Cosmic ray exposure ages for ureilites—New data and a literature study

We report newly measured noble gas isotopic concentrations of He, Ne, and Ar for 21 samples from the 10 ureilites, DaG 084, DaG 319, DaG 340, Dho 132, HaH 126, JaH 422, JaH 424, Kenna, NWA 5928, and RaS 247, including the results of both single and stepwise heating extractions. Cosmic ray exposure (CRE) ages calculated using model calculations that fully account for all shielding depths and a wide range of preatmospheric radii, and are tailored to ureilite chemistry, range from 3.7 Ma for Dho 132 to 36.3 Ma for one of several measured Kenna samples. In a Ne‐three‐isotope plot, the data for DaG 340 and JaH 422 plot below the Ne_cos/Ne_ureilite mixing envelope, possibly indicating the presence of Ne produced from solar cosmic rays. In combination with literature data and correcting for pairing, we established a fully consistent database containing 100 samples from 40 different ureilites. The CRE age histogram shows a trend of decreasing meteorite number with increasing CRE age. We speculate that the parent body of the known ureilites is moving closer to a resonance and/or that there is a loss mechanism that acts on ureilites independent of their size. In addition, there is a slight indication for a peak in the range 30 Ma, which might indicate a larger impact on the ureilite daughter body. Finally, we confirm earlier results that the majority of the studied ureilites have relatively small preatmospheric radii less or equal ~20 cm.     

Textural and compositional evidence for in situ crystallization of palisade bodies in coarse‐grained Ca‐Al‐rich inclusions

Palisade bodies, mineral assemblages with spinel shells, in coarse‐grained Ca‐, Al‐rich inclusions (CAIs) have been considered either as exotic “mini‐CAIs” captured by their host inclusions (Wark and Lovering 1982 ) or as in situ crystallization products of a bubble‐rich melt (Simon and Grossman 1997 ). In order to clarify their origins, we conducted a comprehensive study of palisade bodies in an Allende Type B CAI (BBA‐7), using electron backscatter diffraction (EBSD), micro‐computed tomography (Micro‐CT), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). New observations support the in situ crystallization mechanism: early/residual melt infiltrated into spinel‐shelled bubbles and crystallized inside. Evidence includes (1) continuous crystallography of anorthite from the interior of the palisade body to the surrounding host; (2) partial consolidation of two individual palisade bodies revealed by micro‐CT; (3) a palisade body was entirely enclosed in a large anorthite crystal, and the anorthite within the palisade body shows the same crystallographic orientation as the anorthite host; and (4) identical chemical and oxygen isotopic compositions of the constituent minerals between the palisade bodies and the surrounding host. Oxygen isotopic compositions of the major minerals in BBA‐7 are bimodal‐distributed. Spinel and fassaite are uniformly ¹⁶O‐rich with ?¹⁷O = ?23.3 ± 1.5‰ (2SD), and melilite and anorthite are homogeneously ¹⁶O‐poor with ?¹⁷O = ?3.2 ± 0.7‰ (2SD). The latter ?¹⁷O value overlaps with that of the Allende matrix (?¹⁷O ~ ?2.87‰) (Clayton and Mayeda 1999 ), which could be explained by secondary alteration with a ¹⁶O‐poor fluid in the parent body. The mobility of fluid could be facilitated by the high porosity (1.56–2.56 vol%) and connectivity (~0.17–0.55 vol%) of this inclusion.     

Factors Controlling Total Concentration and Aqueous Speciation of Aluminium in an Acidic Headwater Stream of the Bavarian Forest National Park: a Modelling Approach

The purpose of the present paper is to analyse factors controlling total concentration and aqueous speciation of aluminium in the Große Ohe River, using a thermodynamic equilibrium model and a mixing approach. A model compound for humic substances is derived on the basis of the relation between anion deficit and the organic carbon content in the river as well as literature data. An equilibrium speciation model for aluminium is set up, considering this model compound and relevant inorganic solutes. Although the model cannot be verified directly, its results may be viewed as qualitatively correct. Applying the model to measured stream water samples highlights that aqueous speciation of aluminium is mainly controlled by the pH value and discharge and that free aluminium concentrations reach clearly toxic levels during acidic episodes. Comparing measured concentrations of sulfate and H⁺ and calculated concentrations of Al³⁺ with solubility curves of gibbsite like minerals and jurbanite clearly shows that total aluminium concentrations are not controlled by equilibria with these mineral phases alone. The observed relationship can be better explained from a mixture of two distinct waters, representing lowflow and highflow chemistry, and the resulting equilibrium concentrations. This indicates that total aluminium concentration, in particular during high discharge events, is mainly controlled by the mixture of waters with differing chemistry and flowpaths.     

Vodyanitskii mud volcano,Sorokin trough,Black Sea: Geological characterization and quantification of gas bubble streams

Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to ∼650 mmol L⁻¹ at ∼150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at ∼60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (δD-CH₄ = −170.8‰ (SMOW), δ¹³C-CH₄ = −61.0‰ (V-PDB), δ¹³C-C₂H₆ = −44.0‰ (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 × 10⁶ mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.     

A new view of martian evolution

Conventional evolutionary models for Mars adopt a dry mantle solidus. Taking into account the condensation conditions in the preplanetary nebula in the accretion zone of Mars, it can be concluded that large amounts of water or hydrated silicates have condensed in those regions. Therefore, water influences significantly the melting behaviour and the viscosity of the silicatic material. A model for the calculation of the thermal history of a planet is constructed. On this basis, and use of water — saturated solidus — it is possible to derive that the core is not liquid, as given in models employing a dry mantle solidus, but solid to a large extent, which prevents the operation of a large-scale dynamo and explains in that way the lack of a magnetic field. With these assumptions one can construct a possible evolutionary scheme that covers early crust differentiation, a hot thermal past and the missing magnetic field at present.     

Acoustic backscatter and sediment textural properties of inner shelf sands,northeastern Gulf of Mexico

The relationship between spatial variations of the properties of sea-floor sediments and acoustic backscatter from the surface of the sea floor on the continental shelf off of Panama City, Florida, USA, is investigated using surficial sediment grab samples and digital side-scan sonar data. Acoustic backscatter strength has a high, direct correlation with the mean grain size of the sediments. Acoustic backscatter strength also correlates directly with the carbonate content of the sediments, particularly in medium-and coarse-sand facies, because large, irregularly shaped, carbonate particles affect both the mean grain size of the sediments and the roughness of the surface of the sea floor.     

The Aegir Rift: Crustal Structure of an Extinct Spreading Axis

Two seismic refraction and gravity lines were obtained along and normal to the axis of the Aegir Rift, an extinct spreading centre in the Norway Basin. Velocity-depth solutions and crustal structure models are derived from ocean-bottom records using two-dimensional ray tracing and synthetic seismogram modelling techniques. Gravity data are used to generate models consistent with the lateral variations in thickness of the layers in the crustal models. The resulting models require considerable degree of lateral inhomogeneity along and perpendicular to the rift axis. Crust within the extinct spreading centre is found to be thinner and of low P-wave velocity when compared with the crust sampled off-axis. To explain reduced velocities of the lower crust we suggest that, due to the relationship between fracturing and seismic velocity, the decreasing spreading rate leading up to extinction let the mechanically strong layer thicken, so that faulting and fracturing extended to greater depths . Low velocities are also observed in the uppermost mantle underlying the extinct spreading ridge. This zone is attributed to hydrothermal alteration of upper mantle peridotites. Furthermore, after spreading ceased 32-26 my ago, ongoing passive hydrothermal circulation was accompanied by the precipitation of alteration products in open void spaces, thereby decreasing the porosity and increasing the velocity. Consequently the typical low velocities of layer 2 found at active mid-ocean ridges have been replaced by values typical of mature oceanic crust.