Marine-Derived Fungi in Korea

Ocean Science Journal - Studies on marine fungi (termed as ‘marine-derived fungi’ in this paper) have been significantly increasing worldwide because of the critical role displayed by...     

Mechanisms of nickel sorption by a bacteriogenic birnessite

A synergistic experimental-computational approach was used to study the molecular-scale mechanisms of Ni sorption at varying loadings and at pH 6-8 on the biogenic hexagonal birnessite produced by Pseudomonas putida GB-1. We found that Ni is scavenged effectively by bacterial biomass-birnessite assemblages. At surface excess values below 0.18 mol Ni kg⁻¹ sorbent (0.13 mol Ni mol⁻¹ Mn), the biomass component of the sorbent did not interfere with Ni sorption on mineral sites. Extended X-ray absorption fine structure (EXAFS) spectra showed two dominant coordination environments: Ni bound as a triple-corner-sharing (Ni-TCS) complex at vacancy sites and Ni incorporated (Ni-inc) into the MnO₂ sheet, with the latter form of Ni favored at high sorptive concentrations and decreased proton activity. In parallel to our spectral analysis, first-principles geometry optimizations based on density functional theory (DFT) were performed to investigate the structure of Ni surface complexes at vacancy sites. Excellent agreement was achieved between EXAFS- and DFT-derived structural parameters for Ni-TCS and Ni-inc. Reaction-path calculations revealed a pH-dependent energy barrier associated with the transition from Ni-TCS to Ni-inc. Our results are consistent with the rate-limited incorporation of Ni at vacancy sites in our sorption samples, but near-equilibrium state of Ni in birnessite phases found in nodule samples. This study thus provides direct and quantitative evidence of the factors governing the occurrence of Ni adsorption versus Ni incorporation in biogenic hexagonal birnessite, a key mineral in the terrestrial manganese cycle.     

中国东北地区中生代火山岩的大地构造意义

中国东北地区中生代火山岩可划分为西部大兴安岭环状火山岩带、南部火山岩带和东部火山岩带,它们是古亚洲洋构造域向太平洋构造域转换时期不同构造环境的产物。西部大兴安岭环状火山岩带的形成与古亚洲洋闭合过程中壳幔相互作用引起的深部热地幔柱的上升有关,南部火山岩带与构造域转换时期走滑拉伸构造有关,而东部火山岩带则是太平洋板块斜向俯冲作用的产物。     

A scattering-based over-land rainfall retrieval algorithm for South Korea using GCOM-W1/AMSR-2 data

Heavy summer rainfall is a primary natural disaster affecting lives and properties in the Korean Peninsula. This study presents a satellite-based rainfall rate retrieval algorithm for the South Korea combining polarization-corrected temperature (PCT) and scattering index (SI) data from the 36.5 and 89.0 GHz channels of the Advanced microwave Scanning Radiometer 2 (AMSR-2) onboard the Global Change Observation Mission (GCOM)-W1 satellite. The coefficients for the algorithm were obtained from spatial and temporal collocation data from the AMSR-2 and groundbased automatic weather station rain gauges from 1 July - 30 August during the years, 2012-2015. There were time delays of about 25 minutes between the AMSR-2 observations and the ground raingauge measurements. A new linearly-combined rainfall retrieval algorithm focused on heavy rain for the PCT and SI was validated using ground-based rainfall observations for the South Korea from 1 July - 30 August, 2016. The validation presented PCT and SI methods showed slightly improved results for rainfall > 5 mm h^-1 compared to the current ASMR-2 level 2 data. The best bias and root mean square error (RMSE) for the PCT method at AMSR-2 36.5 GHz were 2.09 mm h^-1 and 7.29 mm h^-1, respectively, while the current official AMSR-2 rainfall rates show a larger bias and RMSE (4.80 mm h^-1 and 9.35 mm h^-1, respectively). This study provides a scatteringbased over-land rainfall retrieval algorithm for South Korea affected by stationary front rain and typhoons with the advantages of the previous PCT and SI methods to be applied to a variety of spaceborne passive microwave radiometers.     

Effects of building-roof cooling on flow and air temperature in urban street canyons

The effects of building-roof cooling on flow and air temperature in 3D urban street canyons are numerically investigated using a computational fluid dynamics (CFD) model. The aspect ratios of the building and street canyon considered are unity. For investigating the building-roof cooling effects, the building-roof temperatures are systematically changed. The traditional flow pattern including a portal vortex appears in the spanwise canyon. Compared with the case of the control run, there are minimal differences in flow pattern in the cases in which maximum building-roof cooling is considered. However, as the building roof becomes cooler, the mean kinetic energy increases and the air temperature decreases in the spanwise canyon. Building-roof cooling suppresses the upward and inward motions above the building roof, resultantly increasing the horizontal velocity near the roof level. The increase in wind velocity above the roof level intensifies the secondarily driven vortex circulation as well as the inward (outward) motion into (out of) the spanwise canyon. Finally, building-roof cooling reduces the air temperature in the spanwise canyon, supplying much relatively cool air from the streamwise canyon into the spanwise canyon.     

On the role of Mn(IV) vacancies in the photoreductive dissolution of hexagonal birnessite

Photoreductive dissolution of layer type Mn(IV) oxides (birnessite) under sunlight illumination to form soluble Mn(II) has been observed in both field and laboratory settings, leading to a consensus that this process is a key driver of the biogeochemical cycling of Mn in the euphotic zones of marine and freshwater ecosystems. However, the underlying mechanisms for the process remain unknown, although they have been linked to the semiconducting characteristics of hexagonal birnessite, the ubiquitous Mn(IV) oxide produced mainly by bacterial oxidation of soluble Mn(II). One of the universal properties of this biogenic mineral is the presence of Mn(IV) vacancies, long-identified as strong adsorption sites for metal cations. In this paper, the possible role of Mn vacancies in photoreductive dissolution is investigated theoretically using quantum mechanical calculations based on spin-polarized density functional theory (DFT). Our DFT study demonstrates unequivocally that Mn vacancies significantly reduce the band-gap energy for hexagonal birnessite relative to a hypothetical vacancy-free MnO₂ and thus would increase the concentration of photo-induced electrons available for Mn(IV) reduction upon illumination of the mineral by sunlight. Calculations of the charge distribution in the presence of vacancies, although not fully conclusive, show a clear separation of photo-induced electrons and holes, implying a slow recombination of these charge-carriers that facilitates the two-electron reduction of Mn(IV) to Mn(II).