fields relative to the information contained in the covariance, at the appropriate season, of the corresponding climate fields.With 8 Figures     

Overbreak and underbreak in underground openings Part 2: causes and implications

Summary The newly developed light sectioning method has been used to investigate some of the causes and costs of overbreak and underbreak. Investigations at the Aquamilpa Hydroelectric Project in Mexico have shown decreased overbreak and increased underbreak as a result of increased rock quality and decreased explosive energy. A new measure of explosive energy, the perimeter powder factor (PPF), has been defined and shown to be useful in the context of tunnel-wall rock damage. Tentative results indicate that explosive energy (PPF) may be a more important factor in producing underbreak, whereas rock quality may be a greater factor in producing overbreak. A site-specific equation is given for predicting overbreak or underbreak as a function of rock quality and explosive energy, with an evaluation of the cost of underbreak and overbreak.     

A quantitative analysis of the prototype [WCL] star CPD-56° 8032

We present a detailed, quantitative study of the standard [WC10] Wolf-Rayet central star CPD-56^o 8032 based on new high resolution AAT UCLES observations and the Hillier (1990) WR standard model. Our analysis of CPD-56^o 8032 gives the wind properties (T _*=34500K, lg (L/L )=3.8, lg (M/M a^–1)=–5.4,v =225 km s^–1) and chemistry (C/He=0.5, O/He=0.1, by number), the latter suggesting an intimate relationship with the Ovi PN central stars and the PG 1159-035 objects. A comparison between the wind properties of CPD-56^o 8032 and Sk-66^o 40 (WN 10) indicates that low excitation, low wind velocity WR winds are common to both low mass PN central stars (WC sequence) and high mass post-LBV's (WN sequence).