对饱和粘性土渗透规律的新认识及其应用

通过实验，对饱和粘性土的渗透规律进行研究，得到几点新认识。利用此认识建立了饱和粘性土越流补给量的计算公式，并在实际应用中得到验证。     

Lamproitic Rocks from a Continental Collision Zone: Evidence for Recycling of Subducted Tethyan Oceanic Sediments in the Mantle Beneath Southern Tibet

Major and trace element, Sr–Nd–Pb isotope and mineralchemical data are presented for newly discovered ultrapotassiclavas in the Tangra Yumco–Xuruco graben in southern Tibet.The ultrapotassic lavas are characterized by high MgO, K₂O andTiO₂, low Al₂O₃ and Na₂O contents, and also have high molarK₂O/Al₂O₃, molar (K₂O + Na₂O)/Al₂O₃ and K₂O/Na₂O ratios. Theirhigh abundances of incompatible trace elements such as largeion lithophile elements (LILE) and light rare earth elements(LREE) reach the extreme levels typical of lamproites. The lamproitesshow highly radiogenic ⁸⁷Sr/⁸⁶Sr (0· 7166–0·7363) and unradiogenic ¹⁴³Nd/¹⁴⁴Nd (0· 511796–0·511962), low ²⁰⁶Pb/²⁰⁴Pb (18· 459–18· 931),and elevated radiogenic ²⁰⁷Pb/²⁰⁴Pb (15· 6732–15·841) and ²⁰⁸Pb/²⁰⁴Pb (39· 557–40· 058) ratios.On the basis of their geochemical and isotopic systematics,the lamproites in south Tibet have a distinct magma source thatcan be differentiated from the sources of potassic lavas inthe east Lhasa and Qiangtang blocks. Their high Nb/Ta ratios(17· 10–19· 84), extremely high Th/U ratios(5· 70–13· 74) and distinctive isotope compositionsare compatible with a veined mantle source consisting of partialmelts of subducted Tethyan oceanic sediments and sub-continentallithospheric depleted mantle. Identification of the lamproitesand the delineation of their mantle source provide new evidencerelevant for models of the uplift and extension of the Tibetanplateau following the Indo-Asia collision. Metasomatism by partialmelts from isotopically evolved, old sediment subducted on theyoung Tethyan slab is an alternative explanation for PrecambrianNd and Pb model ages. In this model, differences in isotopiccomposition along-strike are attributed to differences in thetype of sediment being subducted, thus obviating the need formultiple metasomatic events over hundreds of million years.The distribution of lamproites, restricted within a north–south-trendinggraben, indicates that the initiation of east–west extensionin south Tibet started at 25 Ma. KEY WORDS: lamproites; subducted oceanic sediment; Tibetan active continental collision belt     

成都平原区水稻土成土剖面Cd形态分布特征及影响因素研究

成土过程中不同形态镉(Cd)迁移转化的影响因素研究对于了解Cd的地球化学行为具有非常重要的意义。以四川省成都平原区农田生态系统水稻土剖面中不同形态Cd分布特征为例,探讨成土过程中不同形态Cd的迁移转化影响因素及其生态危害性。结果表明:总量Cd、离子交换态Cd和碳酸盐Cd均表现出表层富集,深层含量稳定的特征;岷江流域和沱江流域水稻土Cd含量的背景值分别为0.147,0.215mg·kg-1。外源输入耕层土壤中Cd主要为活动态,其增加量占Cd总量增加量的60.71%~90.52%,向下垂向迁移能力非常弱。成土过程随着土壤中Cd总量增加,稳定态Cd含量显著增加,而活动态Cd含量明显降低。土壤的pH值主要对碳酸盐态Cd含量有影响,pH值越大,其含量越高;随着土壤成熟度增高,粉粒和粘粒含量增加的同时,残渣态Cd含量显著降低,而有机结合态Cd含量显著增高。耕层土壤中Cd的生物有效性系数高达0.59~0.65,已经严重地影响到农作物安全。     

利用重磁资料研究深部构造与金矿成矿关系

本文探讨了在山西省利用区域重磁资料研究深部构造与金矿成矿的关系及成矿环境的有利标志。研究结果表明，山西省的区域重、磁场以北东、北北东向为特点，中太古界为主要磁源层。根据磁场特征．用统计方法可将前寒武纪构造分为若干隆起和断陷，它们对金矿成矿起到了一定控制作用。另外，利用区域重力资料计算了山西省莫霍面深度，结果表明，莫霍面由东南向北西逐渐变深，莫霍面和岩石圈的结构控制了不同类型岩浆岩的展布，为选择金矿成矿有利地区提供了依据。并提出叠加型异常是重要的找矿靶区。     

溴邻苯三酚红-丁基罗丹明B高灵敏分光光度法测定微量钛的研究

在乳化剂ＯＰ和聚乙烯醇ＰＶＡ－１２４存在下,于０．０２ｍｏｌ／ＬＨ２ＳＯ４介质中,Ｔｉ（Ⅳ）与溴邻苯三酚红（ＢＰＲ）和丁基罗丹明Ｂ（ＢＲＢ）产生高灵敏协同显色反应。配合物λｍａｘ＝５９６ｎｍ,ε为１．５０×１０５Ｌ·ｍｏｌ－１·ｃｍ－１,钛的质量浓度在０～４８０μｇ／Ｌ符合比尔定律,配合物的组成为ｎＴｉ∶ｎＢＰＲ∶ｎＢＲＢ＝１∶２∶２。考察了共存离子的干扰情况。结合阴离子交换树脂分离富集,方法用于地质样品中微量钛的测定,结果与标准值相符,其ＲＳＤ（ｎ＝５）小于２％。     

秦巴地区砂金矿的分布及富集规律

本文通过对秦巴陕、甘、川、豫、鄂五省已知砂金矿床资料的整理和综合,简要的总结了区内砂金矿床的成因,形态类型,不同类型砂金矿床的地质特征及砂金矿的富集规律。对砂金矿的普查找矿工作有一定的指导意义。     

Common Pb of UHP metamorphic rocks from the CCSD project (100–5000 m) suggesting decoupling between the slices within subducting continental crust and multiple thin slab exhumation

In order to understand the vertical structure of the Dabie–Sulu ultrahigh-pressure metamorphic (UHPM) belt, common Pb isotopic compositions of omphacites in eclogites and feldspars in gneisses from the Chinese Continental Scientific Drilling (CCSD) project (100–5000 m) have been investigated in this study. Samples from 0 to 800 m (unit 1) in the drilling core have moderately high radiogenic Pb isotopes with small variations of ²⁰⁶Pb/²⁰⁴Pb (16.82–17.38), ²⁰⁷Pb/²⁰⁴Pb (15.37–15.49), and ²⁰⁸Pb/²⁰⁴Pb (37.21–37.72), indicating either high µ (²³⁸U/²⁰⁴Pb) or high initial Pb isotope ratios of their protoliths. In contrast, the samples from 1600 to 2040 m (unit 3) and most of samples from 3200 to 5000 m (unit 5) have moderately or very unradiogenic Pb (unit 3: ²⁰⁶Pb/²⁰⁴Pb from 16.05 to 16.46, ²⁰⁷Pb/²⁰⁴Pb from 15.22 to 15.29, and ²⁰⁸Pb/²⁰⁴Pb from 36.68 to 37.48; unit 5: ²⁰⁶Pb/²⁰⁴Pb from 15.52 to 15.69, ²⁰⁷Pb/²⁰⁴Pb from 15.15 to 15.27, and ²⁰⁸Pb/²⁰⁴Pb from 36.48 to 37.20), indicating either low µ or low initial Pb isotope ratios of their protoliths. Pb isotopes of samples from 800 to 1600 m (unit 2) and from 2040 to 3200 m (unit 4) in the drilling core with abundant ductile shear zones are intermediate between those of units 1 and 3 or 5 and display larger variations. Pb isotopes combined with the published oxygen isotope data of the CCSD samples reveal the original positions of the five units before the Triassic continental subduction. Units 1, 3, and 5 as three UHPM rock slabs could be derived from the subducted upper continental crust, upper–middle continental crust and lower–middle continental crust, respectively. The ductile shearing zones in units 2 and 4 could be the interfaces where the detachment and decoupling took place between the upper, upper–middle and lower–middle continental crusts. The detachment between the upper slab and subducting continental lithosphere probably occurred during continental subduction, and the upper slab (unit 1) was uplifted to a shallow depth along the detachment surface by thrusting. Units 3 and 5 may be detached later from the subducted middle and lower crust and uplifted to a shallow level underneath unit 1. The low δ¹⁸O values (? 4.0 to ? 7.4‰) [Xiao, Y.-L., Zhang, Z.-M., Hoefs, J., Kerkhof, A., 2006. Ultrahigh-pressure Metamorphic Rocks from the Chinese Continental Drilling Project-II Oxygen Isotope and Fluid Inclusion Distributions through Vertical Sections. Contribution Mineral Petrology 152, 443–458.; Zhang, Z.-M., Xiao, Y.-L., Zhao, X.-D., Shi, C., 2006. Fluid-rock interaction during the continental deep subduction: oxygen isotopic profile of the main hole of the CCSD project. Acta Petrologica Sinica 22 (7), 1941–1951.] in units 2 and 4 suggest that the detachment interfaces could be developed along an ancient fault zones which were the channels of meteoric water activity during the Neoproterozoic.     

胶莱盆地在南黄海的延伸:来自OBS深地震探测的新证据

为了识别胶莱盆地海阳凹陷在南黄海地区的东部延伸边界,利用穿越南黄海的OBS2013-SYS深地震测线开展2D速度结构模拟,在测线NW方向位于千里岩隆起带的OBS（海底地震仪）站位均观察到了折合走时突然增加的现象。速度结构模型显示胶莱盆地东侧海阳凹陷附近海域存在明显的低速沉积层增厚现象,模型自OBS06站位向NW方向,沉积层厚度由小于1.0 km显著增厚至2.5 km左右,推测该处为胶莱盆地海阳凹陷的东部边界断裂。结合前人在海阳凹陷识别出的控盆断裂进行分析,厘定了海阳凹陷在海区大体的构造边界和沉积中心,认为胶莱盆地东部控盆断裂可能延伸至连云港-石岛断裂一线,与嘉山-响水-千里岩断裂构成千里岩隆起带南北边界断裂带的一部分。海阳凹陷沉降中心可能位于南黄海海区连云港-石岛断裂北侧海阳凹陷的NE方向,发育的厚层白垩系可能存在较好的油气前景。     

320矿床成因和找矿方向

320矿床的含矿土岩是一套强烈硅化(角)砾状和(角)砾质岩,是地洼初动期岩溶洞穴沉(堆)积岩——以钙屑岩为主的混杂陆源沉积岩,受硅化形成。硅化主要发育于岩溶沉积岩中,并波及它附近的地层。这一事件发生于地洼余动期初,形成于低温环境,硅来自沉积岩源,流体起源于大气降水。320矿床是一个硅化改造的古岩溶矿床,它与美国亚利桑那州的硅化溶解-塌陷角砾岩筒相同。这类矿床在华南碳酸盐岩地区找矿潜力很大。     

黄骅坳陷港中复杂断块油气田富油砂体分布模式研究

滩坝砂是港中复杂断块油田沙一段重要储集层,滩砂和坝砂在砂体厚度及后期产能方面差异明显。为揭示港中油田富油砂体复杂的分布特征及控油模式,从动静态资料入手,逐次重点分析区内砂体、有效储层、油砂体的纵横向分布变化,引入并界定港中油田富油砂体概念、标准。研究认为,港中油田滩坝砂富油砂体具地质储量大,单井日产高,原始地层压力高、稳产时间长的特点。纵向上主要分布在板3油组和滨Ⅰ油组等5个主力单砂层,平面上主要分布在南四断块、北三断块。探讨了复杂断块油气田富油砂体分布受控因素及分布模式,指出沉积相控、成岩控油、断层控油、微构造控油及构造-岩性控油是港中油田滩坝砂油气富集5种主要控油模式。