Anisotropic model of damage for geomaterials and concrete

A damage model for geomaterials and concrete is proposed. This model expresses the anisotropic character induced by the degradation of material. The law of behavior obtained by differentiation of the free energy shows the dissymmetry effect observed in traction–compression loading and the residual strains caused by the damage. The present approach requires the identification of a reduced number of parameters having a clear physical significance. An application to the case of the uniaxial traction–compression loading shows a good adequacy with the experimental observations. Copyright © 2010 John Wiley & Sons, Ltd.     

Trace-element characteristics of different pyrite types in Mesoarchaean to Palaeoproterozoic placer deposits

A comparative in situ LA-ICP MS trace-element study on pyrite from three different, variably auriferous, Archaean to Palaeoproterozoic palaeoplacer deposits in the Ouro Fino Syncline (Quadrilátero Ferrífero; Brazil), the Elliot Lake area north of Lake Huron (SE Canada) and several deposits within the Witwatersrand Basin (South Africa) revealed systematic differences between morphologically different pyrite types and between the various palaeoplacer deposits. Especially the Ni and Au concentrations as well as Co/Ni and Mo/Ni ratios were found to be systematically different in detrital compact, detrital porous and post-sedimentary/hydrothermal pyrite grains from different source areas. High Co/Ni ratios and low Au concentrations are typical of post-sedimentary pyrite, which is hydrothermal in origin. In contrast, relatively low Co/Ni ratios and high Au contents characterise detrital porous banded and concentric pyrite grains (Au > 1 ppm), which are syn-sedimentary in origin. In the Elliot Lake area and the Witwatersrand Basin, detrital compact rounded pyrite is characterised by high Co/Ni ratios, which is in agreement with derivation from a hydrothermal source. Low Au concentrations in this pyrite type support the contention of the gold and the pyrite in these deposits coming from different source rocks. In contrast, derivation from an originally diagenetic pyrite is suggested for the detrital compact pyrite in the Ouro Fino Syncline because of low to intermediate Co/Ni ratios. High Au contents may indicate a genetic relationship between pyrite and gold there. Systematic differences exist between the three areas with respect to Au, Ni, Co, Mo and Cu distributions in detrital pyrite, which reflects differences in the provenance. A predominantly mafic/ultramafic source is indicated for the Ouro Fino, a felsic source for the Elliot Lake, and a mixed felsic–mafic provenance for the Witwatersrand pyrite populations. Independently of pyrite type, the higher Au endowment of the studied Witwatersrand and Ouro Fino conglomerates are also reflected by an overall higher Au concentration in the respective pyrite grains compared to the relatively Au-poor samples from Elliot Lake. In general, a strong positive correlation between Au and Pb levels in the various pyrite grains is noted. Analogous to Pb, which is well known for not being easily accommodated in the pyrite crystal lattice but occurring as discrete PbS phases, Au is considered to be present mainly in the form of discrete Au phases in minute pores and interstices of the pyrite grains rather than within the pyrite lattice.     

The effect of different second-phase particle regimes on grain growth in two-phase aggregates: insights from in situ rock analogue experiments

The aim of the study was to investigate the effect of rigid second phases on grain growth of a matrix phase. For this purpose, variable mixtures of norcamphor as the matrix phase, with glass beads (0.08–0.51 volume fraction) as second phase, were used to perform see-through rock-analogue experiments under static conditions at constant temperatures (50°C). Irrespective of the second-phase content, grain-size evolution of all mixtures can be subdivided into a stage of continuous grain growth, a transient stage and a stage of a finally stabilized grain size. On the grain-scale, the second phases affect the migrating grain boundaries either by pinning by single particles, by multiple particles or even by particle clusters. Summed up over the entire aggregate, these pinning regimes affect the average bulk grain size of the matrix grains, such that the changes in matrix grain size directly correlate with the amount of second phases, their dispersion and their degree of clustering. In this way, the matrix grain size decreases with increasing second-phase content, which can be expressed as a Zener relationship. Originating from the modification of an ordinary grain growth law, a new mathematical expression is defined, which allows the calculation of changes in the matrix grain size as a function of different second-phase volume fractions and particle sizes. Such models will be helpful in the future to predict microstructural changes in polymineralic rocks at depth.     

A case study of a modelled episode of low Arctic sea ice

Simulations of the Arctic sea ice cover over the last 32 years generated by the HadGEM1 coupled climate model are able to capture the observed long term decline in mean September ice extent. HadGEM1 is also capable of producing an episode of low September ice extent of similar magnitude to the anomalously low extent observed in 2007. Using a heat budget analysis, together with diagnostics partitioning the changes in ice and snow mass into thermodynamic and dynamic components, we analyse the factors driving the long term decline in the ice mass and extent as well as those causing the modelled low ice event. The long term decline in the mass of ice and snow in HadGEM1 is largely due to extra melting during the summer, partly at the top surface of the ice, and partly via extra heating from the ocean as it warms due to the ice retreat. The episode of low summer ice extent is largely driven by the synoptic conditions over the summer moving the ice across and out of the Arctic basin, and also due to pre-conditioning of the snow and ice which is thinner than usual in the Eastern Arctic at the start of the melt season. This case study demonstrates that although HadGEM1 does not capture the persistent dipole pressure anomaly observed during the summer of 2007, it represents broadly similar mechanisms of generating a low ice extent.     

The Place of Narrative in the Study of Third World Migration: The Case of Spontaneous Rural Migration in Sri Lanka*

Studies of migration in geography have most often been based on quantitative research approaches. Such studies cannot adequately shed light on the contextuality of migration and the individual decision-making processes involved. Personal narratives express individual experiences within a social context. The story of “Amma,” a female rural migrant in Sri Lanka, shows the role of women in migration, the importance of family ties, the contextual causes of migration, and characteristics of the migration flow per se. Personal narratives have an underutilized potential of capturing the variety of migrants' experiences and the complexity of the decision to migrate.     

Observational Constraints on Cloud Feedbacks: The Role of Active Satellite Sensors

Cloud profiling from active lidar and radar in the A-train satellite constellation has significantly advanced our understanding of clouds and their role in the climate system. Nevertheless, the response of clouds to a warming climate remains one of the largest uncertainties in predicting climate change and for the development of adaptions to change. Both observation of long-term changes and observational constraints on the processes responsible for those changes are necessary. We review recent progress in our understanding of the cloud feedback problem. Capabilities and advantages of active sensors for observing clouds are discussed, along with the importance of active sensors for deriving constraints on cloud feedbacks as an essential component of a global climate observing system.