Thermal neutron capture effects in radioactive and stable nuclide systems

Neutron capture effects in meteorites and lunar surface samples have been successfully used in the past to study exposure histories and shielding conditions. In recent years, however, it turned out that neutron capture effects produce a nuisance for some of the short‐lived radionuclide systems. The most prominent example is the ¹⁸²Hf‐¹⁸²W system in iron meteorites, for which neutron capture effects lower the ¹⁸²W/¹⁸⁴W ratio, thereby producing too old apparent ages. Here, we present a thorough study of neutron capture effects in iron meteorites, ordinary chondrites, and carbonaceous chondrites, whereas the focus is on iron meteorites. We study in detail the effects responsible for neutron production, neutron transport, and neutron slowing down and find that neutron capture in all studied meteorite types is not, as usually expected, exclusively via thermal neutrons. In contrast, most of the neutron capture in iron meteorites is in the epithermal energy range and there is a significant contribution from epithermal neutron capture even in stony meteorites. Using sophisticated particle spectra and evaluated cross section data files for neutron capture reactions we calculate the neutron capture effects for Sm, Gd, Cd, Pd, Pt, and Os isotopes, which all can serve as neutron‐dose proxies, either in stony or in iron meteorites. In addition, we model neutron capture effects in W and Ag isotopes. For W isotopes, the GCR‐induced shifts perfectly correlate with Os and Pt isotope shifts, which therefore can be used as neutron‐dose proxies and permit a reliable correction. We also found that GCR‐induced effects for the ¹⁰⁷Pd‐¹⁰⁷Ag system can be significant and need to be corrected, a result that is in contrast to earlier studies.     

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.     

Regularized derivatives of potential fields and their role in semi-automated interpretation methods

Evaluation of higher derivatives (gradients) of potential fields plays an important role in geophysical interpretation (qualitative and/or quantitative), as has been demonstrated in many approaches and methods. On the other hand, numerical evaluation of higher derivatives is an unstable process – it has the tendency to enlarge the noise content in the original data (to degrade the signal-to-noise ratio). One way to stabilize higher derivative evaluation is the utilization of the Tikhonov regularization. In the submitted contribution we present the derivation of the regularized derivative filter in the Fourier domain as a minimization task by means of using the classical calculus of variations. A very important part of the presented approach is the selection of the optimum regularization parameter – we are using the analysis of the C-norm function (constructed from the difference between two adjacent solutions, obtained for different values of regularization parameter). We show the influence of regularized derivatives on the properties of the classical 3D Euler deconvolution algorithm and apply it to high-sensitivity magnetometry data obtained from an unexploded ordnance detection survey. The solution obtained with regularized derivatives gives better focused depth-estimates, which are closer to the real position of sources (verified by excavation of unexploded projectiles).     

The radio luminosity function and the luminosity diameter function of extragalactic radio sources

On the basis of a radio index-surface brightness diagram recently published, the luminosity function and the luminosity diameter function are obtained. The uncertainties due to the incompleteness of the sample are of the same order as the statistical uncertainties. The luminosity function differs considerably from a simple power law and supports the distinction of two populations. The density of the weak population (P<10³⁵ W Hz⁻¹ ster⁻¹ at 1400 MHz) follows nearly a power law in P and increases towards small diameters at least down to I kpc. The density of the strong population (the high luminosity and small diameter part of which is occupied by the quasars) has a maximum between 10²⁵ and 10²⁸ W Hz⁻¹ ster⁻¹ and around 100 kpc. A strong evolution effect is clearly present and is in a good agreement with the models obtained from the log N-log S counts.     

Light outburst of a compact galaxy

In a field near M3 photographed in U,B,V from 1963 to 1969 one of 750 compact galaxies shows a brightening of 1 mag in B during 1966/67.     

Inertial Effects on the Vertical Transport of Suspended Particles in a Turbulent Boundary Layer

In many atmospheric flows, a dispersed phase is actively suspended by turbulence, whose competition with gravitational settling ultimately dictates its vertical distribution. Examples of dispersed phases include snow, sea-spray droplets, dust, or sand, where individual elements of much larger density than the surrounding air are carried by turbulent motions after emission from the surface. In cases where the particle is assumed to deviate from local fluid motions only by its gravitational settling (i.e., they are inertialess), traditional flux balances predict a power-law dependence of particle concentration with height. It is unclear, however, how particle inertia influences this relationship, and this question is the focus of this work. Direct numerical simulations are conducted of turbulent open-channel flow, laden with Lagrangian particles of specified inertia; in this way the study focuses on the turbulent transport which occurs in the lowest few meters of the planetary boundary layer, in regions critical for connecting emission fluxes to the fluxes felt by the full-scale boundary layer. Simulations over a wide range of particle Stokes number, while holding the dimensionless settling velocity constant, are performed to understand the role of particle inertia on vertical dispersion. It is found that particles deviate from their inertialess behaviour in ways that are not easily captured by traditional theory; concentrations are reduced with increasing Stokes number. Furthermore, a similarity-based eddy diffusivity for particle concentration fails as particles experience inertial acceleration, precluding a closed-form solution for particle concentration as in the case of inertialess particles. The primary consequence of this result is that typical flux parametrizations connecting surface emission models (e.g., saltation models or sea-spray generation functions) to elevated boundary conditions may overestimate particle concentrations due to the reduced vertical transport caused by inertia in between; likewise particle emission may be underestimated if inferred from concentration measurements aloft.