The gravitational field of topographic-isostatic masses and the hypothesis of mass condensation II-the topographic-isostatic geoid

In Part I we focussed on a convergent representation of the gravitational potential generated bytopographic masses on top of the equipotential surface atMean Sea Level, thegeoid, and by those masses which compensate topography. Topographic masses have also been condensated, namely represented by a single layer. Part II extends the computation of the gravitational field of topographic-isostatic masses by a detailed analysis of itsforce field in terms ofvector-spherical harmonic functions. In addition, the discontinuous mass-condensated topographic gravitational force vector (head force) is given. Once we identify theMoho discontinuity asone interface of isostatically compensated topographical masses, we have computed the topographic potential and the gravitational potential which is generated by isostatically compensated masses atMean Sea Level, the geoid, and illustrated by various figures of geoidal undulations. In comparison to a data oriented global geoid computation ofJ. Engels (1991) the conclusion can be made that the assumption of aconstant crustal mass density, the basic condition for isostatic modeling, does not apply. Insteaddensity variations in the crust, e.g. betweenoceanic and continental crust densities, have to be introduced in order to match the global real geoid and its topographic-isostatic model. The performed analysis documents that thestandard isostatic models based upon aconstant crustal density areunreal.     

Structure and oscillations in quiescent filaments from observations in He i λ10830 å

Observations of two quiescent filaments show oscillatory variations in Doppler shift and central intensity of the He i 10830 Å line.The oscillatory periods range from about 5 to 15 min, with dominant periods of 5, 9, and 16 min. The 5-min period is also detected in the intensity variations, after correction for atmospheric effects. Doppler shifts precede intensity variations by about one period. The possibility that the oscillations are Alfvén waves is discussed.The Doppler signals of the filament form fibril-like structures. The fibrils are all inclined at an angle of about 25° to the long axis of the filament. The magnetic field has a similar orientation relative to the major direction of the filament, and the measured Doppler signals are apparently produced by motions along magnetic flux tubes threading the filament.The measured lifetimes of the small-scale fibrils of quiescent disk filaments are very likely a combined effect of intensity modulations and reshuffling of the structures.     

Pillow talk

Three distinct types of pillows and pillow lava sequences with different modes of origin have been recognized in the extrusive sequences comprising the upper parts of ophiolite complexes that represent the mafic portion of the floor of an Early Cretaceous back-arc basin in southern Chile. One type of pillow formed by non-explosive submarine effusion. A second type formed by magmatic intrusion into pre-existing aquagene tuff formed by explosive eruption. The third type of pillow occurs within dikes, forming pillowed dikes, possibly as a result of vapor streaming within a cooling dike. Where studied in southern Chile, aquagene tuffs and intrusive pillows decrease and water-lain pillows increase in relative abundance from north to south. This variation corresponds with a north-to-south decrease in both the relative volume of extrusives to extensional dikes and the range and volume of differentiated rocks, suggesting a southward increase in rate of extension relative to rate of magma supply within the spreading ridges at which the ophiolites formed. In the northern part of the original basin where the rate of extension was small relative to the rate of magma supply, magma remained in magma chambers longer, resulting in a greater range and volume of differentiated rocks. The larger volume of more differentiated, cooler and more viscous magmas, in conjunction with the likelihood of more violent eruption of volatile-rich differentiates, may have been responsible for the large volume of aquagene tuff in the northern part of the original basin. These observations in southern Chile suggest that ophiolites which contain a great abundance of aquagene tuffs and intrusive pillow lavas formed in tectonic environments in which the rate of extension was small relative to the rate of magma supply (island arcs, embryonic marginal basins). Ophiolites with predominantly water-lain pillowed and massive lavas formed in tectonic environments in which the rate of extension was large relative to the rate of magma supply (mid-ocean ridges, mature back-arc basins). Thus geologic field data may supplement geochemical data as a tool in distinguishing the original igneous-tectonic environments in which ophiolites originate.     

Effective collision strengths for fine-structure forbidden transitions among the 3s23p4 levels of Cl ii

The ab initio R -matrix method is used to calculate effective collision strengths for electron-impact excitation of the sulphur-like ion Cl  ii in the close-coupling approximation. All 10 astrophysically important fine-structure forbidden transitions within the 3s²3p⁴     ,     ,     ground configuration levels are considered. The 12 lowest LS target states are included in the calculation. Effective collision strengths are obtained by averaging the electron collision strengths over a Maxwellian distribution of electron velocities. Results are presented for electron temperatures in the range  log  T (K)=3.3  to  log  T (K)=5.5  , appropriate for astrophysical applications. These are the only effective collision strength data that are currently available.     

Structure Function Analysis of Two-Scale Scalar Ramps. Part II: Ramp Characteristics and Surface Renewal Flux Estimation

Ramp features in the turbulent scalar field are associated with turbulent coherent structures, which dominate energy and mass fluxes in the atmospheric surface layer. Although finer scale ramp-like shapes embedded within larger scale ramp-like shapes can readily be perceived in turbulent scalar traces, their presence has largely been overlooked in the literature. We demonstrate the signature of more than one ramp scale in structure functions of the turbulent scalar field measured from above bare ground and two types of short plant canopies, using structure-function time lags ranging in scale from isotropic to larger than the characteristic coherent structures. Spectral analysis of structure functions was used to characterize different scales of turbulent structures. By expanding structure function analysis to include two ramp scales, we characterized the intermittency, duration, and surface renewal flux contribution of the smallest (i.e., Scale One) and the dominant (i.e., Scale Two) coherent structure scales. The frequencies of the coherent structure scales increase with mean wind shear, implying that both Scale One and Scale Two are shear-driven. The embedded Scale One turbulent structure scale is ineffectual in the surface-layer energy and mass transport process. The new method reported here for obtaining surface renewal-based scalar exchange works well over bare ground and short canopies under unstable conditions, effectively eliminating the α calibration for these conditions and forming the foundation for analysis over taller and more complex surfaces.     

The impact of surplus units from the first Kyoto period on achieving the reduction pledges of the Cancún Agreements

Countries with emission levels below their emission allowances have surplus Assigned Amount Units (AAUs) or other emission credits. Under the Kyoto Protocol, these surplus credits may effectively be carried from the first to a following commitment period. In the climate negotiations, various rules for carry-over and sale of surplus allowances have been put forward. This paper analyses the effect of these options on the reduction pledges for 2020, taking into account the estimated credits from the Clean Development Mechanism, Joint Implementation projects, and land-use activities for the first commitment period. For current Kyoto Protocol rules of unlimited carry-over of surplus allowances and limited carry-over of other credits, the environmental effectiveness of reduction pledges could be seriously undermined. For the group of countries that showed a willingness to participate in a second commitment period, it could imply that instead of an aggregated 2020 target resulting from the pledges of 18 to 28?% below 1990 levels by 2020, their emissions could return to business-us-usual emission projections. For the EU, a 30?% target by 2020 could imply higher emissions compared to a 20?% target, if surplus allowances would be used for achieving the 30?% but not for the 20?% target. Restricting the use of Kyoto surplus units to domestic use only, would limit the problem, but still seriously undermine the effectiveness of 2020 reduction targets.     

Geochronology and geochemistry of Grenvillian igneous suites in the northern Oaxacan Complex, southern Mexico: tectonic implications

Chemical and U–Pb isotopic analyses of metaigneous rocks in the northern Oaxacan Complex in southern Mexico indicate that they form part of two granitic–gabbroic suites intruded at 1157–1130 and 1012 Ma, which were metamorphosed under granulite facies conditions between 1004 and 980 Ma. Although the older suite has both within-plate and arc geochemical signatures, the arc characteristics (enrichment of La and Ce relative to Nb, Ta, and Th) are inferred to result from crustal contamination, a conclusion consistent with their negative _Nd signatures. The younger suite is spatially associated with anorthosites (from which we were unable to acquire a protolith age), suggesting that collectively it forms part of anorthosite–mangerite–charnockite–granite (AMCG) suites. The tholeiitic nature of the mafic rocks along with the within-plate character of the felsic rocks suggests that they were intruded during extension related to either farfield backarc rifting, rifting above a slab window, or anorogenic intercontinental rifting. Potentially correlative AMCG suites are widespread in Mexico, the Grenville Province of eastern Canada and northeastern USA, and the Andean massifs of Colombia, however, Pb isotopic data most closely resemble those in South America. These data are consistent with published hypotheses that suggest Oaxaquia represents an exotic terrane derived from Amazonia.     

The effect of naturally acidified irrigation water on agricultural volcanic soils. The case of Asembagus, Java, Indonesia

Acid water from the Banyuputih river (pH  3.5) is used for the irrigation of agricultural land in the Asembagus coastal area (East Java, Indonesia), with harmful consequences for rice yields. The river water has an unusual composition which is caused by seepage from the acidic Kawah Ijen crater lake into the river. This unique irrigation setting allows the study of soil acidification in situ. This paper assesses the effects of volcanogenically contaminated irrigation water on the chemical properties of the agricultural soils.The changes in soil properties were evaluated by comparing samples taken from the topsoil and sub-soil (1–3 m depth) from areas irrigated with acid water and areas irrigated with neutral water. The field survey thus resulted in four soil categories. Bulk soil composition, organic matter content, moisture content and particle size distribution were determined. Reactive phases were quantified with the selective extractions 1 M KCl, 0.1 M Na-pyrophosphate and 0.2 M acid ammonium oxalate (AAO).By comparing the four soil categories it is shown that the use of the naturally polluted irrigation water has had a large influence on the chemical composition of the topsoil. The composition of the soil solution has changed over the entire investigated soil profile. Furthermore the acid irrigation water has strongly modified the composition of the reactive phases, extracted as KCl, pyrophosphate, and AAO extractable elements, and also the bulk soil composition has been significantly modified. Overall this has resulted in the net dissolution of some elements and the net precipitation of others. The changes in the reactive phases and bulk soil composition are only apparent in the topsoil (0–20 cm) but not in the deeper soil.     

PM2.5 co-benefits of climate change legislation part 2: California governor’s executive order S-3-05 applied to the transportation sector

California Governor’s Executive Order (CGEO) S-3-05 requires that California greenhouse gas (GHG) emissions be reduced to 80 % below 1990 levels by the year 2050. Meeting this target will require drastic changes in transportation technology, fuel, and behavior which will reduce criteria pollutant emissions as well as GHG emissions. The improvement to local air quality caused by the reduced criteria pollutant emissions must be calculated to fully evaluate the overall benefits and costs of CGEO S-3-05. In the present study, seven different transportation scenarios that move towards the goals of CGEO S-3-05 in the transportation sector were examined to determine how they would affect future airborne particulate matter (PM_2.5) concentrations in California: (1) hydrogen fuel cells, (2) electric vehicles, (3) high efficiency vehicles, (4) public mass transit, (5) biofuels, (6) biofuels + hybrid electric vehicles, and (7) hydrogen fuel cells + electric vehicles. The air quality implications of each scenario were evaluated using a chemical transport model applied during a wintertime stagnation episode representing future climate in California. Scenarios (6) and (7) reduced population-weighted PM_2.5 mass concentrations by ~9 % and PM_2.5 elemental carbon (EC) concentrations by ~30 % relative to base-case predictions.