Micro- and nano-textural evidence of Ti(–Ca–Fe) mobility during fluid–rock interactions in carbonaceous lawsonite-bearing rocks from New Zealand

Understanding the mobility of chemical elements during fluid–rock interactions is critical to assess the geochemical evolution of a rock undergoing burial and metamorphism and, more generally, to constrain the geochemical budget of the subduction factory. In particular, determining the behavior and mobility of Ti in aqueous fluids constitutes a great challenge that is still under scrutiny. Here, we study plant fossils preserved in blueschist metasedimentary rocks from the Marybank Formation (New Zealand). Using scanning and transmission electron microscopies (SEM and TEM), we show that the carbonaceous material (CM) composing the fossils contains abundant nano-inclusions of Ti- and Fe-oxides. These nanocrystals are mainly anatase, rutile, and Fe–Ti oxides. The mineral composition observed within the fossils is significantly different from that detected in the surrounding rock matrix. We propose that Ti and Fe might have been mobilized by the alteration of a detrital Ti–Fe-rich protolith during an early diagenetic event under acidic and reducing conditions. Aqueous fluids rich in organic ligands released by the degradation of organic matter may have been involved. Moreover, using mass balance and petrological observations, we show that the contrasted mineralogy between the rock matrix and the fossil CM might be the consequence of the chemical isolation of fossil CM during the prograde path of the rock. Such an isolation results from the early formation of quartz and Fe-rich phyllosilicate layers enclosing the fossil as characterized by SEM and TEM investigations. Overall, this study shows that investigating minerals associated with CM down to the nanometer scale in metamorphic rocks can provide a precious record of early prograde geochemical conditions.     

Metasomatism and the crystallization of zircon megacrysts in Archaean peridotites from the Lewisian complex,NW Scotland

Zircon megacrysts are locally abundant in 1–40 cm-thick orthopyroxenite veins within peridotite host rocks in the Archaean Lewisian gneiss complex from NW Scotland. The veins formed by metasomatic interaction between the ultramafic host and Si-rich melts are derived from partial melting of the adjacent granulite-facies orthogneisses. The interaction produced abundant orthopyroxene and, within the thicker veins, phlogopite, pargasite and feldspathic bearing assemblages. Two generations of zircon are present with up to 1 cm megacrystic zircon and a later smaller equant population located around the megacryst margins. Patterns of zoning, rare earth element abundance and oxygen isotopic compositions indicate that the megacrysts crystallized from crustal melts, whereas the equant zircon represents new neocryst growth and partial replacement of the megacryst zircon within the ultramafic host. Both zircon types have U–Pb ages of ca. 2464 Ma, broadly contemporaneous with granulite-facies events in the adjacent gneisses. Zircon megacrysts locally form?>?10% of the assemblage and may be associated to zones of localized nucleation or physically concentrated during movement of the siliceous melts. Their unusual size is linked to the suppression of zircon nucleation and increased Zr solubility in the Si-undersaturated melts. The metasomatism between crustal melts and peridotite may represent an analog for processes in the mantle wedge above subducting slabs. As such, the crystallization of abundant zircon in ultramafic host rocks has implications for geochemistry of melts generated in the mantle and the widely reported depletion of high field strength elements in arc magmas.     

晚期海西运动在塔里木盆地北部油气藏形成中的作用

海西晚期，塔里木板块总体为挤压背景。有资料表明，该时期存在两次性质差异较大的构造运动：早二叠世末期和晚二叠世末期构造运动。前期运动以火山活动、海防变迁为特征；后期以沉积构造格局改变、褶皱、断裂活动为特征，并叠置于前期构造之上。晚期海西运动最终定型的古隆起控制了油气聚集指向，形成的古生代坳陷和中新代坳陷控制着油源区展布，造成了众多的、具有捕获油气能力的圈闭类型。断裂和区域性不整合面为油气运移提供了通道，而且对油气再分布及破坏亦有一定影响。     

富P过铝质岩浆体系的研究现状及存在的问题

高度演化的富P过铝质岩浆体系,具有鲜明的、不同于其他体系的地球化学行为.富P过铝质熔体以富P,高ASI,贫Fe、Mg、Ca,强烈亏损REE、Th、Y以及具有W、Sn、Nb、Ta等金属的矿化为特征.富P过铝质岩浆体系中的碱性长石为富P长石,长石中P可以有效地指示过铝质岩浆体系的演化历程;在岩浆演化的晚期,P与Li具强的亲和性,形成锂辉石-磷铝锂石-羟磷铝锂石的组合.已有的实验研究揭示,P能降低简单花岗岩的液相线和固相线温度、粘度以及增加H2O在熔体中的溶解度.然而,这一体系还存在许多问题亟待研究,P能否促进过铝质岩浆的液态不混溶,能否促使等价不相容元素在过铝质岩浆演化过程中的分异,是否在稀有金属成矿过程中起作用等都是值得关注的问题.     

煤的变质程度对焦炭结构构造的影响

从宏观和微观两方面对不同变质程度煤所形成焦炭的结构、构造进行了深入研究。从气煤到肥煤阶段（Ｒｏ，ｍ：０．７７％～１．１６％），焦炭气孔壁厚度逐渐增大；进入焦煤阶段（Ｒｏ，ｍ＞１．１６％），焦炭气孔壁厚度降低。气煤、１３焦煤形成的焦炭结构以各向同性体为主，焦煤、肥煤炼出的焦炭以粒状镶嵌结构为主。由气煤和高变质程度的焦煤形成的焦炭，其气孔以微孔和大孔为主，气孔分布标准差Ｄｓ最大；肥煤炼出的焦炭，其气孔分布大小较均一；１３焦煤和低变质程度的焦煤成焦后，气孔分布状况介于上述二者之间     

陕南泥岩三轴压缩蠕变试验及其数值模拟研究

在对泥岩进行室内三轴流变压缩蠕变试验的基础上,确定了泥岩Burgers流变模型本构方程中的各参数数值,描述了陕南勉宁地区泥岩的流变特征。结果表明:随着荷载的增加,泥岩出现明显的三个阶段的蠕变曲线,试块的总体蠕变量较大。利用FLAC3D软件对三轴压缩蠕变试验(围压1MPa)进行了模拟计算,确定泥岩计算机模拟时的流变计算参数。在此基础上,分别对泥岩不同围压和不同试件形态状态下的三轴压缩蠕变试验进行了数值模拟计算,结果表明:圆柱体试件的应变量数值整体小于立方体试验试件的应变量数值。     

银额盆地哈日凹陷油气成藏条件及成藏模式

近年来,银额盆地哈日凹陷的油气勘探呈现出良好的态势,但对于哈日凹陷油气成藏条件相关研究甚少,已不能满足目前油气勘探开发的需求。本研究基于钻录井、地球物理、分析化验等资料,系统分析哈日凹陷油气成藏的烃源岩、储层、圈闭等条件,总结油气成藏条件配置关系,以期为哈日凹陷的后续油气勘探及地质研究提供依据。哈日凹陷主要发育三套烃源岩,其中银根组烃源岩有机质丰度极高,成熟度较低,有机质类型为Ⅰ-Ⅱ1型;巴二段烃源岩有机质丰度较高,成熟-高成熟,有机质类型为Ⅱ1-Ⅱ2型;巴一段烃源岩有机质丰度中等,成熟-高成熟,有机质类型为Ⅱ1-Ⅱ2型。储层类型为砂（砾）岩常规储层、碳酸质泥岩非常规储层和火山岩储层,且均属于特低孔超低渗储层,其中砂、砾岩储层和灰质泥岩储层物性最好,白云岩储层和火成岩储层次之,目前主力油藏主要集中在砂、砾岩储层和灰质泥岩储层这两种类型中。哈日凹陷主要发育两套岩性圈闭,即巴一段砂岩岩性圈闭和巴二段泥岩岩性圈闭,形成了源内（准）连续成藏模式和近源不连续成藏模式。     

XEPOS型偏振能量色散X射线荧光光谱仪分析蒙古铁矿石

以熔融玻璃片和粉末压片制样,采用XEPOS型偏振能量色散X射线荧光光谱仪,建立了铁矿石中总铁、氧化钙、氧化镁、二氧化硅、三氧化二铝、硫、磷、铜等组分的快速分析方法。着重讨论硫、磷两元素测定的可行性和Lucas-Tooth、Price数学校正模型的适应性和改善方法的途径。     

Thermal conductivity measurements of road construction materials in frozen and unfrozen state

A series of thermal conductivity measurements for various materials was performed in a large climate chamber. The size of the chamber allowed the preparation of relatively large samples in a controlled thermal environment. Three types of thermal sensors were used: (1) two needle probes; (2) a grid of temperature sensors, evenly distributed inside the sample; (3) two additional thermal probes, which were simplified versions of an instrument originally developed for measuring thermal properties of the ice/dust mixture expected to exist at the surface of a comet nucleus. They consist of a series of individual temperature sensors integrated into a glass fibre rod. Each of these sensors can be operated in an active (heated) or passive (only temperature sensing) mode. The following sample materials were used: fine-grained reddish sand, coarse-grained moist sand, gravels with various grain size distributions from < 1 cm up to about 6 cm, and for comparison and calibration pure water (with convection suppressed by adding agar-agar), compact ice, and compact granite. Of particular interest are the measurements with composite samples, like stones embedded in an agar-agar matrix. We describe the evaluation methods and present the results of the thermal conductivity measurements.     

内陆河流域分布式日出山径流模型——以黑河干流山区流域为例

应用常规的气象水文数据并结合GIS,建立了一个适合西北干旱区内陆河山区流域的以日为步长的分布式径流模型,并对黑河干流山区出山径流进行了模拟计算和讨论。模型以子流域作为最小的产流、汇流单元,根据植被覆盖将各子流域分为裸地区、乔木区、牧草区和冰川区,并根据实际调查将土壤分为 3层,各分区单独进行水量平衡计算。产流过程以土壤储水能力和储水量表征,而储水能力和储水量等则由土壤的孔隙度、干密度和厚度等表征。入渗原理基于土壤储水率平衡原理,并考虑重力势的作用。实际蒸散发与蒸发力和土壤体积含水量的乘积成正比,不同的土壤和植被具有不同的调节参数。模拟结果表明,模拟效果较差的原因是区域日降水过程具有较大的随机性,难以用有限的站点合理计算区域日降水量。寻找一个合适的区域日降水量计算方法是目前少资料大型流域分布式水文模型模拟成功的关键。