UV attenuation in the cloudy atmosphere

Ultraviolet (UV) energy absorption plays a very important role in the Earth–atmosphere system. Based on observational data for Beijing, we suggest that some atmospheric constituents utilize or transfer UV energy in chemical and photochemical (C&P) reactions, in addition to those which absorb UV energy directly. These constituents are primarily volatile organic compounds (VOCs) emitted from both vegetative and anthropogenic sources. The total UV energy loss in the cloudy atmosphere for Beijing in 1990 was 78.9 Wm⁻². This attenuation was caused by ozone (48.3 Wm⁻²), other compounds in the atmosphere (26.6 Wm⁻²) and a scattering factor (4.0 Wm⁻²). Our results for a cloudy atmosphere in the Beijing area show that the absorption due to these other compounds occurs largely through the mediation of water vapor. This fraction of energy loss has not been fully accounted for in previous models. Observations and previous models results suggest that 1) a cloudy atmosphere absorbs 25∼30 Wm⁻² more solar shortwave radiation than models predict; and 2) aerosols can significantly decrease the downward mean UV-visible radiation and the absorbed solar radiation at the surface by up to 28 and 23 Wm⁻², respectively. Thus, quantitative study of UV and visible absorption by atmospheric constituents involved in homogeneous and heterogeneous C&P reactions is important for atmospheric models.     

Estimation of Surface-Layer Scaling Parameters in the Unstable Boundary Layer: Implications for Orographic Flow Speed-Up

A method is proposed for estimating the surface-layer depth \((z_s)\) and the friction velocity \((u_*)\) as a function of stability (here quantified by the Obukhov length, L) over the complete range of unstable flow regimes. This method extends that developed previously for stable conditions by Argaín et al. (Boundary-Layer Meteorol 130:15–28, 2009), but uses a qualitatively different approach. The method is specifically used to calculate the fractional speed-up \((\varDelta S)\) in flow over a ridge, although it is suitable for more general boundary-layer applications. The behaviour of \(z_s \left( L\right) \) and \(u_*\left( L\right) \) as a function of L is indirectly assessed via calculation of \(\varDelta S\left( L\right) \) using the linear model of Hunt et al. (Q J R Meteorol Soc 29:16–26, 1988) and its comparison with the field measurements reported in Coppin et al. (Boundary-Layer Meteorol 69:173–199, 1994) and with numerical simulations carried out using a non-linear numerical model, FLEX. The behaviour of \(\varDelta S\) estimated from the linear model is clearly improved when \(u_*\) is calculated using the method proposed here, confirming the importance of accounting for the dependences of \(z_s\left( L \right) \) and \(u_*\left( L \right) \) on L to better represent processes in the unstable boundary layer.     

Characteristics of carbonyl compounds in ambient air of Shanghai,China

The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m⁻³ respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.     

Adaptation of Pressure Based CFD Solvers for Mesoscale Atmospheric Problems

General purpose Computational Fluid Dynamics (CFD) solvers are frequently used in small-scale urban pollution dispersion simulations without a large extent of ver- tical flow. Vertical flow, however, plays an important role in the formation of local breezes, such as urban heat island induced breezes that have great significance in the ventilation of large cities. The effects of atmospheric stratification, anelasticity and Coriolis force must be taken into account in such simulations. We introduce a general method for adapting pressure based CFD solvers to atmospheric flow simulations in order to take advantage of their high flexibility in geometrical modelling and meshing. Compressibility and thermal stratification effects are taken into account by utilizing a novel system of transformations of the field variables and by adding consequential source terms to the model equations of incompressible flow. Phenomena involving mesoscale to microscale coupled effects can be analyzed without model nesting, applying only local grid refinement of an arbitrary level. Elements of the method are validated against an analytical solution, results of a reference calculation, and a laboratory scale urban heat island circulation experiment. The new approach can be applied with benefits to several areas of application. Inclusion of the moisture transport phenomena and the surface energy balance are important further steps towards the practical application of the method.     

Vertical and Horizontal Transport of Energy and Matter by Coherent Motions in a Tall Spruce Canopy

In the framework of the EGER (ExchanGE processes in mountainous Regions) project, the contribution of coherent structures to vertical and horizontal transports in a tall spruce canopy is investigated. The combination of measurements done in both the vertical and horizontal directions allows us to investigate coherent structures, their temporal scales, their role in flux transport, vertical coupling between the sub-canopy, canopy and air above the canopy, and horizontal coupling in the sub-canopy layer. The temporal scales of coherent structures detected with the horizontally distributed systems in the sub-canopy layer are larger than the temporal scales of coherent structures detected with the vertically distributed systems. The flux contribution of coherent structures to the momentum and sensible heat transport is found to be dominant in the canopy layer. Carbon dioxide and latent heat transport by coherent structures increase with height and reach a maximum at the canopy height. The flux contribution of the ejection decreases with increasing height and becomes dominant above the canopy level. The flux fraction transported during the sweep increases with height and becomes the dominant exchange process at the upper canopy level. The determined exchange regimes indicate consistent decoupling between the sub-canopy, canopy and air above the canopy during evening, nighttime and morning hours, whereas the coupled states and coupled by sweep states between layers are observed mostly during the daytime. Furthermore, the horizontal transport of sensible heat by coherent structures is investigated, and the heterogeneity of the contribution of coherent events to the flux transport is demonstrated. A scheme to determine the horizontal coupling by coherent structures in the sub-canopy layer is proposed, and it is shown that the sub-canopy layer is horizontally coupled mainly in the wind direction. The vertical coupling in most cases is observed together with streamwise horizontal coupling, whereas the cross-stream direction is decoupled.     

Structural improvement of age-hardened gypsum-treated bauxite red mud waste using readily decomposable phyto-organics

Several years (7) after incidental lithification by added gypsum, the effect of crushing and phyto-organics on some physical properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into <2-mm particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the controls, as a >3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically treated samples. The increase in water infiltration by combining crushing with phyto-organic applications was ascribed to a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized channels and pores. Conversely, it was concluded that the singular crushing of gypsum-hardened bauxite waste in the waste dumps is potentially wasteful and ineffective.     

东海陆架盆地南部中生界沉积模式

在沉积相综合分析基础之上,通过地震相分析的手段明确了东海陆架盆地南部中生界的沉积特征;结合古地理背景分析,建立了该区侏罗纪和白垩纪的沉积模式。侏罗纪时雁荡低凸起和瓯江凹陷均未形成,闽江凹陷和基隆凹陷连为一体,物源来自浙闽隆起区,发育滨浅海沉积体系,火山作用较为强烈。白垩纪晚期-古新世,随着太平洋板块俯冲角度的加大,浙闽隆起区发生裂陷,雁荡低凸起形成。西部的瓯江凹陷沉积了一套陆相的冲积扇-河流-三角洲-湖泊沉积体系;由于此间台北低凸起尚未起到分割作用,东部的闽江凹陷与基隆凹陷仍然连为一体,物源来自浙闽隆起带和台北水下火山岩带,发育滨浅海沉积体系,火山作用影响强烈。     

Characteristics of dry-wet abrupt alternation events in the middle and lower reaches of the Yangtze River Basin and the relationship with ENSO

During recent decades, more frequent flood-drought alternations have been seen in China as a result of global climate change and intensive human activities, which have significant implications on water and food security. To better identify the characteristics of flood-drought alternations, we proposed a modified dry-wet abrupt alternation index (DWAAI) and applied the new method in the middle and lower reaches of the Yangtze River Basin (YRB-ML) to analyze the long-term spatio-temporal characteristics of dry-wet abrupt alternation (DWAA) events based on the daily precipitation observations at 75 rainfall stations in summer from 1960 to 2015. We found that the DWAA events have been spreading in the study area with higher frequency and intensity since 1960. In particular, the DWAA events mainly occurred in May and June in the northwest of the YRB-ML, including Hanjiang River Basin, the middle reaches of the YRB, north of Dongting Lake and northwest of Poyang Lake. In addition, we also analyzed the impact of El Niño Southern Oscillation (ENSO) on DWAA events in the YRB-ML. The results showed that around 41.04% of DWAA events occurred during the declining stages of La Niña or within the subsequent 8 months after La Niña, which implies that La Niña events could be predictive signals of DWAA events. Besides, significant negative correlations have been found between the modified DWAAI values of all the rainfall stations and the sea surface temperature anomalies in the Nino3.4 region within the 6 months prior to the DWAA events, particularly for the Poyang Lake watershed and the middle reaches of the YRB. This study has significant implications on the flood and drought control and water resources management in the YRB-ML under the challenge of future climate change.     

中国东部植被NDVI对气温和降水的时空响应(英文)

Temporal and spatial response characteristics of vegetation NDVI to the variation of temperature and precipitation in the whole year,spring,summer and autumn was analyzed from April 1998 to March 2008 based on the SPOT VGT-NDVI data and daily temperature and precipitation data from 205 meteorological stations in eastern China.The results indicate that as a whole,the response of vegetation NDVI to the variation of temperature is more pronounced than that of precipitation in eastern China.Vegetation NDVI maxi...     

基于快速流式算法的局部余弦相似属性

相似性是一种常用的衡量不同图像之间差异程度的属性,广泛应用于地震数据处理环节.由于地震数据本质上是非平稳的,局部相似性比全局相似性更适用于刻画地震数据的时-空变化特征.现有的局部相似属性可以通过正则化最小二乘问题进行计算,但是其计算过程需要大量的计算时间和数据存储空间,难以适应当前的海量数据处理任务.本文提出了一种基于快速流式算法的局部余弦相似性计算方法,其采取局部数据递推的模式,避免迭代算法带来的计算负担,在保证计算精度的前提下能够快速地表征不同数据之间的差异.流式局部余弦相似性可以用于解决不同的地震数据处理问题,包括叠前地震数据加权叠加、多波多分量数据纵横波速度比估计以及基于构造预测的断层检测,更加适用于现阶段的宽方位角和高密度采集数据的处理流程.理论模型和实际数据测试结果可以验证流式局部余弦相似性算法的效率优势和解决不同地震数据处理问题的有效性.