Photocatalytic degradation of spill oils on TiO(2) nanotube thin films

The nitrogen-doped TiO(2) nanotube (N-TNT) thin films were synthesized using ZnO nanorods as the template and doped with urea at 623K. Under ultraviolet (UV) and visible light irradiation, the efficiencies for photocatalytic degradation of methylene blue is as high as 30%. About 10% of toluene (representing aromatics in the spill oils) in sea water can be photocatalytically degraded under visible light radiation for 120 min. The aliphatic model compound (1-hexadecene) has, on the contrary, a less efficiency (8%) on the N-TNT photocatalyst. On the average, under visible light radiation, the effectnesses of the N-TNT for photocatalytic degradation of model compounds in the spill oils in sea water are 0.38 mg toluene/gN-TNTh and 0.25 mg 1-hexadecene/gN-TNTh. It is expected that spill oils in the harbors or seashores can be adsorbed and photocatalytically degraded on the N-TNT thin films that are coated onto levee at the sea water surface level.     

In situ Pb‐Pb dating of silica‐rich Northwest Africa (NWA) 6594 basaltic eucrite and its constraint on thermal history of the Vestan crust

Eucrites represent one of the major lithologies of the Vestan upper crust, which had experienced pervasive and intense thermal metamorphism. To better constrain the timing and mechanism of thermal metamorphism, we carried out in situ Pb‐isotope analysis of an unbrecciated basaltic eucrite NWA 6594 on the basis of detailed mineralogical and petrographic investigations. Zircon Pb‐Pb dating reveals that NWA 6594 emplaced before or at 4547 ± 11 Ma (95% confidence, MSWD = 1.3). Studies of silica minerals indicate that NWA 6594 had experienced intense thermal metamorphism after emplacement, followed by a late impact reheating and rapid cooling. Apatite grains yield a weighted mean Pb‐Pb age of 4523 ± 2 Ma (95% confidence, MSWD = 0.76). This age could not be attributed to slow cooling after the initial crystallization, but most likely related to an independent thermal event that induced thermal metamorphism. The protracted time lag (~24 ± 13 Myr) between zircon and apatite closure ages indicates that this thermal event is most probably induced by an intense impact event that was synchronous with the metal–silicate mixing event recorded by mesosiderites. HEDs may have experienced multiple stages of thermal metamorphism after emplacement. The late impact reheating occurred after thermal metamorphism, which caused crystallization of tridymite.     

Stochastic seismic slope stability assessment using polynomial chaos expansions combined with relevance vector machine

This paper presents probabilistic assessment of seismically-induced slope displacements considering uncertainties of seismic ground motions and soil properties.A stochastic ground motion model representing both the temporal and spectral non-stationarity of earthquake shakings and a three-dimensional rotational failure mechanism are integrated to assess Newmark-type slope displacements.A new probabilistic approach that incorporates machine learning in metamodeling technique is proposed,by combining relevance vector machine with polynomial chaos expansions(RVM-PCE).Compared with other PCE methods,the proposed RVM-PCE is shown to be more effective in estimating failure probabilities.The sensitivity and relative influence of each random input parameter to the slope displacements are discussed.Finally,the fragility curves for slope displacements are established for sitespecific soil conditions and earthquake hazard levels.The results indicate that the slope displacement is more sensitive to the intensities and strong shaking durations of seismic ground motions than the frequency contents,and a critical Arias intensity that leads to the maximum annual failure probabilities can be identified by the proposed approach.     

Laboratory experiments on depression interfacial solitary waves over a trapezoidal obstacle with horizontal plateau

While shoaling from deep water in a stratified ocean, an internal wave may encounter different types of submarine topography. As it travels, the wave may generate vortex motion on a slope, turbulent mixing between the upper and bottom layer, and even waveform inversion on the plateau of a slope-shelf feature. Although many oceanographers have believed that the inversion from depression to elevation may commence at the turning point where the upper and low layer are equal in depth, this phenomenon has not been fully verified in field observations or numerical schemes. In order to clarify this unique phenomenon, a series of laboratory experiments were conducted on the evolution of an interfacial solitary wave of depression across a slope followed by a horizontal plateau on slope-shelf obstacle. Experimental results indicate the length of the plateau may become a proxy to determine whether the inverted waveform could maintain its strength or be weakened swiftly, which could inflict direct impact on the ecology of the local oceanic environment. Comparison on the internal flow field is also presented in this paper to illustrate the process of waveform inversion as an internal wave propagating over a trapezoidal, triangular ridge and uniform long slope, respectively.     

Spatio-temporal Slip, and Stress Level on the Faults within the Western Foothills of Taiwan: Implications for Fault Frictional Properties

We use preseismic, coseismic, and postseismic GPS data of the 1999 Chi-Chi earthquake to infer spatio-temporal variation of fault slip and frictional behavior on the Chelungpu fault. The geodetic data shows that coseismic slip during the Chi-Chi earthquake occurred within a patch that was locked in the period preceding the earthquake, and that afterslip occurred dominantly downdip from the ruptured area. To first-order, the observed pattern and the temporal evolution of afterslip is consistent with models of the seismic cycle based on rate-and-state friction. Comparison with the distribution of temperature on the fault derived from thermo-kinematic modeling shows that aseismic slip becomes dominant where temperature is estimated to exceed 200° at depth. This inference is consistent with the temperature induced transition from velocity-weakening to velocity-strengthening friction that is observed in laboratory experiments on quartzo-feldspathic rocks. The time evolution of afterslip is consistent with afterslip being governed by velocity-strengthening frictional sliding. The dependency of friction, μ, on the sliding velocity, V, is estimated to be ${{\partial \mu }/{\partial \, {\rm ln}\, V}} = 8 \times 10^{ - 3}$ . We report an azimuthal difference of about 10–20° between preseismic and postseismic GPS velocities, which we interpret to reflect the very low shear stress on the creeping portion of the décollement beneath the Central Range, of the order of 1–3 MPa, implying a very low friction of about 0.01. This study highlights the importance of temperature and pore pressure in determining fault frictional sliding.     

Comparison of capability of time integration methods in capturing dynamic loading

Numerical properties of the time integration method proposed by the first author of this paper in 2007 are the same as those of the constant average acceleration method (AAM) for linear elastic systems, except that the capability to capture dynamic loading was not explored. It was found that there were different quadrature equations to predict the next step displacement increment. A modified quadrature equation of this method was derived so that the equation to determine the next step displacement was numerically equivalent to the equation used in the constant AAM. It was verified that the original form of this method, in general, had a better capability to capture dynamic loadings than the constant AAM. This excellent property, in addition to computational efficiency, will help to make this method competitive with general secondorder accurate integration methods.     

Nonlinear pushover analysis of infilled concrete frames

Six reinforced concrete frames with or without masonry infills were constructed and tested under horizontal cyclic loads. All six frames had identical details in which the transverse reinforcement in columns was provided by rectangular hoops that did not meet current ACI specifications for ductile frames. For comparison purposes, the columns in three of these frames were jacketed by carbon-fiber-reinforced-polymer （CFRP） sheets to avoid possible shear failure. A nonlinear pushover analysis, in which the force-deformation relationships of individual elements were developed based on ACI 318, FEMA 356, and Chen＇s model, was carried out for these frames and compared to test results. Both the failure mechanisms and impact of infills on the behaviors of these frames were examined in the study. Conclusions from the present analysis provide structural engineers with valuable information for evaluation and design of infilled concrete frame building structures.     

Characteristics of the outer rise seaward of the Manila Trench and implications in Taiwan–Luzon convergent belt, South China Sea

The outer rise on the distal periphery of a subduction system is caused by emplacement of an accreted load onto the flexed oceanic lithosphere. By examining the bathymetry and free-air gravity anomaly data collected by satellite observations and marine reflection seismic data collected during the TAIGER project, we demonstrate the characteristics of the flexural outer rise seaward of the Manila Trench. The region of the outer rise on the westernmost periphery of the Manila subduction system is characterized by the positive free-air gravity anomaly seaward parallel to the Manila Trench and the morphological rise at the south of the Manila subduction system. A flexure simulation is performed based on the flexural profiles along the southern Manila Trench-outer system and the resulting effective elastic thickness values may provide an alternative aspect for the spreading rates of the South China Sea basin. Since both the western periphery of the Taiwan collision belt and Manila subduction belt are dominated by the strain regime of extension of flexural origin, it appears that the strain regime of flexural extension associated with the flexural forebulge of the Western Taiwan Foreland Basin to the north, and the strain regime of flexural extension associated with the outer rise seaward of the Manila Trench to the south are meridionally interconnected. This revised understanding of the strain regime of flexural extension origin west of the Taiwan–Luzon convergent belt provides an alternative point of view on the strain regime offshore SW Taiwan.     

利用重力资料精化大陆岩石圈热结构的理论模型

由于地表观测大地热流值的精度较低 ,并且测点分布不均匀 ,加之我们对地球内部介质热学参数随深度分布的了解也很模糊 ,因此 ,由通常解热传导方程获得的岩石层温度模型比较粗糙。本文提出一种利用重力异常资料精化传统的单纯依赖地热资料确定岩石层温度模型的方法 ,并对方法的有效性与局限性进行了讨论。