Dispersal of natural and anthropogenic lead through submarine canyons at the Portuguese margin

Submarine canyons represent natural conduits for preferential transport of particulate material, including anthropogenic contaminants, from coastal zones directly to the deep sea. To assess related dispersal of natural and anthropogenic lead (Pb), we analyzed Pb concentrations and stable isotope ratios in surface sediments and sediment trap particulate material from the Portuguese margin Nazaré and Setúbal/Lisbon canyons. Geochemical data are integrated with previously obtained data on near-bottom hydrodynamics and processes and pathways of sediment transport. The two canyon systems are located in close geographic proximity to each other, but represent contrasting settings in terms of sediment input and down-canyon sediment transport processes.Concentration–isotope diagrams and three-isotope plots (²⁰⁶Pb/²⁰⁷Pb vs. ²⁰⁸Pb/²⁰⁶Pb) suggest binary mixing between natural and anthropogenic end members. The inferred isotopic signature of pollutant Pb (²⁰⁶Pb/²⁰⁷Pb=1.143 [1.134–1.149, 95% confidence interval]) is most consistent with industrial Pb; ongoing influence from gasoline Pb additives is at most of minor importance. Two proposed natural end members most likely bracket the isotopic signature of natural Pb. Accordingly, binary mixing calculations indicate that on average 20–45% vs. 35–55% of total Pb is derived from anthropogenic sources in the Nazaré and Setúbal–Lisbon canyon systems, respectively. Enhanced anthropogenic influence in the latter area is consistent with its proximity to heavily populated and industrialized areas and with sediment input from the Tagus and Sado rivers, potential major carriers of pollutant particles. In both canyon systems, the anthropogenic component generally decreases with increasing water depth.Isotopic signatures of sediment trap particulate material are generally consistent with surface sediment data at similar water depth, but show large variability in the upper Nazaré canyon and major deviations from surface sediments in the lower canyon. In the lower canyon, Pb isotopic ratios of sediment trap particulate material mostly reflect low pelagic fluxes from the overlying water column, whereas surface sediment signatures are dominated by episodic down-canyon mass transport events. Such gravity flows appear to incorporate older (pre-industrial) material masking the isotopic signature of pollutant Pb. Large variability in the upper canyon reflects continuous sediment resuspension by bottom currents. Stronger average bottom currents are associated with higher ²⁰⁶Pb/²⁰⁷Pb ratios of sediment trap particulate material and hence decreased influence of pollutant Pb. This may reflect preferential resuspension of natural Pb at the canyon floor and/or additional remobilization of older, less-polluted sediment in adjacent areas such as the canyon walls.     

Petrology and geochemistry of feldspathic impact‐melt breccia Abar al' Uj 012, the first lunar meteorite from Saudi Arabia

Abar al' Uj (AaU) 012 is a clast‐rich, vesicular impact‐melt (IM) breccia, composed of lithic and mineral clasts set in a very fine‐grained and well‐crystallized matrix. It is a typical feldspathic lunar meteorite, most likely originating from the lunar farside. Bulk composition (31.0 wt% Al₂O₃, 3.85 wt% FeO) is close to the mean of feldspathic lunar meteorites and Apollo FAN‐suite rocks. The low concentration of incompatible trace elements (0.39 ppm Th, 0.13 ppm U) reflects the absence of a significant KREEP component. Plagioclase is highly anorthitic with a mean of An_96.9Ab_3.0Or_0.1. Bulk rock Mg# is 63 and molar FeO/MnO is 76. The terrestrial age of the meteorite is 33.4 ± 5.2 kyr. AaU 012 contains a ~1.4 × 1.5 mm² exotic clast different from the lithic clast population which is dominated by clasts of anorthosite breccias. Bulk composition and presence of relatively large vesicles indicate that the clast was most probably formed by an impact into a precursor having nonmare igneous origin most likely related to the rare alkali‐suite rocks. The IM clast is mainly composed of clinopyroxenes, contains a significant amount of cristobalite (9.0 vol%), and has a microcrystalline mesostasis. Although the clast shows similarities in texture and modal mineral abundances with some Apollo pigeonite basalts, it has lower FeO and higher SiO₂ than any mare basalt. It also has higher FeO and lower Al₂O₃ than rocks from the FAN‐ or Mg‐suite. Its lower Mg# (59) compared to Mg‐suite rocks also excludes a relationship with these types of lunar material.     

Atmospheric Circulation Changes in Response to an Observed Stratospheric Zonal Ozone Anomaly

Abstract

In a sensitivity study, the influence of an observed stratospheric zonal ozone anomaly on the atmospheric circulation was investigated using the Fifth Generation European Centre Hamburg Model (ECHAM5) which is a general circulation model. The model was run from 1960 to 1999 (40 years) with a mean seasonal cycle of zonally symmetric ozone. In order to isolate the induced dynamical influence of the observed zonally asymmetric part of the three-dimensional stratospheric ozone, a second run was performed for the boreal extratropics using prescribed monthly means from the 40-year reanalysis dataset from the European Centre for Medium-range Weather Forecasts (ERA-40). The main findings are the interdecadal westward shift of the polar vortex at about 65°N and a significant increase in the number of stratospheric sudden warmings during the 1980–99 period. Under the action of zonally asymmetric ozone a decrease in the Arctic Oscillation was identified between the mid-1980s and the mid-1990s. The lag correlation between the mean Arctic Oscillation at the surface and the daily stratospheric northern annular mode increased in mid-winter. Furthermore, we examined the influence of the stratospheric zonal ozone anomaly on Rossby wave breaking in the upper troposphere and found a significant westward shift of poleward Rossby wave breaking events over western Europe in the winter. By this we show that the stratospheric zonal ozone anomaly has a strong influence on the tropospheric circulation as a result of enhanced dynamical coupling processes.     

Underestimation of Snow Accumulation Rate in Central Antarctica (Vostok Station) Derived from Stake Measurements

Russian Meteorology and Hydrology - It is shown that the snow stake measurements in central Antarctica systematically underestimate the value of the snow build-up. Two methods for the calculation...     

Winter-to-spring temperature dynamics in Turkey derived from tree rings since AD 1125

In the eastern Mediterranean in general and in Turkey in particular, temperature reconstructions based on tree rings have not been achieved so far. Furthermore, centennial-long chronologies of stable isotopes are generally also missing. Recent studies have identified the tree species Juniperus excelsa as one of the most promising tree species in Turkey for developing long climate sensitive stable carbon isotope chronologies because this species is long-living and thus has the ability to capture low-frequency climate signals. We were able to develop a statistically robust, precisely dated and annually resolved chronology back to AD 1125. We proved that variability of δ¹³C in tree rings of J. excelsa is mainly dependent on winter-to-spring temperatures (January–May). Low-frequency trends, which were associated with the medieval warm period and the little ice age, were identified in the winter-to-spring temperature reconstruction, however, the twentieth century warming trend found elsewhere could not be identified in our proxy record, nor was it found in the corresponding meteorological data used for our study. Comparisons with other northern-hemispherical proxy data showed that similar low-frequency signals are present until the beginning of the twentieth century when the other proxies derived from further north indicate a significant warming while the winter-to-spring temperature proxy from SW-Turkey does not. Correlation analyses including our temperature reconstruction and seven well-known climate indices suggest that various atmospheric oscillation patterns are capable of influencing the temperature variations in SW-Turkey.     

H2 in molecular shocks: observations from 2 to 12 microns

We present spectroscopy of the molecular shock in the supernova remnant IC 443. The H₂ level populations in IC 443 are nearly identical to Orion Peak 1 (Brand et al. 1988; Parmar et al. 1994) and are consistent with a partially dissociative J-shock. The similarity with Orion suggests the shock processes which dominate the emission in both regions are essentially identical.     

Hydrogen peroxide on Mars: evidence for spatial and seasonal variations

Hydrogen peroxide (H₂O₂) has been suggested as a possible oxidizer of the martian surface. Photochemical models predict a mean column density in the range of 10¹⁵-10¹⁶ cm⁻². However, a stringent upper limit of the H₂O₂ abundance on Mars (9×10¹⁴ cm⁻²) was derived in February 2001 from ground-based infrared spectroscopy, at a time corresponding to a maximum water vapor abundance in the northern summer (30 pr. μm, Ls=112°). Here we report the detection of H₂O₂ on Mars in June 2003, and its mapping over the martian disk using the same technique, during the southern spring (Ls=206°) when the global water vapor abundance was ∼10 pr. μm. The spatial distribution of H₂O₂ shows a maximum in the morning around the sub-solar latitude. The mean H₂O₂ column density (6×10¹⁵ cm⁻²) is significantly greater than our previous upper limit, pointing to seasonal variations. Our new result is globally consistent with the predictions of photochemical models, and also with submillimeter ground-based measurements obtained in September 2003 (Ls=254°), averaged over the martian disk (Clancy et al., 2004, Icarus 168, 116-121).     

Spatial patterns of suspended sediment yields in a humid tropical watershed in Costa Rica

An Erratum has been published for this article in Hydrological Processes 16(5) 2002, 1130–1131. Humid tropical regions are often characterized by extreme variability of fluvial processes. The Rio Terraba drains the largest river basin, covering 4767 km², in Costa Rica. Mean annual rainfall is 3139±419_sd mm and mean annual discharge is 2168±492_sd mm (1971–88). Loss of forest cover, high rainfall erosivity and geomorphologic instability all have led to considerable degradation of soil and water resources at local to basin scales. Parametric and non‐parametric statistical methods were used to estimate sediment yields. In the Terraba basin, sediment yields per unit area increase from the headwaters to the basin mouth, and the trend is generally robust towards choice of methods (parametric and LOESS) used. This is in contrast to a general view that deposition typically exceeds sediment delivery with increase in basin size. The specific sediment yield increases from 112±11·4_sd t km^?2 year^?1 (at 317·9 km² on a major headwater tributary) to 404±141·7_sd t km^?2 year^?1 (at 4766·7 km²) at the basin mouth (1971–92). The analyses of relationships between sediment yields and basin parameters for the Terraba sub‐basins and for a total of 29 basins all over Costa Rica indicate a strong land use effect related to intensive agriculture besides hydro‐climatology. The best explanation for the observed pattern in the Terraba basin is a combined spatial pattern of land use and rainfall erosivity. These were integrated in a soil erosion index that is related to the observed patterns of sediment yield. Estimated sediment delivery ratios increase with basin area. Intensive agriculture in lower‐lying alluvial fans exposed to highly erosive rainfall contributes a large part of the sediment load. The higher elevation regions, although steep in slope, largely remain under forest, pasture, or tree‐crops. High rainfall erosivity (>7400 MJ mm ha^?1 h^?1 year ^?1) is associated with land uses that provide inadequate soil protection. It is also associated with steep, unstable slopes near the basin mouth. Improvements in land use and soil management in the lower‐lying regions exposed to highly erosive rainfall are recommended, and are especially important to basins in which sediment delivery ratio increases downstream with increasing basin area. Copyright © 2001 John Wiley & Sons, Ltd.