Geospatial modelling of flood susceptibility pattern in a subtropical area of West Bengal,India

Flood hazards are the most destructive among all natural disasters and are a constant threat to human’s life and property. Effective disaster risk reduction strategies can be improved by geospatial approach in the way of producing information and knowledge that are useful to plan truly effective actions for the protection from floods. This research aims to develop a quantified predictive model of flood susceptibility in the Ghatal and Tamluk subdivision of Medinipur district of West Bengal, India, by means of empirically selected and weighted spatial predictors of flood. The weighted prediction model is used to quantify the spatial associations between individual geospatial factors within the flood inundated study area. Yule’s coefficient and distance distribution analysis are used to assign weights to individual geo-factors, and finally weighted spatial predictors are integrated to a multi-class index overlay analysis to derive the spatially explicit predictive model of flood susceptibility. The resultant susceptibility model reveals that approximately 32.35 and 52.99% of the total study areas (3261.45 km²) are under the category of high-to-moderate flood susceptible zone. Quantitative results of this study could be integrated into the policy process in the formulation of local and national government plans for the future flood mitigation management and also to develop appropriate infrastructure in order to protect the lives and properties of the common people of the Medinipur district.     

Characterization and prediction of stormwater runoff quality in sub-tropical rural catchments

Due to scarcity of local data on stormwater pollution levels and rainfall-runoff generation process, very few attempts have been made towards the management of stormwater in sub-tropical rural catchments. An attempt has been made in the present study to characterize and predict the stormwater runoff characteristics using regression modeling from five rural catchments in north-west India. Stormwater samples and flow data were collected from 75 storm events. Samples were analyzed for pH, total suspended solids (TSS), 5-day biochemical oxygen demand (BOD₅), chemical oxygen demand (COD), total kjeldhal nitrogen (TKN), total phosphorous (TP), nitrate-nitrogen (NO ₃ ^- –N), total coliform count (TC), fecal coliform count (FC), Zn, Cu and Fe. It was found that size of the catchment and the land use practices influenced the stormwater quality even in predominantly rural areas, otherwise thought to be homogeneous. The results obtained were related with the antecedent dry days (ADD) and average rainfall. ADD was found to be positively correlated with pollutant loads whereas average rainfall showed negative correlation. The study highlights the importance of ADD in causing greater mean pollutant concentrations except for TKN, TP and NO ₃ ^- –N. Regression models were developed for the studied catchments to estimate mean pollutant concentrations as a function of rainfall variables. Results revealed that measured pollutant concentrations demonstrated high variability with ADD and average rainfall in small rural catchments, whereas in large catchments, factors like land use, extent of imperviousness etc. resulted in low predictability of measured parameters.     

Thermal evolution of trans‐Neptunian objects,icy satellites,and minor icy planets in the early solar system

Numerical simulations are performed to understand the early thermal evolution and planetary scale differentiation of icy bodies with the radii in the range of 100–2500 km. These icy bodies include trans‐Neptunian objects, minor icy planets (e.g., Ceres, Pluto); the icy satellites of Jupiter, Saturn, Uranus, and Neptune; and probably the icy‐rocky cores of these planets. The decay energy of the radionuclides, ²⁶Al, ⁶⁰Fe, ⁴⁰K, ²³⁵U, ²³⁸U, and ²³²Th, along with the impact‐induced heating during the accretion of icy bodies were taken into account to thermally evolve these planetary bodies. The simulations were performed for a wide range of initial ice and rock (dust) mass fractions of the icy bodies. Three distinct accretion scenarios were used. The sinking of the rock mass fraction in primitive water oceans produced by the substantial melting of ice could lead to planetary scale differentiation with the formation of a rocky core that is surrounded by a water ocean and an icy crust within the initial tens of millions of years of the solar system in case the planetary bodies accreted prior to the substantial decay of ²⁶Al. However, over the course of billions of years, the heat produced due to ⁴⁰K, ²³⁵U, ²³⁸U, and ²³²Th could have raised the temperature of the interiors of the icy bodies to the melting point of iron and silicates, thereby leading to the formation of an iron core. Our simulations indicate the presence of an iron core even at the center of icy bodies with radii ≥500 km for different ice mass fractions.     

Effect of hot injections on electromagnetic ion-cyclotron waves in inner magnetosphere of Saturn

Encounter of Voyager with Saturn’s environment revealed the presence of electromagnetic ion-cyclotron waves (EMIC) in Saturnian magnetosphere. Cassini provided the evidence of dynamic particle injections in inner magnetosphere of Saturn. Also inner magnetosphere of Saturn has highest rotational flow shear as compared to any other planet in our solar system. Hence during these injections, electrons and ions are transported to regions of stronger magnetic field, thus gaining energy. The dynamics of the inner magnetosphere of Saturn are governed by wave-particle interaction. In present paper we have investigated those EMIC waves pertaining in background plasma which propagates obliquely with respect to the magnetic field of Saturn. Applying kinetic approach, the expression for dispersion relation and growth rate has been derived. Magnetic field model has been used to incorporate magnetic field strength at different latitudes for radial distance of \(6.18~R_{{s}}\) (\(1~R_{{s}}= 60{,}268~\mbox{km}\)). Various parameters affecting the growth of EMIC waves in cold bi-Maxwellian background and after the hot injections has been studied. Parametric analysis inferred that after hot injections, growth rate of EMIC waves increases till \(10^{\circ}\) and decreases eventually with increase in latitude due to ion density distribution in near-equatorial region. Also, growth rate of EMIC waves increases with increasing value of temperature anisotropy and AC frequency, but the growth rate decreases as the angle of propagation with respect to \(B_{0}\) (Magnetic field at equator) increases. The injection events which assume the Loss-cone distribution of particles, affect the lower wave numbers of the spectra.     

Robe’s problem: its extension to 2+2 bodies

In the problem of 2+2 bodies in the Robe’s setup, one of the primaries of mass m^*₁m^{*}_{1} is a rigid spherical shell filled with a homogeneous incompressible fluid of density ρ ₁. The second primary is a mass point m ₂ outside the shell. The third and the fourth bodies (of mass m ₃ and m ₄ respectively) are small solid spheres of density ρ ₃ and ρ ₄ respectively inside the shell, with the assumption that the mass and the radius of third and fourth body are infinitesimal. We assume m ₂ is describing a circle around m^*₁m^{*}_{1}. The masses m ₃ and m ₄ mutually attract each other, do not influence the motion of m^*₁m^{*}_{1} and m ₂ but are influenced by them. We also assume masses m ₃ and m ₄ are moving in the plane of motion of mass m ₂. In the paper, the equations of motion, equilibrium solutions, linear stability of m ₃ and m ₄ are analyzed. There are four collinear equilibrium solutions for the given system. The collinear equilibrium solutions are unstable for all values of the mass parameters μ,μ ₃,μ ₄. There exist an infinite number of non collinear equilibrium solutions each for m ₃ and m ₄, lying on circles of radii λ,λ′ respectively (if the densities of m ₃ and m ₄ are different) and the centre at the second primary. These solutions are also unstable for all values of the parameters μ,μ ₃,μ ₄, φ, φ′. Such a model may be useful to study the motion of submarines due to the attraction of earth and moon.     

Transition metals (Mn,Ni, Co) doping in TiO<Subscript>2</Subscript> nanoparticles and their effect on degradation of diethyl phthalate

Transition metal-doped TiO₂ nanoparticles are synthesized by sol–gel method. The as-prepared samples are characterized by various techniques to correlate structural and optical properties with chemical nature of dopants and their effect on photocatalytic degradation of diethyl phthalate esters. X-ray diffraction (XRD) reveals that all the samples are crystalline and exhibit anatase as a major phase. Chemical nature of dopants could not affect the formation of anatase and its volume fraction. The crystallite size of undoped and doped TiO₂ nanoparticles varies between 10 and 12 nm as confirmed by XRD and transmission electron microscope. The lowest optical band gap observed is 2.47 eV in Mn-doped TiO₂. Among all the samples, Ni-doped TiO₂ sample shows better photocatalytic activity and degradation of diethyl phthalate due to its lower crystallite size and higher surface area than those of Mn- and Co-doped TiO₂ samples.     

Release of Chromium from Soils with Persulfate Chemical Oxidation

An important part of the evaluation of the effectiveness of persulfate in situ chemical oxidation (ISCO) for treating organic contaminants is to identify and understand its potential impact on metal co‐contaminants in the subsurface. Chromium is a redox‐sensitive and toxic metal the release of which poses considerable risk to human health. The objective of this study was to investigate the impact of persulfate chemical oxidation on the release of chromium from three soils varying in physical‐chemical properties. Soils were treated with unactivated and activated persulfate [activated with Fe(II), Fe(II)‐EDTA, and alkaline pH] at two different concentrations (i.e., 41 mM and 2.1 mM persulfate) for 48 h and 6 months and were analyzed for release of chromium. Results show that release of chromium with persulfate chemical oxidation depends on the soil type and the activation method. Sandy soil with low oxidant demand released more chromium compared to soils with high oxidant demand. More chromium was released with alkaline pH activation. Alkaline pH and high Eh conditions favor oxidation of Cr(III) to Cr(VI), which is the main mechanism of release of chromium with persulfate chemical oxidation. Unactivated and Fe(II)‐activated persulfate decreased pH and at low pH in absence of EDTA chromium release is not a concern. These results indicate that chromium release can be anticipated based on the given site and treatment conditions, and ISCO system can be designed to minimize potential chromium release when treating soils and groundwater contaminated with both organic and metal contaminants.     

Metasomatism of ferroan granites in the northern Aravalli orogen,NW India: geochemical and isotopic constraints,and its metallogenic significance

The late Palaeoproterozoic (1.72–1.70 Ga) ferroan granites of the Khetri complex, northern Aravalli orogen, NW India, were extensively metasomatised ~900 Ma after their emplacement, at around 850–830 Ma by low-temperature (ca. 400 °C) meteoric fluids that attained metamorphic character after exchanging oxygen with the surrounding metamorphic rocks. Albitisation is the dominant metasomatic process that was accompanied by Mg and Ca metasomatism. A two-stage metasomatic model is applicable to all the altered ferroan intrusives. The stage I is represented by a metasomatic reaction interface that developed as a result of transformation of the original microcline–oligoclase (An_12–14) granite to microcline–albite (An_1–3) granite, and this stage is rarely preserved. In contrast, the stage II metasomatic reaction front, where the microcline-bearing albite granite has been transformed to microcline-free albite granite, is readily recognisable in the field and present in most of the intrusives. Some of them lack an obvious reaction interface due to the presence of stage II albite granites only. When studied in isolation, these intrusives were incorrectly classified and their tectonic setting was misinterpreted. Furthermore, our results show that the mafic mineralogy of metasomatised granites has a significant impact on the characterisation of such rocks in the magmatic classification and discrimination diagrams. Nevertheless, the stage I metasomatised granites can be appropriately characterised in these diagrams, whereas the characterisation of the stage II granites will lead to erroneous interpretations. The close spatial association of these high heat producing ferroan granites with iron oxide–copper–gold (IOCG), U and REE mineralisation in the region indicates a genetic link between the metasomatism and the mineralisation. World-class IOCG, U and REE deposits are associated with metasomatised ferroan granites, suggesting that such a relationship may act as a critical first-order exploration target for undiscovered mineral deposits.