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51.
From February to March 1989 the Phobos 2 spacecraft took 37 TV images of Phobos at a distance of 190-1100 km. These images complement Mariner-9 and Viking data by providing higher-resolution coverage of a large region West of the crater Stickney (40-160 degrees W) and by providing disk-resolved measurements of surface brightness at a greater range of wavelengths and additional phase angles. These images have supported updated mapping and characterization of large craters and grooves, and have provided additional observations of craters' and grooves' bright rims. Variations in surface visible/near-infrared color ratio of almost a factor of 2 have been recognized; these variations appear to be associated with the ejecta of specific large impact craters. Updated determinations of satellite mass and volume allow calculation of a more accurate value of bulk density, 1.90 +/- 0.1 g cm-3. This is significantly lower than the density of meteoritic analogs to Phobos' surface, suggesting a porous interior perhaps containing interstitial ice.  相似文献   
52.
This is a 4-year longitudinal study to evaluate changes to the environment and exposure of young children associated with the introduction of methylcyclopentadienyl manganese tricarbonyl (MMT) into Australia in 2000. The cohort includes 57 females and 56 males; age range of 0.29 to 3.9 years. Samples are collected every 6 months from children in residences located at varying distances from major traffic thoroughfares in Sydney. Environmental samples: air, house and day care dustfall, soil, dust sweepings and gasoline. Samples from children: blood, urine, handwipes prior to and after playing outdoors, and a 6-day duplicate diet. All samples are analyzed for a suite of 20 elements using ICP-MS. Results are presented for the first three 6-month sampling periods for Pb and Mn. For dustfall accumulation, there was no significant change over the 3 sampling periods (time) for Pb or Mn, and a positive relationship between ‘traffic exposure' (traffic volume and proximity to the road) and Pb but not Mn. For handwipes, Pb and Mn in wipes taken from children after playing outdoors were usually significantly greater than for wipes taken prior to playing. There was no significant association between Pb or Mn in handwipes with traffic exposure. Dustfall accumulation was a significant predictor for Pb in the handwipes, and dust sweepings were a significant predictor of Mn in handwipes.  相似文献   
53.
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments.  相似文献   
54.
For the sake of cost and potential environmental risk, it is necessary to minimize the amount of chelates used in chemically-enhanced phytoextraction. In the present study, a biodegradable chelating agent, EDDS was added in a hot solution at 90℃ to the soil in which garland chrysanthemum (Chrysanthemum coronarium L.) and beans (Phaseolus vulgaris L., white bean) were growing. The application of hot chelate solutions was much more efficient than the application of normal chelate solutions (25℃) in improving the uptake of heavy metals by plants. When 1 mmol kg1 of EDDS as a hot solution was applied to soil, the concentrations ofCu, Zn and Cd and the total phytoextraction by the shoots of the two plant species exceeded or approximated those in the shoots of plants treated with 5 mmol kg^-1 of normal EDTA solution. The concentrations of metals in the shoots of beans were significantly correlated with the relative electrolyte leakage rate of root cells, indicating that the root damage resulting from the hot solution might play an important role in the process of chelate-enhanced metal uptake. The soil leaching study demonstrated that decreasing the dosage of chelate resulted in decreased concentrations of soluble metals in soils. On the 28th day following the application of chelate, the concentrations of soluble metals in the EDDS treated soil were not significantly different from the concentrations in the control soil to which chelates had not been applied.  相似文献   
55.
Permeable Reactive Barrier (PRB) is an emplacement of inert material (s) in the subsurface, designed to intercept a contaminated plume, provides a preferential flow path through the reactive media, and transforms the contaminant into environmentally acceptable forms to attain concentration remediation goals at the discharge of the barrier. The phenomena, which help in remediation within PRB, are adsorption/sorption, precipitation, oxidation/reduction and biodegradation. Various materials like zero-valent iron, zero-valent bi-metals, natural zeolites, organic carbon, fly ash, zeolites, limestone, activated alumina, apatites, etc. have been tried by many researchers to remove organic and inorganic contaminants. In USA, Canada, and many European countries commercial full-scale and pilot scale PRBs are successfully working. The design and installation of full scale PRBs needs laboratory treatability and dynamic flow column experiments? The concept of PRB is being applied to treat contaminated surface water in the Katedan industrial area, Hyderabad, India. National Geophysical Research Institute (NGRI), Hyderabad, India, conducted systematic studies in collaboration with Norwegian Geotechnical Institute (NGI), Norway, to develop PRB technique to decontaminate the surface water pollution due to industrial effluent. A site assessment study in the Katedan Industrial Area, were carried out and water, soil and sediment from the lakes of the area were found to be polluted with high concentrations of heavy metals like As, Pb, Cr, Cd, Ni, etc. Adsorption studies at NGRI with synthetic samples and in-situ industrial effluent using different reactive media for removing contaminants like arsenic, chromium, cadmium, copper, nickel, lead and zinc have been carried out and yielded satisfactory results. The performance of zero-valent iron and limestone is encouraging in removing As,  相似文献   
56.
A link between the inhalation of respirable silicas (SiO2) and respiratory diseases such as silicosis is widely recognized. Ash from dome collapse eruptions on Montserrat has been found to contain high levels (〉20%) of silicas in the form of cristobalite, tridymite, quartz and/or amorphous silica. The toxicity of these silica polymorphs varies widely. Cristobalite and quartz (tridymite less well established) are viewed as carcinogenic to humans whereas amorphous silica generally shows a reduced biological response. In assessing the potential health effects of volcanic ash particulates it is vital to determine the types and concentration of silicas as well as their size (respirable fraction), shape and surface properties. The aim of this study is to develop methods to assess potentially toxic respirable airborne silicas in the dome collapse ash (applicable to a range of ash types) and to develop a model to predict the levels and types of respirable silicas from future eruptions. The model is being developed by comparing dome rock with related ash from a series of previous eruption events. Mineralogical assessment using conventional scanning X-ray diffraction (XRD) was hampered by difficulties in differentiating characteristic peaks for cristobalite and tridymite in complex multi-component ash samples (containing high levels of plagioclase). These difficulties have been largely overcome using an Enraf-Nonius PDS120 diffractometer with curved (120 degrees 20) position sensitive detector (PSD). The determination of size, shape and elemental characteristics of ash particulate and dome rock samples has been carried out using automated analytical scanning electron microscopy. The quantification of mineral proportions using PSD-XRD was highly successful with an accuracy of 1 to 2 wt%. However, the determination of phase proportions using automated analytical SEM was problematic due to scattering effects and the multiphase nature of many of the particles.  相似文献   
57.
In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors: mineralogy and hydrology. Parameters that potentially affect water chemistry include: host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations (for example: Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L). With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides.  相似文献   
58.
随着激光雷达(Light detection and ranging,Lidar)技术的成熟,美国地质调查局(U.S.Geo-logical Survey,USGS)在这个方向开展了许多应用研究。科学家们正在发展表达、使用高分辨率Lidar数据的新型技术;同时,为方便公众获取相应信息,数据及提取信息的发布手段也在研究之中。以下通过几个实例做一简要介绍。1典型研究1.1数据分发建立国家地图集(National Map)的一个目标是向公众发布基础数字地理信息。该地图集的高程部分是通过USGS地球观测系统(EROS)数据中心的国家高程数据集(National ElevationDataset,NED)维护的。NED提供3种…  相似文献   
59.
对新疆1996年5月28-30日一次特大暴雨过程的诊断分析,给出了暴雨产生的原因。  相似文献   
60.
1概述加强对天气、气候和水相关的极端事件的预测和预报,并通过实施完备的防灾、减灾、救灾战略,最大限度地降低气象灾害极端事件带来的负面影响,保证国家经济建设顺利进行和广大人民群众的生命财产安全是我们面临的重要任务。人工影响天气作为防灾减灾手段之一,在抵御气象灾害方面发挥着越来越重要的作用,为人类未雨绸缪,趋利避害,营造美好的生存环境,做出了越来越大的贡献。人工影响天气技术问世已有半个多世纪了,并从起初的人工增水逐步扩展到人工防雹、人工消云(雾)、人工防霜、人工抑制闪电等方面。同时,人工影响天气的理…  相似文献   
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