Distribution and Influence of Iron Phases the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-ray Electron Spin Resonance(ESR) spectroscopes.The purity of the samples and the degree of their structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which persist after chemical dissolution of free iron.The Moessbauer spectra of these clays show two doublets with isomer shift and quadrupole splitting typical of octahedrally coordinated Fe^3 ,in addition to third doublet with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H) sample.Six-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octahedral symmetry as well as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activation of the investigated montmorillonite samplas by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,the amount and site occupation of Fe associated with kaolinite samples show an inverse correlation with the parameters used to describe the degree of crystallinity perfection,color,brightness and vitrification range of these kaolinite samples.     

Tunisian landfill leachate treatment using <Emphasis Type="Italic">Chlorella</Emphasis> sp.: effective factors and microalgae strain performance

The potential of the autoclaved Tunisian landfill leachate treatment using microalgae (Chlorella sp.) cultivation was investigated in this study. Landfill leachate was collected from Borj Chakir landfill, Tunisia. A full factorial experimental design 2² was proposed to study the effects of the incubation time and leachate ratio factors on the organic matter removal expressed in chemical oxygen demand (COD) and ammoniacal nitrogen (NH₄─N) and on the biological response of Chlorella sp. expressed by the cell density and chlorophyll content. All experiments were batch runs at ambient temperature (25 ± 2 °C). The Chlorella sp. biomass and chlorophyll a concentrations of 1.2 and 5.32 mg L^?1, respectively, were obtained with 10% leachate spike ratio. The obtained results showed that up to 90% of the ammoniacal nitrogen in landfill leachate was removed in 10% leachate ratio spiked medium with a residual concentration of 40 mg L^?1. The maximum COD removal rate reached 60% within 13 days of incubation time indicating that microalgae consortium was quite effective for treating landfill leachate organic contaminants. Furthermore, with the 10% leachate ratio spiked medium, the maximum lipid productivity was 4.74 mg L^?1 d^?1. The present study provides valuable information for potential adaptation of microalgae culture and its contribution for the treatment of Tunisian landfill leachate.     

利用瞬变电磁和多频电磁方法监测地下水位及其对Hawara遗址的影响

利用瞬变电磁（TEM）和地面电磁（GEM）方法,本文研究了埃及Hawara遗址区的地下水对遗址的影响.这个遗址包括Hawara金字塔、北区墓地、以及被称作“迷宫”的南区墓葬场所.现今Hawara遗址已经完全荒废,被耕作区和Bahr Wahba运河包围.地表水和地下水会破坏Hawara金字塔和“迷宫”遗址的地基,现在金字塔入口已被淹没至地面下约6 m深处.本文在耕作区、金字塔以及“迷宫”等三个地区进行了TEM勘察;在“迷宫”地区进行了GEM勘察.综合分析以上两种勘察数据,我们发现,农业灌溉是浸入到地下的水的主要来源;本地区地下水位随着观测点及海拔的不同,在地面以下2~7 m之间变化.     

The interrelation between the two hemispheres and long-range forecasting

Summary This investigation represents an attempt to illustrate some important aspects of the general circulation and the interrelation of seasonal atmospheric variations between northern and southern hemispheres. It presents evidence that the winter circulation of the northern hemisphere has a significant influence on subsequent seasons in the southern hemisphere. The idea is backed up by specific examples, showing that winter rainfall at Malta and Cairo is strongly correlated with the subsequent seasonal rainfall in Zimbabwe. These findings, which potentially allow to forecast Zimbabwe rainfalls several months in advance of the rainy season, are interpreted physically in terms of the variations of major features of the general circulation, such as the strength of the Winter Siberian Anticyclone (WSA) and the El-Niño-Southern Oscillation (ENSO). These two features appear to be related, from the point of view that the forecasting techniques of the study also allow the possibility of predicting the outstanding ENSO events several months before January.With 8 Figures     

Middle Miocene ostracods from Wadi Sudr,westcentral Sinai,Egypt: systematic,biostratigraphy and palaeobiogeographic affinity with the Mediterranean realm

The investigation of the exposed middle Miocene strata from Wadi Sudr yielded well-preserved ostracod carapaces. Detailed taxonomic and paleontological studies led to the recognition of 36 ostracod species belonging to 25 genera, 4 species of them were considered new which fully described. Three assemblage biozones were recorded as follows: Actinocythereis spinosa–Actinocythereis hystrix zone, Chrysocythere cataphracta muricata-Cytheretta africana zone, and Disopontocypris schweijeri-Bythocypris tripolensis zone. The recorded biozones were calibrated with the previously studied middle Miocene planktonic foraminiferal biozones on the same samples and also correlated with the Miocene ostracod biozones from the neighboring countries. Our ostracod assemblages present in the lower and upper parts of the studied section (section II) indicated an inner neritic marine environment of moderate energy of currents and rapid sedimentation, while the assemblages in the middle part showed more deeper (outer neritic) environments with low energy of currents and low rate of sedimentation. The palaeobiogeographic distribution of the studied ostracods showed high affinity with the ostracod assemblages of the southern Mediterranean and moderate to low affinities with that of the northern and eastern Mediterranean respectively. The highly ornamented ostracod species with structures on the carapace were recorded from both Northern and Southern Mediterranean, while the smooth ones were found in the Southern Mediterranean only. The highly ornamented species are more widely distributed in both Southern and Northern Mediterranean than the smooth species. This may indicate that the ornamented species are more able to migrate than the smooth ones.     

Geochemical evidence for the genesis of the Sarical-Yavu hematite mineralizations (Sivas,Central Turkey)

The hematite mineralization under investigation is located 11 km NE of Sarical (Yavu) village of the Yildizeli town (Sivas Province) in central Turkey. The region is within the Central Anatolian Thrust Zone and is comprised of metamorphic units, ophiolitic rocks and overlying Tertiary volcanic and volcanosedimentary rocks in addition to Neogene terrestrial deposits. The mineralization occurs as lenticular or bedded bodies and is composed chiefly of hematite and a lesser amount of goethite. Quartz, calcite, and dolomite are the gangue minerals. Kaolinite and zeolite are the common alteration products. In this study, geochemical and mineralogical investigations were carried out using an X-ray diffractometer analysis (XRD), Raman spectroscopy, and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDX). The V/(V + Ni) ratio increases in parallel to the detritic contribution, and when this ratio is less than 0.60, deposition conditions are said to be anoxic. Considering the V/(V + Ni) ratio and Ce_anom values of the studied samples, we suggest that the environment is both oxic and anoxic in character. The overall assessment of the field observations, mineral paragenesis, major, trace, and rare earth element (REE) data indicates that the Sarical hematite mineralization is of a hydrothermal-sedimentary type.     

Land use/land cover change impact on groundwater quantity and quality: a case study of Ajman Emirate,the United Arab Emirates,using remote sensing and GIS

Ajman is a rapidly urbanizing emirate with land development succeeding at a fast pace. This study aims to monitor land use/land cover changes and assesses the impact of these changes on groundwater quality and quantity of the shallow aquifer using multitemporal remote sensing data and geographic information system (GIS). To monitor the land use/land cover changes, the Spectral Angle Mapper (SAM) and the Normalized Difference Vegetation Index (NDVI) algorithms were utilized. The obtained maps were correlated against a set of total dissolved solid (TDS); Mg, Cl, and NO₃ groundwater quality index; and depth to the groundwater table maps constructed from groundwater data. The spatial analysis revealed a sharp depletion in groundwater quality and quantity related to the increase in the land use/land cover classes. The mean total TDS is from 21,971 to 26,450 mg/L and depth to groundwater level from ?12.33 to ?17.2 m over a period of 15 years. Maps of normalized difference and groundwater quality sustainability showed that the eastern side of the study area has a high value of groundwater quality sustainability and normalized difference, while the western side of the study area has a minimal value of groundwater quality sustainability and normalized difference. This study is of great assistance for decision makers and land developers to relate to municipal land allotment in rapidly developing regions such as Ajman.     

Automatic Feature Extraction Module for Change Detection in Al Ain,UAE: Analysis by Means of Multi-temporal Remote Sensing Data

Monitoring new changes in cities adjacent to dynamic sand dunes requires precise classifier technique. Unlike traditional techniques of supervised classification which use training sites, the integration of image transformation tasseled cap and automatic feature extraction module based on spectral signatures has provided to be sensitive and realistic techniques with time and cost effective. The proposed module was applied to Al Ain district, United Arab Emirates (UAE). The module consists of four steps in terms of segmentation, thresholding and clustering and computing attributes. The obtained greenness and classified maps were then enhanced by applying a 3?×?3 Sobel filter. The new changes were detected by combining the multi-temporal greenness and classification maps. Accuracy assessment and quantitative analysis were performed using confusion matrix and ground truthing. The results showed significant increasing in urban and agricultural areas from the year from 1990 to 2000 compared with the period of time from the year 2000 to 2006. The image difference showed that the vegetation and building classes had increased 7.58 and 20.28 km² respectively. This study showed that image difference and fuzzy logic approach are the most sensitive techniques for detecting new changes in areas adjacent to dynamic sand dunes.