Preferred orientation of antiphase boundaries in pigeonite as a cooling ratemeter

Antiphase domains (APD's) of pigeonite lamellae in natural and heated augite crystals from the Hakonetoge andesite have been examined by a transmission electron microscope (TEM). Antiphase boundaries (APB's) of the pigeonite lamellae in natural specimens have a sigmoidal shape cutting the c axis in (010) sections. APB's in specimens heated at temperatures above the high-low inversion and then quenched are nearly parallel to the c axis with almost straight boundaries. These observations indicate that the preferred orientation of APB's in (010) sections depends on cooling rate; at fast colling rates the APB's are nearly parallel to the c axis, whereas at slower cooling rates they are inclined to the c axis. The cooling rate of the natural augite specimen from Hakonetoge is estimated to be about 0.01 °C/h from the experimentally determined time-temperature-transformation (TTT) diagram for the APB orientations. APD sizes are large in specimens quenched from above the inversion temperature; they are at a minimum after cooling rates of around 1–0.1 °C/h, and then become larger with slower cooling rates.     

Radium uptake during barite recrystallization at 23 ± 2 °C as a function of solution composition: An experimental Ba and Ra tracer study

High-purity synthetic barite powder was added to pure water or aqueous solutions of soluble salts (BaCl₂, Na₂SO₄, NaCl and NaHCO₃) at 23 ± 2 °C and atmospheric pressure. After a short pre-equilibration time (4 h) the suspensions were spiked either with ¹³³Ba or ²²⁶Ra and reacted under constant agitation during 120-406 days. The pH values ranged from 4 to 8 and solid to liquid (S/L) ratios varied from 0.01 to 5 g/l. The uptake of the radiotracers by barite was monitored through repeated sampling of the aqueous solutions and radiometric analysis. For both ¹³³Ba and ²²⁶Ra, our data consistently showed a continuous, slow decrease of radioactivity in the aqueous phase.Mass balance calculations indicated that the removal of ¹³³Ba activity from aqueous solution cannot be explained by surface adsorption only, as it largely exceeded the 100% monolayer coverage limit. This result was a strong argument in favor of recrystallization (driven by a dissolution-precipitation mechanism) as the main uptake mechanism. Because complete isotopic equilibration between aqueous solution and barite was approached or even reached in some experiments, we concluded that during the reaction all or substantial fractions of the initial solid had been replaced by newly formed barite.The ¹³³Ba data could be successfully fitted assuming constant recrystallization rates and homogeneous distribution of the tracer into the newly formed barite. An alternative model based on partial equilibrium of ¹³³Ba with the mineral surface (without internal isotopic equilibration of the solid) could not reproduce the measured activity data, unless multistage recrystallization kinetics was assumed. Calculated recrystallization rates in the salt solutions ranged from 2.8 × 10⁻¹¹ to 1.9 × 10⁻¹⁰ mol m⁻² s⁻¹ (2.4-16 μmol m⁻² d⁻¹), with no specific trend related to solution composition. For the suspensions prepared in pure water, significantly higher rates (∼5.7 × 10⁻¹⁰ mol m⁻² s⁻¹ or ∼49 μmol m⁻² d⁻¹) were determined.Radium uptake by barite was determined by monitoring the decrease of ²²⁶Ra activity in the aqueous solution with alpha spectrometry, after filtration of the suspensions and sintering. The evaluation of the Ra uptake experiments, in conjunction with the recrystallization data, consistently indicated formation of non-ideal solid solutions, with moderately high Margules parameters (W_AB = 3720-6200 J/mol, a₀ = 1.5-2.5). These parameters are significantly larger than an estimated value from the literature (W_AB = 1240 J/mol, a₀ = 0.5).In conclusion, our results confirm that radium forms solid solutions with barite at fast kinetic rates and in complete thermodynamic equilibrium with the aqueous solutions. Moreover, this study provides quantitative thermodynamic data that can be used for the calculation of radium concentration limits in environmentally relevant systems, such as radioactive waste repositories and uranium mill tailings.     

Strong motion uncertainty determined from observed records by dense network in Japan

The variation of ground motions at specific stations from events in six narrow areas was inspected by using K-NET and KiK-net records. A source-area factor for individual observation stations was calculated by averaging ratios between observed values for horizontal peak acceleration and velocity, as well as acceleration response spectra for 5% damping, and predicted values using a ground-motion model (usually known as an attenuation relation) by Kanno et al. (Bull Seismol Soc Am, 96:879–897, 2006). Standard deviations between observed and predicted amplitudes after the correction factor are less than 0.2 on the logarithmic scale and decrease down to around 0.15 in the short-period range. Intra-event standard deviation clearly increases with decreasing distance due to differing paths around near source area. Standard deviations may increase with amplitude or decrease with magnitude; however, both amplitude and magnitude of the data are strongly correlated with distance. The standard deviation calculated in this study is obviously much smaller than that of the original ground-motion model, as epistemic uncertainties are minimized by grouping ground motions at specific stations. This result indicates that the accuracy of strong ground motion prediction could be improved if ground-motion models for specified region are determined individually. For this to be possible, it is necessary to have dense strong-motion networks in high-seismicity regions, such as K-NET and KiK-net.     

Oxygen isotope fractionation factors between anhydrite and water from 100 to 550°C

Oxygen isotope exchange between anhydrite and water was studied from 100 to 550°C, using the partial equilibrium method. The exchange rate was extremely low in NaCl solution. In the lower-temperature range, acid solutions were used to produce sufficient reaction to determine the oxygen isotope fractionation factors. The fractionation factors obtained in the present study are definitely different from those given by Lloyd [8]. They are similar to those for the HSO₄^?-water system studied by Mizutani and Rafter [19], and are consistently 2‰ higher than those of the barite-water system by Kusakabe and Robinson [5]. The temperature dependence of the oxygen isotope fractionation factors was calculated by the least squares method in which the weight was taken to be inversely proportional to the experimental error. The fractionation is given by:10³lnαanhydrite-water=3.21×(10³/T)²?4.72Available δ¹⁸O values of natural anhydrite were used to test the validity of this expression. It is shown that this newly revised geothermometer can be successfully applied to natural hydrothermal anhydrite.     

Gravitational N-body problem on the accretion process of terrestrial planets

Numerical integration of the gravitational N-body problem has been carried out for a variety of photoplanetary clusters in the range N = 100 to 200. Particles are assumed to coagulate at collisions irrespective of relative velocity and mass ratio of the particles. It is shown graphically how the dispersed N-bodies accumulate to a single planet through mutual collisions. The velocity distribution and size distribution of bodies are also investigated as functions of time in the accretion process. The root mean square velocity of bodies in a cluster increases with time in an early stage of accretion but decreases with time in a late stage of accretion. Accretion rates of planets are found to be dependent strongly on the initial number density distribution, the initial size distribution, and the initial velocity distribution of bodies. Formation of satellites of about 10% in the planet mass is common to most cases in the present study. A substantial mass of bodies also escapes from the cluster. Many satellites and escapers formed during the accretion process of planets may be source materials of heavy bombardment in the early history of planets.     

X-ray observation of the Jovian impacts of comet Shoemaker - Levy 9

An ASCA observation of the Jovian impact of the comet Shoemaker-Levy 9 is reported. Four impacts of H, L, Q1 and R were observed and four impacts of B, C, G, and Q2 were observed within 60 minutes after their impacts. No significant flaring of X-ray emission was observed. Upper limit X-ray fluxes of 90 % confidence level, averaged 5 minutes just after the impacts, were 2.4 × 10^–13 erg sec^–1 cm^–2, 3.5 × 10^–13 erg sec^–1 cm^–2, 1.6 × 10^–13 erg sec^–1 cm^–2 and 2.9 × 10^–13 erg sec^–1 cm^–2 for the impacts of H, L, Q1 and R, respectively, in the 0.5(0.7 for H and Q1)–10 keV energy range. However, a hint of X-ray enhancement around Jupiter from July 17 to July 19 was detected with about 2 6 × 10^–14 erg sec^–1 cm^–2 in the 0.5–10 keV energy range.     

Surface roughness of alumina fragments caused by hypervelocity impact

Hypervelocity impact experiments are carried out with alumina ceramic targets at impact velocities of 2-4 km/s. The fractal dimension (or roughness exponent) of fragment surfaces is estimated by two different methods (different length scales). One is a divider method (large scale) and the other is a gas-absorption one (small scale). The obtained fractal dimensions are different: ∼2.2-2.4 for larger scale and ∼2.5-2.7 for smaller scale. These values are regardless of the degree of fragmentation.     

Impact fragmentation experiments of basalts and pyrophyllites

Results of impact fragmentation experiments for basalts and pyrophyllites are reported. Aluminum cylindrical projectiles were impacted on cubic basalt and pyrophyllite targets at velocities of 70 to 990 m/sec. The targets and projectiles were 20 g to 3.3 kg and 2 to 20 g in weight respectively. Weights of the fragments produced by impacts were measured and the size distributions of fragments were examined. Data of the largest fragment mass (m_L) normalized to the original target mass (M_t), m_L/M_t, correlate better with the nondimensional impact stress, P_I, a new scaling parameter introduced by H. Mizutani, Y. Takagi, and S. Kawakami (1984, in preparation) than the conventional projectile's kinetic energy per unit target mass, E/M_t, used in the previous studies. All the m_L/M_t data for basalts obtained in the present study are summarized by m_L/M_t = 2.95 × 10^?2P_I^?1 where P_I = P₀L³/YR³, P₀ = peak shock pressure, L = projectile size, R = target size and Y = material strength of target. For aluminum targets, however, the m_L/M_t is 2.5 orders of magnitude larger than that for brittle targets at impacts with the same P_I. Size distributions of fragments expressed in a log N - log (m/M_t) diagram divided into three regimes bounded by two inflection points. In each regime the curve is expressed by $\text{N (>}\text{m}\text{M}{}_{\mathrm{t}}\text{) = A (}\text{m}\text{M}{}_{\mathrm{t}}\text{)}{}^{\mathrm{?a}}$. The slopes, a, of the log $\text{N -}\text{log}\text{(}\text{m}\text{M}{}_{\mathrm{t}}\text{)}$ curves in the regimes of a large and a medium size range are positively correlated with the nondimensional impact stress, P_I, and expressed as a = C₃ + a₃log P_I. The slopes, a, in the smallest size range are, on the other hand, nearly constant and have values of $\text{0.5}\text{to}\text{0.7 (}\text{1}\text{2}\text{?}\text{2}\text{3}\text{)}$. Present results indicate that the impact fragmentation is scaled well by the new scaling parameter, P_I, of Mizutani, Takagi, and Kawakami and that the present experimental data may shed new light on planetary impact processes.     

Out‐of‐plane stability of buckling‐restrained braces including moment transfer capacity

Buckling‐restrained braces (BRBs) are widely used as ductile seismic‐resistant and energy‐dissipating structural members in seismic regions. Although BRBs are expected to exhibit stable hysteresis under cyclic axial loading, one of the key limit states is global flexural buckling, which can produce an undesirable response. Many prior studies have indicated the possibility of global buckling of a BRB before its core yields owing to connection failure. In this paper, BRB stability concepts are presented, including their bending‐moment transfer capacity at restrainer ends for various connection stiffness values with initial out‐of‐plane drifts, and a unified simple equation set for ensuring BRB stability is proposed. Moreover, a series of cyclic loading tests with initial out‐of‐plane drifts are conducted, and the results are compared with those of the proposed equations. © 2013 The Authors. Earthquake Engineering & Structural Dynamics published by John Wiley & Sons Ltd.