Organic geochemistry and petrology of barren and Mo–Ni–PGE mineralized marine black shales of the Lower Cambrian Niutitang Formation (South China)

Marine black shales of the Lower Cambrian Niutitang Formation in southern China host Mo–Ni–platinum group elements (PGE) mineralization confined to a phosphate- and pyrite-rich stratiform body (max. 20-cm thick). The H/C atomic ratio, carbon isotopic composition, FTIR spectra of bulk organic matter, and spectra of extractable part of organic matter indicate similar sources and thermal evolution of organic matter in barren and mineralized black shales.The morphology and relative abundance of organic particles in barren and mineralized shales are different. In barren black shales, organic particles comprise only elongated bodies and laminae 2–10 μm across or elongated larger bodies (> 10 μm) with R_max = 2.96–5.21% (Type I particles). Mineralized black shales contain Type I particles in rock matrix (90–95 vol%), small veinlets or irregular organic accumulations (Type II particles, 1–5 vol%) that display weak to well developed mosaic texture and a variable reflectance (R_max = 3.55–8.65%), and small (< 1 to 5 μm) rounded or irregular Type III organic particles (1–4 vol%) distributed within phosphate nodules and sulphide rip-up clasts. Type III particles show similar reflectance as particles of Type I in rock matrix. Type I particles are interpreted as remnants of in situ bacterially reworked organic matter of cyanobacteria/algal type, Type II as solidified products or oil-derived material (migrabitumen), and Type III particles as remnants of original organic matter in phosphatized or sulphidized algal/microbial oncolite-like bodies. Equivalent vitrinite reflectances of Type I and III particles in barren and mineralized rocks are similar and correspond to semi-anthracite and anthracite. Micro-Raman spectra of organic particles in rocks display a wide belt in the area of 1600 cm^− 1 (G belt) and approximately the same belt in the area of 1350 cm^− 1 (D belt). The ratio of integrated areas of the two belts correlate with R_max values.The Mo–Ni–PGE mineralized body is interpreted as to represent a remnant of phosphate- and sulphide-rich subaquatic hardground supplied with organic material derived from plankton and benthic communities as well as with algal/microbial oncolite-like bodies that originated in wave-agitated, shallow-water, nearshore environment.     

Isoseismals of the strongest Friuli aftershocks of September 1976

Summary Isoseismal maps of the three strongest Friuli aftershocks of September 1976 were compiled using the contributions from European countries within the shaken area. The characteristic features of the macroseismic fields are discussed.     

Annual and seasonal variability of precipitation in Vojvodina,Serbia

Annual and seasonal variability of precipitation observed at 92 stations in Vojvodina (Serbia) were analyzed during the period 1946–2006. The rainfall series were examined by means of the empirical orthogonal functions (EOF). The first set of singular vectors explains from 68.8 % (in summer) to 81.8 % (in winter) of the total variance. The temporal variability of the time series associated with the main EOF configurations (the principal components, PCs) was examined using the Mann–Kendall test and the spectral analysis. The time series of PC1 revealed decreasing trend in the winter and spring precipitation and increasing trend in the autumn, summer, and annual precipitation. The relationships between the first PC and circulation patterns, such as the North Atlantic Oscillation (NAO), the East Atlantic (EA) pattern, and East Atlantic/West Russia pattern, were also investigated. The PC1, displaying temporal behavior of the first mode, demonstrated evident correspondence with the NAO index in analysis of the annual, winter, and autumn precipitation. Power spectra of the PC1 show statistically significant oscillations of about 3.3 years for the spring precipitation and about 8 and 15 years for the winter precipitation. Comparisons with spectral analysis of authors for some regions in Europe, most of them in the Mediterranean domain, show that similar periodicities are detected.     

2D geological–geophysical model of the Timok Complex (Serbia,SE Europe): a new perspective from aeromagnetic and gravity data

The study reports new aeromagnetic and gravity data for the northern part of the Timok Magmatic Complex (TMC), East Serbia. The TMC is part of the Tethyan Eurasian metallogenic zone well known for hosting large copper and gold deposits. The complex formed by continuous volcanic activity 90–78 Ma ago, that developed in roughly three phases: Turonian andesites, Santonian–Campanian andesites/basaltic andesites (both mostly volcanic) and Campanian latites/monzonites (mostly shallow intrusive). The aeromagnetic measurements included acquiring total magnetic intensity data that were corrected for diurnal variations, leveling, microleveling, calculated normal field values, calculated anomaly values of total magnetic field intensity and reduction to the pole. The gravity measurements were carried out in an irregular grid with relative gravity values obtained using a Worden gravity meter. 2D modeling reveals that the subsurface extension of the Campanian Valja Str? pluton is ten times larger than it is indicated by its surface outcrops. This implies that the area south and southeast from the pluton can be interesting in terms of finding new porphyry systems. The model indicates that this intrusive body should not be considered as a deeply dissected pluton. This sheds new light onto its potential with respect to epithermal gold mineralization, as well. The model also suggests that there are larger non-exposed bodies of Santonian–Campanian volcanics and near-surface hydrothermally altered rocks than it is inferred from geological maps. The results of our study suggest that further interdisciplinary investigations in the TMC, in particular those integrating geophysics and geology, may have potential of advancing the existing exploration models.     

An analysis of heat waves in Serbia

In this study, heat waves at three meteorological stations in Serbia were analyzed based on the daily maximum temperature during the summer (June, July and August). The warmest summers as regards heat wave duration and severity occurred within the periods 1951–1952, 1987–1998 (especially 1994) and 2000–2007. The longest heat waves were recorded in 1952, lasting 16 days in Smederevska Palanka and 21 days in Ni?, while in 1994 in Belgrade lasting 18 days. The summer of 1994 in Belgrade and Smederevska Palanka, and 2003 in Ni? were characterized with the highest number of consecutive tropical days (21 and 29, respectively).The autoregressive-moving-average models were applied to generate long series of the daily maximum temperature, from which the relative frequencies of heat waves were estimated. The relationships between the longest heat waves, and the circulation conditions were analyzed using the subjective Hess–Brezowsky catalogue of weather types.     

Immigrant groups and the local environment: socio-spatial differentiation in Czech metropolitan areas

The spatial distribution of immigrant groups is a more relevant topic now than ever before. While the study of this topic has a long tradition in the “traditional” immigration countries, it is rare in the very different context of Central and Eastern Europe, especially at the level of metropolitan areas. This study aims to address this gap by providing an analysis of the spatial distribution of various immigrant groups (defined by country of citizenship) in 17 Czech metropolitan areas, and its determinants. First, we characterize the specific situation of the Czech immigration system. Then we use cluster analysis to create a typology of neighbourhoods and compare the distribution of immigrant groups in each type of neighbourhood. Finally, we use regression analysis to examine which characteristics of the local environment are connected to concentrations of different immigrant groups. We show that the presence of foreigners remains associated with core urban areas. Some predominantly Western citizens act as gentrifiers, being associated with spacious pre-war apartments in prestigious inner-city areas, but there are also signs of suburbanization among more well-off immigrants to Czech metropolitan areas. We identify little evidence of ghettoization of immigrants into socially excluded areas.     

Scalar-Flux Similarity in the Layer Near the Surface Over Mountainous Terrain

The scaled standard deviations of temperature and humidity are investigated in complex terrain. The study area is a steep Alpine valley, with six measurement sites of different slope, orientation and roughness (i-Box experimental site, Inn Valley, Austria). Examined here are several assumptions forming the basis of Monin–Obukhov similarity theory (MOST), including constant turbulence fluxes with height and the degree of self-correlation between the involved turbulence variables. Since the basic assumptions for the applicability of the MOST approach—horizontally homogeneous and flat conditions—are violated, the analysis is performed based on a local similarity hypothesis. The scaled standard deviations as a function of local stability are compared with previous studies from horizontally homogeneous and flat terrain, horizontally inhomogeneous and flat terrain, weakly inhomogeneous and flat terrain, as well as complex terrain. As a reference, similarity relations for unstable and stable conditions are evaluated using turbulence data from the weakly inhomogeneous and flat terrain of the Cabauw experimental site in the Netherlands, and assessed with the same post-processing method as the i-Box data. Significant differences from the reference curve and also among the i-Box sites are noted, especially for data derived from the i-Box sites with steep slopes. These differences concern the slope and the magnitude of the best-fit curves, illustrating the site dependence of any similarity theory.     

First record of vertical rhizomes in the seagrass Zostera marina (Novigrad Sea,Croatia)

We report the first record of vertical rhizome growth in the temperate seagrass Zostera marina. In a population of Z. marina occurring on subtidal sand in the Novigrad Sea (Croatia), an area subject to episodic high sediment transport, collected plants of Z. marina showed vertical rhizomes with shorter and narrower inter‐nodes (mean length = 3.4 ± 1.5 SD mm, mean width = 1.9 ± 0.3 SD mm) than those recorded for horizontal rhizomes (mean length = 9.0 ± 3.5 SD mm, mean width = 2.8 ± 0.4 SD mm). Out of a sample of 1130 rhizome fragments, 288 (25.5%) were vertical. Repeated moderate burial events may have stimulated the production of vertical rhizomes, and the ability of Z. marina to produce vertical rhizomes may enable it to withstand moderate burial in this highly dynamic environment.