Pressure responses of portlandite and H–D isotope effects on pressure-induced phase transitions

The pressure responses of portlandite and the isotope effect on the phase transition were investigated at room temperature from single-crystal Raman and IR spectra and from powder X-ray diffraction using diamond anvil cells under quasi-hydrostatic conditions in a helium pressure-transmitting medium. Phase transformation and subsequent peak broadening (partial amorphization) observed from the Raman and IR spectra of Ca(OH)₂ occurred at lower pressures than those of Ca(OD)₂. In contrast, no isotope effect was found on the volume and axial compressions observed from powder X-ray diffraction patterns. X-ray diffraction lines attributable to the high-pressure phase remained up to 28.5 GPa, suggesting no total amorphization in a helium pressure medium within the examined pressure region. These results suggest that the H–D isotope effect is engendered in the local environment surrounding H(D) atoms. Moreover, the ratio of sample-to-methanol–ethanol pressure medium (i.e., packing density) in the sample chamber had a significant effect on the increase in the half widths of the diffraction lines, even at pressures below the hydrostatic limit of the pressure medium.     

Seismic activity beneath the Nankai trough revealed by DONET ocean-bottom observations

We conducted a detailed investigation of seismic activity from January 2011 to February 2013 along the Nankai trough off the Kii Peninsula, central Japan, by using data obtained from the DONET ocean-bottom observation network. The hypocenters are mostly within the subducting Philippine Sea (PHS) plate, although a few are along the plate boundary or in the sedimentary wedge below the Kumano forearc basin. The seismic activity can be separated into events above and below 20 km depth, which corresponds approximately to the Moho. The hypocenter distributions are distinctly different for these groups. The seismic activity in the oceanic crust can be further separated into three clusters. Most of the seismic activity recorded in our data represents aftershocks of the 2004 off the Kii Peninsula earthquakes (M _JMA = 7.1, 7.4, and 6.5), which occurred in the PHS plate. The hypocenter distribution in the oceanic crust correlates well with the location of the Paleo-Zenisu ridge, which is formed by a chain of seamounts that is subducting beneath the forearc basin. The hypocenters in the uppermost mantle are aligned on a plane dipping to the southeast, consistent with the existence of a thrust fault cutting through the lithosphere of the oceanic plate. The focal mechanisms of the earthquakes show that the axis of compressive stress in the PHS plate is oriented N–S, almost perpendicular to the direction of plate convergence, indicating a complex tectonic regime in this region. These results suggest that intraplate shortening may be occurring in the subducting oceanic plate.     

Formation mechanism of the Weddell Sea Polynya and the impact on the global abyssal ocean

An experiment using a global ocean–ice model with an interannual forcing data set was conducted to understand the variability in the Southern Ocean. A winter-persisting polynya in the Weddell Sea (the Weddell Polynya, WP) was simulated. The process of WP breaking out after no-WP years was explored using the successive WPs found in the late 1950s. The results suggested that the anomalously warm deep water, saline surface layer, and a cyclonic wind stress over the Maud polynya region in early winter are essential for the surface layer to be dense enough to trigger deep convections which maintain a winter-persisting polynya; also, the reanalyzed surface air temperature (SAT) over the observed polynya region is too high for an ocean–ice model’s bulk formula to yield sufficient upward heat fluxes to induce WP formation. Therefore the Weddell Polynya, a series of WPs observed from satellite in the mid-1970s, is reproduced by replacing the SAT with a climatological one. Subsequent to the successive WP events, density anomalies excited in the Weddell Sea propagate northward in the Atlantic deep basins. The Antarctic Circumpolar Current (ACC) is enhanced through the increased meridional density gradient. The enhanced ACC and its meandering over the abyssal ridges excite buoyancy anomalies near the bottom at the southwestern end of the South Pacific basin. The buoyancy signals propagate northward and eventually arrive in the northern North Pacific.     

Three‐dimensional structures and elemental distributions of Stardust impact tracks using synchrotron microtomography and X‐ray fluorescence analysis

Abstract— Three‐dimensional structures and elemental abundances of four impact tracks in silica aerogel keystones of Stardust samples from comet 81P/Wild 2 (bulbous track 67 and carrot‐type tracks 46, 47, and 68) were examined non‐destructively by synchrotron radiation‐based microtomography and X‐ray fluorescence analysis. Track features, such as lengths, volumes and width as a function of track depth, were obtained quantitatively by tomography. A bulbous portion was present near the track entrance even in carrot‐type tracks. Each impact of a cometary dust particle results in the particle disaggregated into small pieces that were widely distributed on the track walls as well as at its terminal. Fe, S, Ca, Ni, and eight minor elements are concentrated in the bulbous portion of track 68 as well as in terminal grains. It was confirmed that bulbous portions and thin tracks were formed by disaggregation of very fine fragile materials and relatively coarse crystalline particles, respectively. The almost constant ratio of whole Fe mass to track volume indicates that the track volume is almost proportional to the impact kinetic energy. The size of the original impactor was estimated from the absolute Fe mass by assuming its Fe content (CI) and bulk density. Relations between the track sizes normalized by the impactor size and impact conditions are roughly consistent with those of previous hypervelocity impact experiments.     

Phylogeny and phylogeography of the land hermit crab Coenobita purpureus (Decapoda: Anomura: Coenobitidae) in the Northwestern Pacific Region

Hermit crabs of the family Coenobitidae comprise the land hermit crabs, with 16 Coenobita species, and the coconut crab Birgus latro. They are terrestrial but spend their marine life as planktonic larvae. Some coenobitid crabs are widely distributed in the Indo‐West Pacific region, and some species occupy narrower ranges. To improve our knowledge of coenobitid crab speciation and geographical distribution patterns, we examined the phylogenetic relationship between Coenobita purpureus, which has a narrow distribution in the Northwestern Pacific, and its more widely distributed coenobitids including B. latro, Coenobita brevimanus, Coenobita cavipes, Coenobita perlatus, Coenobita rugosus and Coenobita violascens based on the mtDNA cytochrome c oxidase subunit I (COI) and 16S rDNA genes. We also assessed the phylogeography of Co. purpureus populations based on the COI gene. Our phylogenetic and phylogeographical analyses revealed that (i) Co. purpureus clustered with Co. rugosus and (ii) the Co. purpureus population in the Ogasawara Islands was genetically distinct from those in other regions, which showed genetic panmixia. It has been hypothesized that Co. purpureus evolved in the isolated landmasses of the Ryukyu region during the Pliocene, and that its population expanded and colonized the Ogasawara Islands in the late Pleistocene. Further phylogeographical studies on Coenobita species with relatively narrow distributions coupled with characterization of their phylogenetic relationships with widely distributed congeners will advance our knowledge of the speciation and geographical distribution history of coenobitid crabs.     

Use of similarity solutions for the problem of a wetting front — a question of unique representation

The use of similarity solutions for the problem of horizontal infiltration of water into a semi-infinite, dry and homogeneous porous medium is studied based upon some recent results of functional analysis. It is found that the so-called non-unique representation of reported experimental moisture profiles for this problem is not necessarily evidence against the validity of the extended Darcy's law for unsaturated flow through porous media.     

Particular solutions to the problem of horizontal flow of water and air through porous media near a water table

Particular solutions to the problem of horizontal flow of water and air through porous media near a water table are derived and regularity properties of the solutions are presented. It is found that a singularity occurs in the solutions at the water table and the water table can be interpreted as an acceleration wave of the nth order in terms of either air or water flow where n is a positive integer. Effects of air flow on water flow are discussed.     

A 10-Year Study on Techniques for Vegetation Restoration in a Desertified Salt Lake Area

Vegetation restoration is one of the most common and effective ways to combat desertification and prevent adjacent areas from sand encroachment in many of the desertified regions of the world. However, vegetation restoration in desertified regions is very difficult because of low rainfall, the mobile ground surface, and cost. An effective, low-cost method of afforestation is urgently required. To determine such a method, a 10-year study was carried out in the Jilantai Salt Lake area. Five different afforestation areas were established: a ‘comparison area,’ a ‘land enclosure area,’ a ‘land enclosure + irrigation area,’ a ‘leveled-afforestation area’ (the dune areas were leveled and then planted with seedlings with added irrigation), and a ‘protected afforestation area’ (the dune areas were planted with seedlings, and the surviving natural vegetation was protected as much as possible). Vegetation-related parameters (survival rate, height, trunk diameter, coverage, canopy size, and density) and environment-related factors (relative humidity, wind velocity, and amount of sand encroachment) were measured by standard methods. Results show that the protected afforestation method had the following advantages: (1) the survival rate was higher for seedlings planted in the protected afforestation area than in the leveled afforestation area; (2) vigor (height, trunk diameter, coverage, and canopy size) was better in seedlings planted in the protected afforestation area than in the leveled afforestation area, especially in the beginning period of revegetation; (3) coverage (of individual species, of all planted vegetation, and of all vegetation) was larger in the protected afforestation area than in the leveled afforestation area; (4) density of naturally germinated plant species was higher in the protected afforestation area than in the other areas, showing that the protected afforestation method provided a suitable growing environment not only for planted species but also for naturally growing species; (5) in the protected vegetation area, relative humidity of air increased and wind velocity was greatly reduced; (6) after the establishment of vegetation by the protected afforestation method, sand encroachment into the salt lake area was significantly reduced. These results suggest that protected afforestation is an effective method of vegetation rehabilitation that has the potential not only to be applied to arid lands in China but also to desertified areas throughout the world; (7) cost-effective calculation shows that the leveled afforestation area costs much more than other areas.     

Chemical variations of magmas at Izu-Oshima volcano,Japan: plagioclase-controlled and differentiated magmas

Systematic analyses of the major-element chemistry of products of several eruptions during syn-and post-caldera stages of Izu-Oshima volcano were compiled. Comparisons of the products of large-scale eruptions in 1338?, 1421? and 1777–1778, of intermediate-scale eruptions in 1950–1951 and 1986, and of small-scale eruptions in 1954, 1964 and 1974 clearly show the existence of two types of magmas. One is “plagioclase-controlled” and the other is “differentiated” magma (multimineral-controlled); i.e. the bulk chemistry of the first magma type is controlled by plagioclase addition or removal, while that of the second type is controlled by fractionation of plagioclase, orthopyroxene, clinopyroxene, and titanomagnetite. Eruptions of Izu-Oshima volcano have occurred at the summit and along the flanks. Summit eruptions tap only plagioclase-controlled magmas, while flank eruptions supply both magma types. It is considered unlikely that both magma types would coexist in the same magma chamber based on the petrology. In the case of the 1986 eruption, the flank magma was isolated sometime in the past from the summit magma chamber or central conduit, and formed small magma pockets, where further differentiation occurred due to relatively rapid cooling. In a period of quiescence prior to the 1986 eruption, new magma was supplied to the summit magma chamber, and the summit eruption began. The dike intrusion or fracturing around the small magma pockets triggered the flank eruption of the differentiated magma. This model can be applied to the large-scale flank eruption in 1338(?) which erupted differentiated magmas. In 1421(?), the flank eruption tapped plagioclase-controlled magma. In this case, the isolated magmas from the summit magma chamber directly penetrated the flank without differentiation.     

Geochemical Cycles of Bio-essential Elements on the Early Earth and Their Relationships to Origin of Life

Abstract: The bio-essential elements are demanded for the metabolic action of all living organisms. These elements are continuously supplied to biosphere through the elemental cycle on the surface Earth. The geochemical cycle of bio-essential elements was most likely different in the pre-biotic era (ca. 4.4 to 4.0 Ga) compared to the modern Earth. The difference was probably made by the absence of continents and biological mediation in the pre-biotic environments. Geochemical cycle models of bio-essential elements (P, B and Mo) on the pre-biotic Earth are proposed in this study, and these models are examined using available geochemical data.
The input flux of phosphorous in pre-biotic oceans was probably dominated by submarine hydrothermal activities associated with carbonatized oceanic crusts. Such input flux by submarine hydrothermal activities is not known in the present-day oceans, and probably a unique flux in the pre-biotic oceans. Boron chemistry of pre-biotic oceans was also controlled by submarine hydrothermal input flux. The Mo exchange between the pre-biotic ocean and lithosphere may have restricted only at the submarine hydrothermal areas. These suggest that the submarine hydrothermal discharging areas were only locations to obtain bio-essential elements for the earliest life. This model is consistent with the previously proposed model for hydrothermal origin of life.