Cobalt(II) interactions with near-coastal marine sediments

Chemical speciation of trace metals in aqueous systems is determined by a variety of competitive reactions. Sediments act as sinks for many trace elements, forming surface complexes and otherwise surface-related compounds. Reactions between dissolved trace metals and functional groups at sediment surfaces can be described as coordination reactions similar to those occurring in solution.Factors inherent to both sediment and solution influence the trace metal speciation. These factors include pH, type of mineral, surface area and/or density of reactive surface sites, complexing ligands, and competing ions. The relative importance of some of these factors was studied using an isotope dilution technique. Coastal sediment samples from the Gulf of Mexico were used as the solid matrix. Models developed for pure minerals were used here to (empirically) describe the complex assemblages of minerals in the natural sediment samples.The adsorption experiments showed that cobalt uptake by marine sediment samples followed a two-step time dependency. The initial fast step lasted about five to ten days and the subsequent slow step continued after more than 100 d of equilibration. The pseudoequilibrium reached during the fast step was modeled with an equilibrium model, while the twostep behavior was modeled with a time-dependent model. The two models are related by the reaction stoichiometries. It is believed that the experimental as well as the modeling approach taken in this study, although empirical when used for natural settings, is much more powerful than the use of traditional means to describe trace element interactions with natural solid phases.     

Depth distribution of Calanus finmarchicus and C. glacialis in relation to environmental conditions in the Barents Sea

Stage composition and vertical distribution of copepodids of Calanus finmarchicus and C. glacialis are described during spring and summer in Atlantic and Arctic waters, respectively. The two species co-occurred in the region of the Polar Front, both in moderate to high population densities. Ontogenetic migration, meaning that the migration range becomes progressively wider with advancing stage, was found in both species. The present study also revealed that C. finmarchicus had modifications in its ontogenetic vertical distribution. The standing crop of phytoplankton, predominantly Phaeocystis pouchetii , appeared to influence the degree of stage-specific segregation. Both low and high food concentrations tended to increase the vertical distribution of the instars. On the other hand, a narrow subsurface stratum of abundant phytoplankton led to an aggregation of copepodids at this depth. In the region of the Polar Front, where the two species co-occur, C. glacialis had a deeper distribution than C. finmarchicus , thus creating a bimodal vertical distribution pattern within the uppermost 200 m.     

Stable Isotopic Composition for Hydrothermal Vein Deposits, Southeastern Korea

The southeastof Korea has attracted considerable atten-tion in the geologic community because of its extensive ig-neous activity and associated mineralizations from the L ateCretaceous to the Early Tertiary (Cu,Pb- Zn,W- Mo,Bi andAu- Ag hydrotherm al- vein deposits,porphyry,skarn and al-tered clay deposits) .The southeast of Korea is composed ofCretaceous sedimentary Gyeongsan basin,volcanic and plu-tonic rocks.Most of the m ines are either closed or incapableof producing more ores becau…     

Nonlinear Finite Element Analysis of Ocean Cables

This study has focused on developing numerical procedures for the dynamic nonlinear analysis of cable structures subjected to wave forces and ground motions in the ocean. A geometrically nonlinear finite element procedure using the isoparamnetrie curved cable element based on the Lagrangian folmulation is briefly summarized. A simple and accurate method to determine the initial equilibrium state of cable systems associated with self-weights, buoyancy and the motion of end points is presented using the load incremental method combined with penalty method. Also the Newmark method is used for dynamic nonlinear analysis of ocean cables. Numerical examples are presented to validate the present numerical method.     

226Ra in phosphate nodules from the Peru/Chile seafloor

²²⁶Ra and other uranium-series radionuclides have been measured in a suite of marine phosphorite samples from the upwelling area off Peru/Chile by gamma-ray spectrometry and radiochemical techniques. Our results lead to the following conclusions: (1) phosphorite nodules typically show unidirectional growth at rates of 1 to 10 mm/Kyr; (2) very young samples (less than a few thousand years) contain slight excess amounts of ²²⁶Ra probably derived from pore fluids; and (3) slow but persistent leakage of ²²⁶Ra out of phosphate nodules occurs resulting in systematically lower ²²⁶Ra ages compared to ²³⁰Th ages for samples older than about twenty thousand years. Radium fluxes from these phosphate nodules appear to be 1 to 3 orders of magnitude less than those calculated for deep-sea sediments and ferromanganese nodules.     

Seismic stratigraphy and structural analysis of the northern East China Sea Shelf Basin interpreted from multi-channel seismic reflection data and cross-section restoration

Analysis of multi-channel seismic data from the northern East China Sea Shelf Basin (ECSSB) reveals three sub-basins (Socotra, Domi, and Jeju basins), separated by structural highs (Hupijiao Rise) and faulted basement blocks. These sub-basins show a typical rift-basin development: faulted basement and syn-rift and post-rift sedimentation separated by unconformities. Four regional unconformities, including the top of acoustic basement, have been identified and mapped from multi-channel seismic data. Faults in the acoustic basement are generally trending NE, parallel to the regional structural trend of the area. The depths of the acoustic basement range from less than 1000 m in the northwestern part of the Domi Basin to more than 4500 m in the Socotra Basin and 5500 m in the Jeju Basin. The total sediment thicknesses range from less than 500 m to about 1500 m in the northwest where the acoustic basement is shallow and reach about more than 5500 m in the south.Interpretation of seismic reflection data and reconstruction of three depth-converted seismic profiles reveal that the northern ECSSB experienced two phases of rifting, followed by regional subsidence. The initial rifting in the Late Cretaceous was driven by the NW-SE crustal stretching of the Eurasian Plate, caused by the subduction of the Pacific Plate beneath the Eurasian Plate. Extension was the greatest during the early phase of basin formation; estimated rates of extension during the initial rifting are 2%, 6.5%, and 3.5% in the Domi, Jeju, and Socotra basins, respectively. A regional uplift terminated the rifting in the Late Eocene-Early Oligocene. Rifting and extension, although mild, resumed in the Early Oligocene; while fluvio-lacustrine deposition continued to prevail. The estimated rates of extension during the second phase of rifting are 0.7%, 0.8%, and 0.5% in the Domi, Jeju, and Socotra basins, respectively. A second phase of uplift in the Early Miocene terminated the rifting, marking the transition to the post-rift phase of regional subsidence. Regional subsidence dominated the study area between the Early Miocene and the Late Miocene. An inversion in the Late Miocene interrupted the post-rift subsidence, resulting in an extensive thrust-fold belt in the eastern part of the area. Uplift and subsequent erosion were followed by regional subsidence.     

Fluid–structure interaction analysis of 3-D rectangular tanks by a variationally coupled BEM–FEM and comparison with test results

A variationally coupled BEM–FEM is developed which can be used to analyse dynamic response, including free-surface sloshing motion, of 3-D rectangular liquid storage tanks subjected to horizontal ground excitation. The tank structure is modelled by the finite element method and the fluid region by the indirect boundary element method. By minimizing a single Lagrange function defined for the entire system, the governing equation with symmetric coefficient matrices is obtained. To verify the newly developed method, the analysis results are compared with the shaking-table test data of a 3-D rectangular tank model and with the solutions by the direct BEM–FEM. Analytical studies are conducted on the dynamic behaviour of 3-D rectangular tanks using the method developed. In particular, the characteristics of the sloshing response, the effect of the rigidity of adjacent walls on the dynamic response of the tanks and the orthogonal effects are investigated. © 1998 John Wiley & Sons, Ltd.     

Nutrient budgets for European seas: a measure of the effectiveness of nutrient reduction policies

Socio-economic development in Europe has exerted increasing pressure on the marine environment. Eutrophication, caused by nutrient enrichment, is evident in regions of all European seas. Its severity varies but has, in places, adversely impacted socio-economic activities. This paper aims to evaluate the effectiveness of recently adopted policies to reduce anthropogenic nutrient inputs to European seas. Nitrogen and phosphorus budgets were constructed for three different periods (prior to severe eutrophication, during severe eutrophication and contemporary) to capture changes in the relative importance of different nutrient sources in four European seas suffering from eutrophication (Baltic Proper, coastal North Sea, Northern Adriatic and North-Western Black Sea Shelf). Policy success is evident for point sources, notably for P in the Baltic and North Seas, but reduction of diffuse sources has been more problematic.     

Rate of late Quaternary ice-cap thinning on King George Island, South Shetland Islands, West Antarctica defined by cosmogenic 36Cl surface exposure dating

Glacial landforms on the Barton and Weaver peninsulas of King George Island in the South Shetland Islands, West Antarctica were mapped and dated using terrestrial cosmogenic ³⁶Cl methods to provide the first quantitative terrestrial record for late Quaternary deglaciation in the South Shetland Islands. ³⁶Cl ages on glacially eroded and striated bedrock surfaces range from 15.5±2.5 kyr to 1.0±0.7 kyr. The ³⁶Cl ages are younger with decreasing altitude, indicating progressive downwasting of the southwestern part of the Collins Ice Cap at a rate of ∼12 mm yr⁻¹ since 15.5±2.5 kyr ago, supporting the previously published marine records for the timing and estimate of the rate of deglaciation in this region.     

Sensitivity analysis of extended TOPMODEL for agricultural watersheds equipped with tile drains

An extension of TOPMODEL was developed for rainfall–runoff simulation in agricultural watersheds equipped with tile drains. Tile drain functions are incorporated into the framework of TOPMODEL. Nine possible flow generation scenarios are suggested for tile-drained watersheds and applied in the modelling procedure. In the model development, two methods of simulation of the flow in the unsaturated zone were compared: the traditional, physically based storage approach and a new approach using a transfer function. A regionalized sensitivity analysis was used to determine the sensitivity of parameters and to compare the behaviour of the transfer function with that of the simple storage-related formulation. The number of accepted combinations of parameter values, on average, was higher for the transfer function approach than when using a Monte Carlo method of parameter estimation. Since the rainfall–runoff response pattern tends to vary seasonally, seven events distributed throughout a year were used in the sensitivity analysis to investigate the seasonal variation of the hydrological characteristics. © 1997 John Wiley & Sons, Ltd.