Trace elements in tropical African savanna biomass burning aerosols

As a part of the FOS/DECAFE experiment, aerosol particles emitted during prescribed savanna fires were collected in January 1991 at Lamto (Ivory Coast), either close to the emission or in ambient air. Analytical transmission electron microscopy pointed out the presence of sub-micrometer soots, salt condensates, vegetation relicts and soil derived particles. The samples were also analyzed for their total particulate matter (TPM) content and elemental composition by PIXE or XRF. At the emission, high concentrations of soil derived elements (Fe and Al) pointed out an intense remobilization process during the fires. Biomass burning emissions contributed to more than 90% of the measured concentrations, of P, Cl, S, K, Cu and Zn, which were found primarily in the fine fraction with the exception of P. Near the emission, K was mainly present as KCl, evolving to K₂SO₄ in the ambient samples. Trace elements emission factors were obtained for the first time for the African savanna burning and their annual emissions were estimated: our median K emission factor (0.78 g/kg of C) is higher than estimates for other ecosystems (0.2–0.58 g/kg of C); Zn emissions (0.008 Tg/year) account for 4 to 11% of the global anthropogenic emissions.     

Neoproterozoic to Early-Palaeozoic magmatic evolution in the Gondwana-derived Austroalpine basement to the south of the Tauern Window (Eastern Alps)

In the Austroalpine Basement to the south of the Tauern Window, distinct suites of metabasites occur with orthogneisses in pre-Early-Ordovician units. Tholeiitic and alkaline within-plate basalt-type metabasites are associated with acid meta-porphyroids in the post-Early-Ordovician Thurntaler Phyllite Group. According to their correlated trace element abundances, metabasite zircons crystallized with their host rocks. Protolith Pb–Pb zircon ages, whole-rock Ta/Yb–Th/Yb and oxygen, Sr, Nd isotope data define two principal evolution lines. An older evolution at elevated Th/Yb typical of subduction-related magmatism, started by 590-Ma N-MORB-type and 550–530 Ma volcanic arc basalt type basic suites, which mainly involved depleted mantle sources. It finished with mainly crustal-source 470–450-Ma acid magmatites. An other evolution line by tholeiitic and 430-Ma alkaline within-plate basalt-type suites in both pre- and post-Early-Ordovician units is characterized by an intraplate mantle metasomatism and enrichment trend along multicomponent sources. These magmatic evolution lines can be related to a plate tectonic scenario that involved terranes in a progressively mature Neoproterozoic to Ordovician active margin, and a subsequent Palaeo-Tethys passive margin along the north Gondwanan periphery.     

Different age response of zircon and monazite during the tectono-metamorphic evolution of a high grade paragneiss from the Ruhla Crystalline Complex,central Germany

Results of TIMS, SIMS and SEM analyses show that zircon and monazite in a high-grade paragneiss of the Ruhla Crystalline Complex, central Germany, were formed and/or altered during different stages of a tectono-metamorphic history between Early Devonian and Permian times. Detrital zircon cores of >460 Ma place an older limit on the age of anatexis, and show that the paragneiss sequence contains rocks at least as young as early Cambrian. Metamorphic zircon growth commenced at ~365 Ma, peaking at ~360–355 Ma at the same time that granite dykes were emplaced. In contrast, monazite in the paragneiss preserves little record of the metamorphic peak. Most monazite grains grew or were recrystallised in the Lower Carboniferous at ~339 Ma, contemporaneous with the emplacement of voluminous diorite and granite bodies. These intrusions and related tectonics caused some of the high-U zircon overgrowths to undergo moderate to severe Pb loss. A second Pb loss event, between 300 and 280 Ma, can be related to Late Carboniferous/Early Permian large-scale block faulting.Editorial responsibility: J. Hoefs     

Evaporation from a riparian system in a semi-arid environment

Measurements of micrometeorological variables were made for a complete annual cycle using an automatic weather station and two energy budget–Bowen ratio systems at a field site adjacent to the Santa Cruz River in southern Arizona. These data were used to provide the basis of an estimate of the evaporation from a one-mile long losing reach of a riparian corridor in this semi-arid environment. A remotely sensed map of vegetation cover was used to stratify the corridor into five categories of surface cover. The total evaporation was calculated as the area-weighted average of the measured evaporation for sampled areas of the two most common covers, and appropriate estimates of evaporation for the less common covers. Measurements showed a substantial, seasonally dependent evaporation from the taller, deep-rooted riparian cover in the study reach, while the short, sparse vegetation provided little evaporation. In terms of the volume of water evaporated from the study reach, the evaporation from irrigated agriculture accounts for almost half of the total loss, while the majority of the remaining evaporation is from the taller riparian vegetation covers, with about one-quarter of the total loss estimated as coming from obligatory phreatophytes, primarily cottonwood. © 1998 John Wiley & Sons, Ltd.     

0-D-Modelling of Carbonaceous Aerosols over Greater Paris Focusing on the Organic Particle Formation

To improve our understanding of aerosol formation and ageing in urban atmospheres, we have tested the ORISAM 0-D aerosol module (ORganic and Inorganic Spectral Aerosol Model). This module accounts for both types of primary carbonaceous particles (black carbon BC and primary organic carbon OC_p) and also simulates the formation of secondary inorganic and organic particles (sulfates, nitrates, ammonium, water and secondary organic carbon particles OC_sec) by attachment of gas precursors to pre-existing carbonaceous particles. Simulations were performed for surface aerosols over Greater Paris area during the ESQUIF summer 1998 and winter 2000 experiments. Results show that OC_sec formation is highly dependent on temperature and insolation with more intense secondary formation in summer than in winter. Moreover in Summer, when atmospheric conditions shift from warm and humid to hot and dry, the model indicates a decreasing formation of secondary organic aerosols OC_sec as shown by an increase of the OC_p/(OC_p+OC_sec) ratio from 42 to 56%. These results satisfactorily compare with the few experimental available data for BC/(OC_p+OC_sec) ratios increasing from 24 to 37% against modelled values in the range 21–32%. ORISAM module sensitivity to initial size distributions, background concentrations and emissions of gases and primary carbonaceous particles was documented too. One main result is that the formation of secondary organic particles with ORISAM is very sensitive to the concentrations of gaseous precursors. At the present stage of ORISAM development, OC_sec build up appears to be however less sensitive to particulate background concentrations.     

Economic drivers of migration and climate change in LDCs

Environmental migration is a topic which has given rise to widespread debate and gloomy predictions about the state of the world in 2050, but where rigorous research and empirical evidence are unfortunately in short supply. In this paper, we review the existing research on and empirical evidence of how climate change and climate variability in Less Developed Countries (LDCs) affects two main drivers of migration identified by migration models in the economic literature, namely income level differentials between origin and destination areas and income variability in origin areas, and how they in turn affect migration. We find that there are serious gaps in both the economic and the environmental literature that render it impossible to make sound and robust predictions of how climate change and increased climate variability will affect the economic migration drivers, and of how these in turn may change existing migration patterns. There are some empirical indications that income differentials may increase due to lower income levels in the origin areas of LDCs, but virtually no evidence exists of the effects of climate change or increased climate variability on income variability. Furthermore, although a negative relationship between migration and rainfall has been established by many researchers, there is only very limited evidence as to what drives it. A clearer picture of the driving force behind the link between rainfall and migration would greatly benefit policymaking in this area.     

Place,gender and the appeal of video lottery terminal gambling: unpacking a focus group study of Montreal youth

Youth gambling has become an important public health issue in Canada and elsewhere owing to the known associations between gambling and delinquency, family dysfunction and suicide. Modern electronic and virtual gambling activities like video lottery terminals (VLTs) may have particular appeal to youth who have been raised in social environments that are increasingly dependent on information and communication technologies. The main objective of the study was to explore why youth gamble and what makes gambling activities like VLTs popular to youth in the places where youth live, study and play. The research is framed within a population health perspective that recognizes the role of social and physical environments in influencing health-related behaviours. Group discussions were conducted with youth to explore the popularity and appeal of gambling and VLTs, and how gambling fits into the daily routines of youth and the spaces they occupy. Methodologically, this research was conscious of responding to calls in the literature to analyze focus groups as an interactive group process rather a collection of individual responses, and to exercise analytic rigour by explicitly making the research team’s positionality and the data collection process transparent. Group discussions revealed gender differences in the appeal of particular gambling activities with young males being more likely to discuss poker, dice, sports-betting and online gambling as exciting social activities, while females described lottery and scratch (instant win) tickets as fun solitary activities. Substantive results point to the need for interventions to address social aspects of gambling that appeal, in particular, to young males potentially through increased provision of healthier alternatives to social engagement and greater attention to young people’s use of space.     

Iridium enrichment and poor fractionation from gold, platinum and palladium in clausthalite (PbSe), Tilkerode, eastern Harz, Germany

Enrichments in platinum-group elements were found in clausthalite, PbSe, which occurs in carbonate–hematite veins hosted in black shale of Upper Wenlockian age in the eastern Harz, Germany. Spot measurements by laser ablation–quadrupole inductively coupled plasma mass spectrometry (LA–QICPMS) show that the clausthalite has Pt contents that average 0.459?ppm and range from 0.003 to 2.83?ppm. Other noble metals quantified in the present work include Au (0.226?ppm, 0.109–0.451?ppm), Ru (0.061?ppm, 0.006–0.264?ppm), Ir (0.071?ppm, 0.010–0.185?ppm), Pd (0.046?ppm, 0.017–0.107?ppm) and Os (0.010?ppm, <0.003–0.024?ppm). Elemental ratios of Au/Ir, Pd/Ir and Pt/Ir, the average values of which are respectively 4.6, 0.8, and 4.9, suggest that Au, Pd and Pt are poorly fractionated from Ir. The resulting Ir enrichment is unusual and should reflect a particularly soluble (and stable) aqueous complex of Ir in a highly oxidizing, low-temperature, Se-rich solution.     

Contrasting geomorphic response to structural control: The Loughros estuaries, northwest Ireland

Sediment-rich estuaries typically exhibit considerable dynamicity, with channel shifts and shoreline erosion/deposition occurring over timescales of years to decades. Contemporary behaviour is usually attributed to the immediate effect of short-term events (such as storms), longer-term forcing (such as sea-level change) or anthropogenic modifications to system controls (such as wave–tidal–fluvial regime and sediment supply). In this context, geological control is understood to provide an inherited framework within which an estuary will evolve. This paper examines the morphodynamics of two sand-filled, but sediment-limited, mixed-energy estuaries of Loughros Bay in northwest Ireland. Analysis of ebb channel morphometry shows that estuaries can be divided into upper and lower estuary components, which appear to represent a down-valley increasing energy gradient. Examination of historical ebb channel migration reveals three morphodynamic zones delimited by a significant spatial variability in channel mobility that reflects the distribution of specific structural controls along the estuary and their influence on the changing energy gradient. Based upon analysis of low tide channel migration over the last 172 years, three phases of geomorphic response are identified. In Loughros More, the behaviour is characterised by a 19th century phase of steady-state equilibrium; a subsequent period of dynamic response to extrinsic (storm) forcing; and, most recently, adjustment to intrinsically forced changes in structural control. In Loughros Beg, the phases are comparable, but contrast specifically in inlet and ebb-tidal behaviour. This analysis illustrates discontinuities in decadal- to century-scale forcing and morphological response, identified here as complex response. It suggests that the sedimentary evolution of coastal systems that have no appreciable external sediment supply is potentially more strongly determined by local variability in system character than climate or sea-level driven mechanisms.