A 180 ka record of environmental change at Erdut (Croatia): a new chronology for the loess–palaeosol sequence and its implications for environmental interpretation

While there are numerous thick loess–palaeosol sequences preserved across the Carpathian Basin, well dated sites that provide terrestrial palaeoenvironmental records extending beyond last glacial–interglacial cycle are scarce. Robust chronologies are essential for correlations of loess with other long-term Quaternary records and to further understanding of the palaeoenvironment and climate of this important region beyond the last 125 ka. Here a new geochronology based on 13 post-infrared infrared stimulated luminescence ages focused on the lower part of the loess–palaeosol sequence at Erdut is presented. The results show that the lower part of the Erdut profile spans the penultimate glacial cycle (MIS 7 to MIS 5). The considerable sediments overlaying the investigated part of the profile suggest that this section spans two glacial cycles, rather than the previously suggested one. The most likely source of the discrepancy is the use of uncorrected infrared stimulated luminescence signal, which can cause age underestimation if not accounted for. This study demonstrates the need to revisit sites such as Erdut, re-date them using updated measurement protocols, and update existing palaeoenvironmental interpretations.     

Cosmochemical and spectroscopic properties of Northwest Africa 7325—A consortium study

This work is part of a project to build an infrared database in order to link IR data of planetary materials (and therefore possible Mercury material) with remote sensing observations of Mercury, which will probably be obtained by the MERTIS instrument on the forthcoming BepiColombo mission. The unique achondrite Northwest Africa (NWA) 7325, which has previously been suggested to represent the first sample from Mercury, was investigated by optical and electron microscopy, and infrared and Raman spectroscopy. In addition, the oxygen, strontium, xenon, and argon isotopes were measured and the abundance of selected trace elements determined. The meteorite is a cumulate rock with subchondritic abundances of HFSE and REE and elevated Sr contents, which underwent a second heating and partial remelting process. Oxygen isotope measurements show that NWA 7325 plots in the ureilite field, close to the ALM‐A trachyandesitic fragment found in the unique Almahata Sitta meteorite breccia. On the other hand, mineralogical investigations of the pyroxenes in NWA 7325 provide evidence for similarities to the lodranites and acapulcoites. Furthermore, the rock is weakly shocked and argon isotope data record ancient (~4.5 Ga) plateau ages that have not been reset. The sample records a cosmogenic exposure age of ~19 Ma. Systematics of Rb‐Sr indicate an extreme early volatile depletion of the precursor material, similar to many other achondrite groups. However, despite its compositional similarities to other meteorite groups, our results suggest that this meteorite is unique and unrelated to any other known achondrite group. An origin for NWA 7325 as a sample from the planet Mercury is not supported by the results of our investigation. In particular, the evidence from infrared spectroscopy indicates that a direct relationship between NWA 7325 and the planet Mercury can be ruled out: no acceptable spectral match between laboratory analyses and remote sensing observations from Mercury has been obtained. However, we demonstrate that infrared spectroscopy is a rapid and nondestructive method to characterize mineral phases and thus an excellent tool for planetary surface characterization in space missions.     

Verification of the RAMS-based operational weather forecast system in the Valencia Region: a seasonal comparison

Natural Hazards - The meteorological model Regional Atmospheric Modeling System (RAMS) in its version 4.4 has been applied operationally within the Valencia Region. The model output is being used...     

Suspended sediment in a wave field: Research note

Abstract

A series of photographs are presented that illustrate the ripple form and the kinematics of suspended sediment in a wave field. The strong shear on the local upstream side of the ripples and the subsequent vortex development on the downstream side is illustrated. Sediment is visible in the body of the fluid above the bed to a height equal to about one‐half the wavelength of the ripples.     

Stability Regions and Quasi-Periodic Motion in the Vicinity of Triangular Equilibrium Points

The regions of quasi-periodic motion around non-symmetric periodic orbits in the vicinity of the triangular equilibrium points are studied numerically. First, for a value of the mass parameter less than Routh's critical value, the stability regions determined by quasi-periodic motion are examined around the existing families of short (L^s ₄) and long (L^l ₄) period solutions. Then, for two values of μ greater than the Routh value, the unified family L^sl ₄, to which, in these cases, L^s ₄ and L^l ₄ merge, is considered. It is found that such regions surround in general the linearly stable segments of the corresponding families and become smaller as the mass ratio increases. This revised version was published online in July 2006 with corrections to the Cover Date.     

Masses of the local group and of the M81 group estimated from distortions in the local velocity field

Based on high precision measurements of the distances to nearby galaxies with the Hubble telescope, we have determined the radii of the zero velocity spheres for the local group, R₀ = 0.96±0.03Mpc, and for the group of galaxies around M 81/M 82, 0.89±0.05Mpc. These yield estimates of M_T = (1.29±0.14)· 10¹² M_⊙ and (1.03±0.17)· 10¹² M_⊙, respectively, for the total masses of these groups. The R₀ method allows us to determine the mass ratios for the two brightest members in both groups, as well. By varying the position of the center of mass between the two principal members of a group to obtain minimal scatter in the galaxies on a Hubble diagram, we find mass ratios of 0.8:1.0 for our galaxy and Andromeda and 0.54:1.00 for the M82 and M81 galaxies, in good agreement with the observed ratios of the luminosities of these galaxies. __________ Translated from Astrofizika, Vol. 49, No. 1, pp. 5–22 (February 2006).     

Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.     

Rotational atmospheric circulation during North Atlantic-European winter: the influence of ENSO

The dominant variability modes of the North Atlantic-European rotational flow are examined by applying a principal component analysis (PCA/EOF) to the 200?hPa streamfunction mid-winter anomalies (Jan?CFeb monthly means). The results reveal that, when this norm is used, the leading mode (EOF1) does not correspond to the traditional North Atlantic Oscillation (NAO, which appears in our analysis as the second leading mode, EOF2) but is the local manifestation of the leading hemispheric streamfunction EOF. The regression of this regional mode onto the global SST field exhibits a clear El Ni?o signature, with no signal over the Atlantic, while the associated upper height anomalies resemble the Tropical/Northern Hemisphere (TNH) pattern. East of North America, this TNH-like wavetrain produces a meridional dipole-like pattern at lower levels. Although in some ways this pattern resembles the NAO (EOF2), the dynamics of these two modes are very different in that only EOF2 is associated with a latitudinal shift of the North Atlantic stormtrack. Thus, the choice of the streamfunction norm in the EOF analysis allows the separation of two different phenomena that can produce similar dipolar surface pressure anomalies over the North Atlantic but that have different impact on European climate. These two modes also differ on their contribution to variability at lower levels: while NAO-EOF2 is mostly confined to the North Atlantic, TNH-EOF1 has a more annular, global character. At upper levels NAO-EOF2 also produces a global pattern but with no annular structure, reminiscent of the ??circumglobal?? teleconnection.     

Oil pollution of the anabranches of the Ob river on the territory of Khanty-Mansi Autonomous Okrug–Yugra

An analysis is made of the oil pollution of the Ob river waters using a long-term (1993–2013) hydrochemical monitoring of oil fields in Khanty-Mansi Autonomous Okrug. Contents of oil hydrocarbons (OHC) were determined in 4277 samples from the main Ob channel, and in 7076 samples from its anabranches by using infrared spectrometry. An increase in MAC (0.05 mg/dm³) was observed in 28% of the samples from the main channel, and in 32% from the anabranches. The total percentage of samples with an extremely high (> 50 MAC) and high (30–50 MAC) pollution level made up 0.3% of the samples for the anabranches, and 0.1% for the main channel. Maximum pollution was revealed in the eastern part of Okrug, from its eastern boundary to the mouth of the Trom’egan river which is associated with a considerable number of accidents on the pipelines within the Nizhnevartovskii district. The upper and lower quantiles in the most polluted anabranches, Pasl and Bagras, are 0.03–01.7 and 0.032–0.16 mg/dm³, respectively, whereas in the main Ob channel they vary from 0.022 to 0.065 mg/dm³ (0.4–1.2 MAC). The methods of geoinformatics and mathematical statistics were used to assess a dependence of OHC on the number of pollution sources (well clusters, and the area of oil spills) in zones at different distances from the river channels. By calculating the Spearman correlation coefficients, it was shown that OHC contents are dependent mainly on the number of wells, and on the area of oil spills located at less than 2 km from the channels.