The assessment of sediment sources: A field experiment

The possibility of using metals from mining activity as tracers for identifying stream sediment sources is explored. Sampling of monthly bed sediment yield and of the spatial and temporal variation in Pb concentration was undertaken in a 1·02 km² catchment, and estimates of the sediment contribution from different stream reaches are calculated. The method has considerable limitations, for metal concentrations are notably dependent on sediment size, season, source availability, and the chemical mobility of the metal used. In most natural streams these must preclude the use of pollutants for simple sediment source identification.     

A determination of the decay constant for spontaneous fission of natural uranium using fission track accumulation

The decay constant for spontaneous fission of natural uranium has been determined by accumulating fission fragment tracks in Lexan plastic held adjacent to uranium metal for one year. The value, 6.8 ± 0.6. 10⁻¹⁷ yr⁻¹, is consistent with values most commonly used in fission track dating.     

Raman spectrum of natural and synthetic stishovite

Raman spectra of natural and synthetic samples of stishovite have been measured with a micro-optical spectrometer system. These spectra have a pattern that is characteristic of rutile-structured oxides. The spectrum of synthetic stishovite is characterized by well-resolved bands at 231, 589, 753, and 967 cm^?1, which are assigned as theB _1g,E _g,A _1g, andB _2g fundamentals, respectively, of the first-order Raman spectrum of the ideal, ordered structure. Natural stishovite obtained from Meteor Crater, Arizona has a first-order Raman spectrum that is fully consistent with that of the synthetic material. The observed spectrum of the natural sample, however, is weaker and has bands in addition to those identified as fundamentals in the spectrum of the synthetic material. A broad band at ～475 cm^?1 may be indicative of glass or contaminants derived from the extraction procedure. Alternatively, this band may arise from multiphonon scattering that is enhanced by poor crystallinity or structural disorder in the natural shocked sample.     

Simultaneous optical polarimetry and X-ray observations of the magnetic CV CP Tuc (AX J2315−592)

CP Tuc (AX J2315–592) shows a dip in X-rays which lasts for approximately half the binary orbit and is deeper in soft X-rays compared with hard X-rays. It has been proposed that this dip is due to the accretion stream obscuring the accretion region from view. If CP Tuc were a polar, as has been suggested, then the length of such a dip would make it unique amongst polars since in those polars in which a dip is seen in hard X-rays the dip lasts for only 0.1 of the orbit. We present optical polarimetry and RXTE observations of CP Tuc which show circular polarization levels of ∼10 per cent and find evidence for only one photometric period. These data confirm CP Tuc as a polar. Our modelling of the polarization data implies that the X-ray dip is due to the bulk of the primary accretion region being self-eclipsed by the white dwarf. The energy dependence of the dip is due to a combination of this self-eclipse and also the presence of an X-ray temperature gradient over the primary accretion region.     

Shocked quartz in polymict impact breccia from the Upper Cretaceous Yallalie impact structure in Western Australia

Yallalie is a ~12 km diameter circular structure located ~200 km north of Perth, Australia. Previous studies have proposed that the buried structure is a complex impact crater based on geophysical data. Allochthonous breccia exposed near the structure has previously been interpreted as proximal impact ejecta; however, no diagnostic indicators of shock metamorphism have been found. Here we report multiple (27) shocked quartz grains containing planar fractures (PFs) and planar deformation features (PDFs) in the breccia. The PFs occur in up to five sets per grain, while the PDFs occur in up to four sets per grain. Universal stage measurements of all 27 shocked quartz grains confirms that the planar microstructures occur in known crystallographic orientations in quartz corresponding to shock compression from 5 to 20 GPa. Proximity to the buried structure (~4 km) and occurrence of shocked quartz indicates that the breccia represents either primary or reworked ejecta. Ejecta distribution simulated using iSALE hydrocode predicts the same distribution of shock levels at the site as those found in the breccia, which supports a primary ejecta interpretation, although local reworking cannot be excluded. The Yallalie impact event is stratigraphically constrained to have occurred in the interval from 89.8 to 83.6 Ma based on the occurrence of Coniacian clasts in the breccia and undisturbed overlying Santonian to Campanian sedimentary rocks. Yallalie is thus the first confirmed Upper Cretaceous impact structure in Australia.     

White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Diver-operated piston corer for nearshore use

A diver-operated piston corer suitable for collecting cores of >3 m length from fine-grained nearshore sediment has been developed. The corer uses a platform that rests on the sediment surface supporting both the operators and a derrick that maintains the piston at the sediment-water interface. The core is insected into and recovered from the sediment manually. The technique offers several advantages; low cost, minimal disruption of the sediment-water interface, little compaction of the sediment, the ability to collect longer length cores than is possible with gravity corers, and the ability to be deployed from relatively small boats. Dissolved ammonium and inorganic carbon data are presented from a 3.3-m core collected by this technique from Tomales Bay, California.     

Fire and vegetation change during the Early Pleistocene in southeastern Australia

Early Pleistocene vegetation in upland southeastern Australia included diverse rainforests and sclerophyll forests, which alternated on precessional timescales. The nature and timing of transitions between these biomes, and the role of fire in maintaining or driving transitions between them, are uncertain. Here we present a high‐resolution pollen record from Stony Creek Basin, a small Early Pleistocene palaeolake in southeastern Australia. The pollen record documents a pattern of vegetation change, over ca. 10 ka at ca. 1590–1600 ka, between sclerophyll forests, dominated by Eucalyptus, Callitris (Cupressaceae) or Casuarinaceae, and rainforests dominated by either angiosperms or conifers of the family Podocarpaceae. Transitions between these biomes typically occurred within ca. 1–2 ka. The associated charcoal record suggests that greatest biomass combustion occurred when local vegetation was dominated by Eucalyptus, and the least biomass combustion occurred when local vegetation was dominated by Podocarpaceae. However, local fires burnt in both sclerophyll and angiosperm‐dominated rainforest vegetation, at least once every several centuries. Fire was very rare (less than about one fire per millennium) only when the local vegetation was rainforest dominated by Podocarpaceae. This suggests that fire was an irregular presence in both sclerophyll‐ and angiosperm‐dominated rainforest biomes during the late Neogene, though was largely absent in Podocarpaceae‐dominated rainforests. Copyright © 2011 John Wiley & Sons, Ltd.     

The flocculation and de-watering of kimberlite clay slimes

The crushing of kimberlite at certain diamond mines produces a very persistent “slime” which is exceptionally difficult to filter or de-water. The colloidally stable component has been identified as a swelling clay, saponite, which carries a strong negative charge in alkaline media.Methods of coagulating or flocculating these slimes have been investigated; the most convenient method found was the combined use of magnesium sulphate and an anionic polyacrylamide (A-130 from B.T.I. Chemicals Ltd.). Optimal results were obtained only in a narrow range of conditions but with these it was possible to build flocs of any required size.The permeability and de-watering of coagulated or flocculated kimberlite slimes has been investigated with a hydraulic apparatus and in the capillary suction time (c.s.t.) apparatus. Typically compressible filter-cakes are obtained, their character varying greatly with the flocculation conditions.