Measurements of solar occulation: the error in a naive retrieval if the constituent's concentration changes

The stratospheric concentrations of many minor constituents change rapidly at sunrise or sunset. If this happens, there is an inherent error when retrieving the vertical profiles of the constituents from measurements of their absorption of sunlight. For retrievals of NO at sunset the error can be estimated from in-situ measurements alone, without appeal to a model of stratospheric photochemistry. Below 20 km this error can approach 100% so that the retrieved NO is zero. But at 40 km, and at 25 km when the absorption is strong and Lorentzian, it can be less than 20%. Precise calculations of the error, even if small, require model calculations of the sunset and sunrise changes. With a model, we have calculated the error for NO, NO₂, OH and ClO.     

Condensed water in tropical cyclone “Oliver”, 8 February 1993

On February 8, 1993, the NASA DC-8 aircraft profiled from 10,000 to 37,000 feet (3.1–11.3 km) pressure altitude in a stratified section of tropical cyclone “Oliver” over the Coral Sea northeast of Australia. Size, shape and phase of cloud and precipitation particles were measured with a 2-D Greyscale probe. Cloud/ precipitation particles changed from liquid to ice as soon as the freezing level was reached near 17,000 feet (5.2 km) pressure altitude. The cloud was completely glaciated at −5°C. There was no correlation between ice particle habit and ambient temperature. In the liquid phase, the precipitation-cloud drop concentration was 4.0 × 10³ m⁻³, the geometric mean diameter D_g=0.5−0.7 mm, and the liquid water content 0.7−1.9 g m⁻³. The largest particles anywhere in the cloud, dominated by fused dendrites at concentrations similar to that of raindrops (2.5 × 10³ m⁻³) but a higher condensed water content (5.4 g m⁻³ estimated) were found in the mixed phase; condensed water is removed very effectively from the mixed layer due to high settling velocities of the large mixed particles. The highest number concentration (4.9 × 10⁴ m⁻³), smallest size (D_g=0.3−0.4 mm), largest surface area (up to 2.6 × 10² cm² m⁻³ at 0.4−1.0 g m⁻³ of condensate) existed in the ice phase at the coldest temperature (−40°C) at 35,000 feet (10.7 km). Each cloud contained aerosol (haze particles) in addition to cloud particles. The aerosol total surface area exceeded that of the cirrus particles at the coldest temperature. Thus, aerosols must play a significant role in the upscattering of solar radiation. Light extinction (6.2 km⁻¹) and backscatter (0.8 sr⁻¹ km⁻¹) was highest in the coldest portion of the cirrus cloud at the highest altitude.     

Element Mobility During Incipient Granulite Formation at Kabbaldurga, Southern India

At Kabbaldurga, infiltration of carbonic fluids along a systemof ductile shears and foliation planes has led to partial transformationof Archaean grey biotite–hornblende gneiss to coarse-grainedmassive charnockite at about 2.5 b.y. ago. The dehydration ofthe gneiss assemblage was induced by a marked metasomatic changeof the reacting system from granodioritic to granitic, and obviouslytook place under conditions of an open system at 700–750?C and 5–7 kb. Extensive replacement of plagioclase (An_16–30)by K-feldspar through Na, Ca–K exchange reactions withthe ascending carbonic fluids led to strong enrichment in K,Rb, Ba, and SiO₂, and to a depletion in Ca. Progressive dissolutionof hornblende, biotite, magnetite, and the accessory mineralsapatite and zircon resulted in a marked depletion in Fe, Mg,Ti, Zn, V, P, and Zr. Most important is the recognition of REEmobility: with advancing charnockitization, the moderately fractionatedREE distribution patterns of the grey gneisses (La_N270; La_N/Yb_N= 5–20; Eu_N27; Eu/Eu^* = 0.6–0.3) give way to stronglyfractionated REE patterns with a positive Eu-anomaly (La_N200;La_N/Yb_N = 20–80; Eu_N22; Eu/Eu^* = 0.6–1.8). The systematicdepletion especially in the HREE is due to the progressive dissolutionof zircon, apatite (and monazite), which strongly concentratethe REE. Stable isotope data (¹⁸O of 6.9–8.0 per mille for gneissesand charnockites; ¹³C of –8.5 and –6.5 per millefor late carbonate) indicate a magmatogenic source for the carbonicfluids. In contrast to the currently favoured derivation ofcarbonic fluids by decarbonation of the upper mantle or degassingof underplated basaltic intrusions, it is discussed here thatabundant fluid inclusions in lower crustal charnockites providedan extensive reservoir of ‘fossil’ carbonic fluids.Shear deformation has tapped this reservoir and generated thechannel-ways for fluid ascent. Charnockitization of the Kabbaldurgatypethus appears to be a metasomatic process which is tectonicallycontrolled and restricted to the crustal level of the amphiboliteto granulite transition.     

Large-scale farming as a cultural dilemma in U.S. rural development— The role of capital

Although agressive economic traditions have benefited U.S. agricultural fortunes enormously in the past, expanding farming scale now also seriously threatens equally-prized rural traditions extolling the values of family farming. To see in detail how strongly and in what ways large-scale farming is exerting its influence across the nation, a multivariate model was applied to county census data. Emphasized were forces of capital accumulation rather than traditional single criteria like farm size or incorporation. Results uniformly dispute the argument for continued vigor of the family farm. Smaller operators are not only disadvantaged in all production factors, but also are no longer protected by such traditional recourses as labor intensification and production efficiency. Far more farmers are also subjected to large-scale farming pressures well beyond the “factory farm” areas, and in several places to pressures as intense. One of these centers is the Western Corn Belt, a bastion of both technology and rural tradition, and thus quite possibly the place where the foremost dilemma in American agriculture is finally resolved.     

Tectono-thermal modeling of the Yinggehai Basin,South China Sea

Based on the observed data, the average value of surface heat flow in the Yinggehai Basin is calculated and it turns out to be 84.1 mW/m². The thermal evolution of the basin since the Cenozoic era has been attempted by tectono-thermal modeling. Three-phase extension made the basin become hotter and hotter, reaching its climax in paleo-temperature history since 5.2 Ma. And nowadays, the basin is in the heat flow decreasing period. During the Cenozoic era, the basement heat flow remained at 50–70 mW/m² all the time. This is related to the degree of each extension phase, stretching rate mode and also the limited basin scale. Modeling results also show that, the surface heat flow is controlled mainly by the basement heat flow, and less than 20% comes from radiogenic heat production in the sediments of the basin     

Iodine concentrations of soils near Trabzon, Turkey: a region of endemic goiter

Iodine contents of soils developed over the major rock formations of the northern zone of the Eastern Pontide Tectonic Belt (Northeastern Turkey) have been investigated with respect to soil-parent rock relationship, effect of topography, elevation, and climate to construe its effect on the health of the local population. Samples were collected from the A and B horizons of the soils developed over the major stratigraphic units constituting the eastern Pontides, including the Lower Basic Complex of Jurassic-Lower Cretaceous age, the Berdiga limestone (Jurassic-lower Cretaceous), the Dagbasi granitoid (Upper Cretaceous), volcano-sedimentary sequence of Upper Cretaceous age, ore-bearing and barren dacites of Upper Cretaceous age, and Neogene alkaline basalts. Chemical analyses of soil samples indicate significantly lower iodine abundances for all the soils studied (5–28 ppm) in comparison to the average abundance of iodine in analogous soils of other parts of the world (22–93 ppm). The concentration of iodine in soils developed over the same geologic formation decrease with increasing elevation. In certain cases, this decrease may reach up to 70%. Goiter is highly common throughout this region in Turkey. The results of this study suggest that the iodine deficiency of region’s soils may be a principal underlying cause for this area of Turkey being an endemic goiter region.