Dolomitization of the Waulsortian Limestone (Lower Carboniferous) in the Irish Midlands

The Waulsortian Limestone (Lower Carboniferous) of the southern Irish Midlands is dolomitized pervasively over a much larger region than previous studies have documented. This study indicates a complex, multistage, multiple fluid history for regional dolomitization. Partially and completely dolomitized sections of Waulsortian Limestones are characterized by finely crystalline (0·01–0·3 mm) planar dolomite. Planar replacive dolomite is commonly followed by coarse (≥0·5 mm) nonplanar replacive dolomite, and pervasive void‐filling saddle dolomite cement is frequently associated with Zn–Pb mineralization. Planar dolomite has average δ¹⁸O and δ¹³C values (‰ PDB) of –4·8 and 3·9 respectively. These are lower oxygen and slightly higher carbon isotope values than averages for marine limestones in the Waulsortian (δ¹⁸O=–2·2, δ¹³C=3·7). Mean C and O isotope values of planar replacive dolomite are also distinct from those of nonplanar and saddle dolomite cement (–7·0 and 3·3; –7·4 and 2·4 respectively). Fluid inclusions indicate a complex history involving at least three chemically and thermally distinct fluids during dolomite cementation. The petrography and geochemistry of planar dolomites are consistent with an early diagenetic origin, possibly in equilibrium with modified Carboniferous sea water. Where the Waulsortian was exposed to hydrothermal fluids (70–280 °C), planar dolomite underwent a neomorphic recrystallization to a coarser crystalline, planar and nonplanar dolomite characterized by lower δ¹⁸O values. Void‐filling dolomite cement is isotopically similar to nonplanar, replacive dolomite and reflects a similar origin from hydrothermal fluids. This history of multiple stages of dolomitization is significantly more complex than earlier models proposed for the Irish Midlands and provides a framework upon which to test competing models of regional vs. localized fluid flow.     

Evidence for centennial-scale Lateglacial and early Holocene climatic complexity from Quoyloo Meadow,Orkney, Scotland

The influence of the North Atlantic on the margins of Europe means the region is particularly sensitive to changes in the ocean–atmospheric system. During the Last Glacial–Interglacial Transition (16–8 cal ka bp ) this system was repeatedly disrupted, leading to a series of abrupt and short-lived shifts in climate. Despite much research, the number and magnitude of these ‘centennial-scale’ events is not well understood. To address this, we expand upon investigations at Quoyloo Meadow, Orkney, Scotland, one of the best chronologically constrained palaeoclimate records in northern Britain. By coupling stable isotope and chironomid fossil analyses with existing data, this study identifies multiple phases of centennial-scale disturbance at: c. 14.0, 11.1, 10.8, 10.5, 10.45 and 10.3 cal ka bp , with the events at 14.0 and 10.3 exhibiting a particularly pronounced cold-climate signature. During the Holocene, the strongest response to climate forcing was at c. 10.3–10.0 cal ka bp , expressed as a two-stage drop in mean July temperatures, a shift in pollen spectra indicative of ‘less-stable’ climatic regimes, and a depletion in δ¹⁸O values. We interpret this as the first reliably dated incidence of the ‘10.3-ka event’ in the British Isles and consider the wider impact of this climatic reversal in other Holocene records.     

Armalcolite stability as a function of pressure and oxygen fugacity

The stability of synthetic armalcolite of composition (Fe_0.5Mg_0.5Ti₂O₅ was studied as a function of total pressure up to 15 kbar and 1200°C and also as a function of oxygen fugacity (?O₂) at 1200°C and 1 atm total pressure. The high pressure experiments were carried out in a piston-cylinder apparatus using silver-palladium containers. At 1200°C, armalcolite is stable as a single phase at 10 kbar. With increasing pressure, it breaks down ($\text{dT}\text{dP}\text{= 20°C/}\text{kbar}$), to rutile, a more magnesian armalcolite, and ilmenite solid solution. At 14 kbar, this three-phase assemblage gives way ($\text{dT}\text{dP}\text{= 30°C/}\text{kbar}$) to a two-phase assemblage of rutile plus ilmenite solid solution.A zirconian-armalcolite was synthesized and analyzed; 4 wt % ZrO₂ appears to saturate armalcolite at 1200°C and 1 atm. The breakdown of Zr-armalcolite occurs at pressures of 1–2 kbar less than those required for the breakdown of Zr-free armalcolite. The zirconium partitions approximately equally between rutile and ilmenite phases.The stability of armalcolite as a function of ?O₂ was determined thermogravimetrically at 1200°C and 1 atm by weighing sintered pellets in a controlled atmosphere furnace. Armalcolite, (Fe_0.5Mg_0.5)-Ti₂O₅, is stable over a range ?O₂ from about 10^?9.5to 10^?10.5 atm. Below this range to at least 10^?12.8 atm, ilmenite plus a reduced armalcolite are formed. These products were observed optically and by Mössbauer spectroscopy, and no metallic iron was detected; therefore, some of the titanium must have been reduced to Ti³⁺. This reduction may provide yet another mechanism to explain the common association of ilmenite rims around lunar armalcolites.     

Employment in retailing: A case study of employment in suburban shopping centres

There have been many studies of the retail industry in recent years, and of the impact that retailing has had on the spatial arrangement of urban areas and on consumer behaviour. Little attention has been paid, however, to employment in retailing, which is disturbing in view of its growing importance and its rapidly changing nature and composition. This paper examines the nature of the broad structural changes within the industry, and investigates their spatial consequences through a case study of employment generation within a system of suburban retail centres in Canberra, Australia. It is shown that the evolution of suburban centres, particularly those of a regional variety, has had an important and enriching impact on the suburban labour market. The regional centres are also seen to be the focus of the major structural employment changes currently affecting the retail industry. This has some important implications for urban planning.     

Plate and intraplate processes of Hercynian Europe during the late paleozoic

It is speculated that until Late Carboniferous time the region of Hercynian Europe was occupied by an elongated island arc system underlain by a segment of continental crust. In the Upper Carboniferous, two subduction zones are assumed to have extended from the north and south beneath Hercynian Europe. An extensive zone of hot, partially molten upper mantle lay above and between these, and diapiric uprise of portions of this material led to separation of mafic magmas, widespread partial melting in the lower and middle crust, high temperature-low pressure metamorphism in crustal rocks, and regional uplift and extension of the crust, as indicated by intermontane troughs and their associated volcanic rocks.In Visean to Westphalian time Hercynian Europe collided with both the large neighbouring plates North America-Europe and Africa. During these diachronous collisions and owing to reduced rigidity of the relatively hot island arc crust, the irregular continental margins of the larger and thicker continental plates induced oroclinal bending of Hercynian Europe. After the collision processes had been terminated, processes of upper mantle activity continued, causing further crustal uplift and even, enhanced crustal extension for several tens of million years into the Lower Permian. Decline of the upper mantle activity beneath Hercynian Europe is indicated by crustal subsidence and formation of a peneplain in Permian time followed by the Upper Permian transgression of both the Zechstein sea and the Tethys sea which mark the end of the Hercynian geodynamic cycle.     

Geospatial analysis between the environment and past incidences of West Nile virus in bird specimens in Ontario,Canada

Over recent years, the prevalence of the West Nile virus (WNV) in Canada has greatly increased due to various factors including changes in feeding behavior among WNV vectors. To understand whether changes in climate are a significant factor, the association between the environment and cases of WNV-infected bird specimens from 2009 to 2012 in Ontario, Canada, was examined using SAS and Quantum Geographic Information Systems (QGIS). Through a generalized linear mixed analysis, monthly totals of cooling degree days (CDD) and a two-way interaction between maximum temperature (Tmax) and precipitation were significantly positively associated to past incidences of WNV; while Tmax, precipitation, and a two-way interaction between CDD and precipitation were significantly negatively associated to past incidences of WNV. With the effects of increased warming, locations at higher latitudes in Canada may soon be at risk to WNV, as a positive case of WNV in a bird specimen was found close to the near north of Ontario in 2012.     

Shape and distribution analysis of Merensky Reef potholing, Northam Platinum Mine, western Bushveld Complex: implications for pothole formation and growth

Syn-magmatic removal of the cumulate pile during the formation of the Bushveld Complex resulted in “potholes”. Erosion progressed downward in the cumulate pile, resulting in a series of steep, transgressive contacts between locally conformable potholed reefs in the regional pothole sub-facies of the Swartklip Facies in the western limb of the Bushveld Complex. The deepest of these potholes, “third-order” or “FWP2” potholing, occurs where the base of the Merensky Cyclic Unit transgresses the Upper Pseudo-Reef Chromitite marker horizon. The base of a FWP2 pothole on Northam Platinum Mine consists of an unconformable stringer Merensky Chromitite overlain by a medium-grained, poikilitic orthopyroxenite and underlain by either a pegmatitic harzburgite or the medium-grained Lower Pseudo-Reef Anorthosite. Detailed shape and distribution analysis of FWP2 potholes reveals underlying patterns in their shape and distribution which, in turn, suggest a structural control. The ratio between pothole short vs long axes is 0.624 (N=1,385), although the ratio increases from 0.48 to 0.61 in the long axis range 10 to 60 m, then decreases from 0.61 to 0.57 from 61 to 100 m, increasing again from 0.57 to 0.61 from 101 to 400 m, suggesting that there is not a simple relationship between pothole shape and size. Shape (circularity, eccentricity, and dendricity) analysis of a subset of 638 potholes indicates that potholes with long axes <100 m have an elliptical, average normalized shape, elongate on a 120–150° orientation. Potholes with long axis lengths >100 m have an average normalized shape that is bilobate and elongate on a 120° orientation. The average aspect ratio (short axis length divided by long axis length) of potholes is highest for potholes with long axis lengths >100 m and lowest for potholes with long axis lengths between 35 and 60 m. The most common long axis orientation for potholes with long axis lengths <100 m is 150° but 120° for long axis lengths >100 m. Fractal analysis indicates that the distribution of pothole centers is controlled neither by a single nor several interacting fractal dimensions. Autocorrelation (Fry) analysis of the distribution of pothole centers shows recurring pothole distribution trends at 038, 070, and 110° for potholes over the full range of long axis lengths, while the trends of 008 and 152° occur in potholes with long axes lengths between 60 and 100 m. Chi-squared (X ²) analysis of the locations of pothole centers suggests that the distribution of small potholes is highly non-uniform but becomes exponentially more uniform with increasing pothole size. The model which best fits the observed shape and distribution analysis is a combination of protracted independent growth and “nearest neighbor” merging along specific orientations. For instance, the clustered distribution of original pothole centers resulted in merged potholes with long axes lengths of up to 60 m, exhibiting short vs long axes ratios of 0.61, preferred orientations of 150°, and alignment along 010 and 150° trends. Further independent growth allowed for merging of similar-sized (and smaller) neighboring potholes, generating potholes with long axes of up to 100 m in length, a preferred long axis orientation of 150°, and alignment along 010, 040, 075, and 150°. Subsequent preferential merging occurred along a 120° trend, thereby preserving a bilobate form. This implies that while pothole initiation and enlargement may be driven by a “top-down” (i.e., possibly thermomechanical) process, an underlying linear or structural catalyst/control is revealed in changes in pothole shape during enlargement and, furthermore, in the preferred trends along which potholes merged over a considerable period, possibly concomitant with adjustment of major structures in the footwall to the Bushveld Complex and pulses into the magma chamber.     

The compressibility of silicate liquids containing Fe2O3 and the effect of composition,temperature, oxygen fugacity and pressure on their redox states

Ultrasonic longitudinal acoustic velocities in oxidized silicate liquids indicate that the pressure derivative of the partial-molar volume of Fe₂O₃ is the same in iron-rich alkali-, alkaline earth- and natural silicate melt compositions at 1 bar. The dV/dP for multicomponent silicate liquids can be expressed as a linear combination of partial-molar constants plus a positive excess term for Na₂O−Al₂O₃ mixing. Partial-molar properties for FeO and Fe₂O₃ components allow extension of the empirical expression of Sack et al. (1980) to permit the calculation of Fe-redox equilibrium in a natural silicate liquid as a function of composition, temperature, fo₂ and pressure; a more formal thermodynamic expression is presented in the Appendix. The predicted equilibrium fo₂ of natural silicate melts, of fixed oxygen content, closely parallels that defined by the metastable assemblage fayalite+magnetite+β-quartz (FMQ), in pressure-temperature space. A silicate melt initially equilibrated at 3 GPa and FMQ, will remain within approximately 0.5 log₁₀ units of FMQ during its closed-system ascent. Thus, for magmas closed to oxygen, iron-redox equilibrium in crystal-poor pristine glassy lavas represents an excellent probe of the relative oxidation state of their source regions.