Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.     

Interaction of wind and cold-season hydrologic processes on erosion from complex topography following wildfire in sagebrush steppe

Wildfire is a natural component of sagebrush (Artemisia spp.) steppe rangelands that induces temporal shifts in plant community physiognomy, ground surface conditions, and erosion rates. Fire alteration of the vegetation structure and ground cover in these ecosystems commonly amplifies soil losses by wind- and water-driven erosion. Much of the fire-related erosion research for sagebrush steppe has focused on either erosion by wind over gentle terrain or water-driven erosion under high-intensity rainfall on complex topography. However, many sagebrush rangelands are geographically positioned in snow-dominated uplands with complex terrain in which runoff and sediment delivery occur primarily in winter months associated with cold-season hydrology. Current understanding is limited regarding fire effects on the interaction of wind- and cold-season hydrologic-driven erosion processes for these ecosystems. In this study, we evaluated fire impacts on vegetation, ground cover, soils, and erosion across spatial scales at a snow-dominated mountainous sagebrush site over a 2-year period post-fire. Vegetation, ground cover, and soil conditions were assessed at various plot scales (8 m² to 3.42 ha) through standard field measures. Erosion was quantified through a network of silt fences (n = 24) spanning hillslope and side channel or swale areas, ranging from 0.003 to 3.42 ha in size. Sediment delivery at the watershed scale (129 ha) was assessed by suspended sediment samples of streamflow through a drop-box v-notch weir. Wildfire consumed nearly all above-ground live vegetation at the site and resulted in more than 60% bare ground (bare soil, ash, and rock) in the immediate post-fire period. Widespread wind-driven sediment loading of swales was observed over the first month post-fire and extensive snow drifts were formed in these swales each winter season during the study. In the first year, sediment yields from north- and south-facing aspects averaged 0.99–8.62 t ha⁻¹ at the short-hillslope scale (~0.004 ha), 0.02–1.65 t ha⁻¹ at the long-hillslope scale (0.02–0.46 ha), and 0.24–0.71 t ha⁻¹ at the swale scale (0.65–3.42 ha), and watershed scale sediment yield was 2.47 t ha⁻¹. By the second year post fire, foliar cover exceeded 120% across the site, but bare ground remained more than 60%. Sediment yield in the second year was greatly reduced across short- to long-hillslope scales (0.02–0.04 t ha⁻¹), but was similar to first-year measures for swale plots (0.24–0.61 t ha⁻¹) and at the watershed scale (3.05 t ha⁻¹). Nearly all the sediment collected across all spatial scales was delivered during runoff events associated with cold-season hydrologic processes, including rain-on-snow, rain-on-frozen soils, and snowmelt runoff. Approximately 85–99% of annual sediment collected across all silt fence plots each year was from swales. The high levels of sediment delivered across hillslope to watershed scales in this study are attributed to observed preferential loading of fine sediments into swale channels by aeolian processes in the immediate post-fire period and subsequent flushing of these sediments by runoff from cold-season hydrologic processes. Our results suggest that the interaction of aeolian and cold-season hydrologic-driven erosion processes is an important component for consideration in post-fire erosion assessment and prediction and can have profound implications for soil loss from these ecosystems. © 2019 John Wiley & Sons, Ltd.     

Choice chamber experiments to test the attraction of postflexion Rhabdosargus holubi larvae to water of estuarine and riverine origin

Although the recruitment of larvae and juveniles of marine fishes into estuaries has been well documented, little is known about the factors governing the immigration of estuary-associated marine fishes into estuaries. Fishes have a well-developed sense of smell and it has been suggested by several workers that olfactory cues of freshwater or estuarine origin serve as stimuli, attracting larvae and juveniles of estuary-associated species into estuaries. Attraction of postflexion Rhabdosargus holubi larvae to estuary and river water from the Kowie estuarine system, South Africa, was measured using a rectangular choice chamber. In experiments, conducted during peak recruitment periods, larvae selected estuary and river water with a significantly higher frequency than sea water. This study, the first to assess the possible role of olfaction in the recruitment process of an estuary-associated marine fish species, demonstrates that larvae are able to recognise water from different origins, probably based on odour.     

A review of human and natural changes in Maya Lowland wetlands over the Holocene

In the Maya Lowlands of Mexico, Belize, and Guatemala two main types of wetlands have played important roles in human history: bajos or intermittently wet environments of the upland, interior Yucatán and perennial wetlands of the coastal plains. Many of the most important Maya sites encircle the bajos, though our growing evidence for human–wetland interactions is still sparse. The deposits of these wetlands record two main eras of slope instability and wetland aggradation: the Pleistocene–Holocene transition as rainfall increased and forests eclipsed savannas and the Maya Preclassic to Classic as deforestation, land-use intensity, and drying increased. The ancient Maya adapted with terraces around these bajo margins but retracted in the Late Preclassic in some areas. The perennial wetlands of the coastal plains have different histories, and the first conceptual model of human–wetland interaction described intensive wetland agriculture in the Preclassic through Classic based on raised fields and canals. But a second model arose that interpreted the wetland stratigraphy and canals as more indicative of natural aggradation by accelerated erosion and gypsum precipitation that buried Archaic and Preclassic fields and there was little Classic era use. We present new data on a third and fourth model in this study. The third is a hybrid of the models one and two, including the Archaic to Preclassic aggradation of the second model, and the first model's Classic period fields and canals as piecemeal attempts by the Maya to adapt to these and other environmental changes. The fourth conceptual model describes a very Late/Terminal Classic, preplanned project on a floodplain. These wetland fields were short-lived, aggraded rapidly but with some reoccupation in the Postclassic. All of these new models display the burgeoning evidence for intricate Maya interactions with wetlands, and the diversity of evidence from the relatively few studies underscores the infancy of our understanding of Maya interaction with tropical wetlands.     

The Catalogue of the Vogtland/Western Bohemia Earthquakes and Vocatus as an Auxiliary Code

The catalogue of earthquakes from the Vogtland/Western Bohemia region joins data which have been observed with local seismic stations since 1962. Up to now, data on more than 17.000 earthquakes were compiled to the catalogue. A special code VOCATUS supports its use and explains the collected data. Both, catalogue and code VOCATUS are described. From the catalogue, there follows a recurrence of the earthquake occurrence which is discussed in detail.     

Dust tail streamers of a comet with rotating nucleus

Synthetic images of the dust tail are presented for a comet which has a rotating nucleus with one predominant dust source fixed to it. The images have been generated using a new computer model which, unlike similar models, allows for the study of dust tails caused by a rotating nucleus with an anisotropic distribution of sources.The dust tail is studied in the post-perihelion phase of a parabolic comet with a perihelion distance of 0.5 AU. One finds that in the case of a rotating nucleus with anisotropic emission characteristics streamers caused solely by the dynamics of the dust particles are forming in the dust tail even if there is no dependence between the solar irradiation angle of the source and the amount of dust emitted. If the dust emission depends on the solar irradiation angle of the dust source, then the brightest tail regions do not necessarily coincide with the synchrones for the times of maximum dust emission.As a consequence, a thorough analysis of streamer patterns in a cometary dust tail requires assumptions on the rotational state and the dust source distribution of the nucleus. Otherwise, it seems not possible to discern between streamers which are caused dynamically by nucleus rotation and others which reflect variations in the emission activity.     

The influence of the anomalous cosmic-ray component on the dynamics of the solar wind

It is well known that both the galactic and anomalous cosmic rays show positive intensity gradients in the outer heliosphere which are connected with corresponding pressure gradients. Due to an efficient dynamical coupling between the solar wind plasma and these highly energetic media by means of convected MHD turbulences, there exists a mutual interaction between these media. As one consequence of this scenario the enforced pressure gradients influence the distant solar wind expansion. Here we concentrate in our theoretical study on the interaction of the solar wind only with the anomalous cosmic-ray component. We use the standard two-fluid model in which the cosmic-ray fluid modifies the solar wind flow via the cosmic-ray pressure gradient. Then we derive numerical solutions in the following steps: first we calculate an aspherical pressure distribution for the anomalous cosmic rays, describing their diffusion in an unperturbed radial solar wind. Second, we then consider the perturbation of the solar wind flow due to these induced anomalous cosmic-ray pressure gradients. Within this context we especially take account of the action of a non-spherical geometry of the heliospheric shock which may lead to pronounced upwinddownwind asymmetries in the pressures and thereby in the resulting solar wind flows. As we can show in our model, which fits the available observational data, radial decelerations of the distant solar wind by between 5 to 11% are to be expected, however, the deviations of the bulk solar wind flow from the radialdirections are only slightly pronounced.